Producing carbon nanotube powder in a floating iron catalyst LPCVD system

Yannan Li; Zhuo Sun; Yue Chen; Zhejuan Zhang; Lili Wang; Ting Chen; Yiwei Chen; Jiexin Yang

Producing carbon nanotube powder in a floating iron catalyst LPCVD system

Yannan Li^*
, Zhuo Sun
, Yue Chen
, Zhejuan Zhang
, Lili Wang
, Ting Chen
, Yiwei Chen
, Jiexin Yang

^*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Large amounts of web-like CNTs were synthesized in a large scale in a floating iron catalyst chemical vapor deposition system below atmospheric pressure, using ferrocene as a catalyst precursor, cyclohexane as carbon source, H₂ as carrier gas, C₄H₄S to C ₆H₁₂ molar ratio of 4.5 × 10^-3 of thiophene as a promoter, and H₂ flow rate of 60 seem, under the pressure of 15 kPa, reaction temperature of 650°C. The effect of ferrocene sublimed temperature on the growth of carbon products was studied. It is found that the quantity of the CNTs were enhanced with the increase of the ferrocene amount while the quality of the CNTs became worse on the contrary. Scanning electron microscopy (SEM), Raman spectroscopy were utilized to characterize the samples.

Original language	English
Title of host publication	AD'07 - Proceedings of Asia Display 2007
Pages	1742-1746
Number of pages	5
State	Published - 2007
Externally published	Yes
Event	Asia Display 2007, AD'07 - Shanghai, China Duration: 12 Mar 2007 → 16 Mar 2007

Publication series

Name	AD'07 - Proceedings of Asia Display 2007
Volume	2

Conference

Conference	Asia Display 2007, AD'07
Country/Territory	China
City	Shanghai
Period	12/03/07 → 16/03/07

Keywords

Ferrocene sublimed temperature
Sulfur effect
Web-like CNTs

Cite this

@inproceedings{795ff1e6ca024b2bb71125e4d62fe122,

title = "Producing carbon nanotube powder in a floating iron catalyst LPCVD system",

abstract = "Large amounts of web-like CNTs were synthesized in a large scale in a floating iron catalyst chemical vapor deposition system below atmospheric pressure, using ferrocene as a catalyst precursor, cyclohexane as carbon source, H2 as carrier gas, C4H4S to C 6H12 molar ratio of 4.5 × 10-3 of thiophene as a promoter, and H2 flow rate of 60 seem, under the pressure of 15 kPa, reaction temperature of 650°C. The effect of ferrocene sublimed temperature on the growth of carbon products was studied. It is found that the quantity of the CNTs were enhanced with the increase of the ferrocene amount while the quality of the CNTs became worse on the contrary. Scanning electron microscopy (SEM), Raman spectroscopy were utilized to characterize the samples.",

keywords = "Ferrocene sublimed temperature, Sulfur effect, Web-like CNTs",

author = "Yannan Li and Zhuo Sun and Yue Chen and Zhejuan Zhang and Lili Wang and Ting Chen and Yiwei Chen and Jiexin Yang",

year = "2007",

language = "英语",

isbn = "9787561752289",

series = "AD'07 - Proceedings of Asia Display 2007",

pages = "1742--1746",

booktitle = "AD'07 - Proceedings of Asia Display 2007",

note = "Asia Display 2007, AD'07 ; Conference date: 12-03-2007 Through 16-03-2007",

}

TY - GEN

T1 - Producing carbon nanotube powder in a floating iron catalyst LPCVD system

AU - Li, Yannan

AU - Sun, Zhuo

AU - Chen, Yue

AU - Zhang, Zhejuan

AU - Wang, Lili

AU - Chen, Ting

AU - Chen, Yiwei

AU - Yang, Jiexin

PY - 2007

Y1 - 2007

N2 - Large amounts of web-like CNTs were synthesized in a large scale in a floating iron catalyst chemical vapor deposition system below atmospheric pressure, using ferrocene as a catalyst precursor, cyclohexane as carbon source, H2 as carrier gas, C4H4S to C 6H12 molar ratio of 4.5 × 10-3 of thiophene as a promoter, and H2 flow rate of 60 seem, under the pressure of 15 kPa, reaction temperature of 650°C. The effect of ferrocene sublimed temperature on the growth of carbon products was studied. It is found that the quantity of the CNTs were enhanced with the increase of the ferrocene amount while the quality of the CNTs became worse on the contrary. Scanning electron microscopy (SEM), Raman spectroscopy were utilized to characterize the samples.

AB - Large amounts of web-like CNTs were synthesized in a large scale in a floating iron catalyst chemical vapor deposition system below atmospheric pressure, using ferrocene as a catalyst precursor, cyclohexane as carbon source, H2 as carrier gas, C4H4S to C 6H12 molar ratio of 4.5 × 10-3 of thiophene as a promoter, and H2 flow rate of 60 seem, under the pressure of 15 kPa, reaction temperature of 650°C. The effect of ferrocene sublimed temperature on the growth of carbon products was studied. It is found that the quantity of the CNTs were enhanced with the increase of the ferrocene amount while the quality of the CNTs became worse on the contrary. Scanning electron microscopy (SEM), Raman spectroscopy were utilized to characterize the samples.

KW - Ferrocene sublimed temperature

KW - Sulfur effect

KW - Web-like CNTs

UR - https://www.scopus.com/pages/publications/77958026694

M3 - 会议稿件

AN - SCOPUS:77958026694

SN - 9787561752289

T3 - AD'07 - Proceedings of Asia Display 2007

SP - 1742

EP - 1746

BT - AD'07 - Proceedings of Asia Display 2007

T2 - Asia Display 2007, AD'07

Y2 - 12 March 2007 through 16 March 2007

ER -

Producing carbon nanotube powder in a floating iron catalyst LPCVD system

Abstract

Publication series

Conference

Keywords

Other files and links

Fingerprint

Cite this