Preparation of fluorine-doped lead dioxide modified electrodes for electroanalytical applications

Shiyun Ai; Mengnan Gao; Wen Zhang; Zhengdong Sun; Litong Jin

doi:10.1002/elan.200302667

Preparation of fluorine-doped lead dioxide modified electrodes for electroanalytical applications

Shiyun Ai
, Mengnan Gao
, Wen Zhang
, Zhengdong Sun
, Litong Jin^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

The effect of F- on the modified films of lead dioxide in morphology and structure was studied. The results obtained by cyclic voltammetry (CV), X-diffractometer (XRD) and scanning electron microscope (SEM) techniques indicated that F- could change the magnitude of lead dioxide crystal grain and the preferred crystallizing orientation on the substrate surface, even though it didn't change the basic structure of PbO₂. When the modified electrode was applied as an analytical sensor to determine phenolic compounds, the linearity was in the range of 2 × 10^-5 - 1 × 10 ^-3 mol/L and the detection limit was 2.5 × 10^-6 mol/L. It was all found that the stability and reproducibility of the oxide-modified electrodes were improved by additional F^-.

Original language	English
Pages (from-to)	1403-1409
Number of pages	7
Journal	Electroanalysis
Volume	15
Issue number	17
DOIs	https://doi.org/10.1002/elan.200302667
State	Published - Sep 2003

Keywords

Amperometry
Anode
Fluoride
Lead dioxide
Phenol

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title = "Preparation of fluorine-doped lead dioxide modified electrodes for electroanalytical applications",

abstract = "The effect of F- on the modified films of lead dioxide in morphology and structure was studied. The results obtained by cyclic voltammetry (CV), X-diffractometer (XRD) and scanning electron microscope (SEM) techniques indicated that F- could change the magnitude of lead dioxide crystal grain and the preferred crystallizing orientation on the substrate surface, even though it didn't change the basic structure of PbO2. When the modified electrode was applied as an analytical sensor to determine phenolic compounds, the linearity was in the range of 2 × 10-5 - 1 × 10 -3 mol/L and the detection limit was 2.5 × 10-6 mol/L. It was all found that the stability and reproducibility of the oxide-modified electrodes were improved by additional F-.",

keywords = "Amperometry, Anode, Fluoride, Lead dioxide, Phenol",

author = "Shiyun Ai and Mengnan Gao and Wen Zhang and Zhengdong Sun and Litong Jin",

year = "2003",

month = sep,

doi = "10.1002/elan.200302667",

language = "英语",

volume = "15",

pages = "1403--1409",

journal = "Electroanalysis",

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TY - JOUR

T1 - Preparation of fluorine-doped lead dioxide modified electrodes for electroanalytical applications

AU - Ai, Shiyun

AU - Gao, Mengnan

AU - Zhang, Wen

AU - Sun, Zhengdong

AU - Jin, Litong

PY - 2003/9

Y1 - 2003/9

N2 - The effect of F- on the modified films of lead dioxide in morphology and structure was studied. The results obtained by cyclic voltammetry (CV), X-diffractometer (XRD) and scanning electron microscope (SEM) techniques indicated that F- could change the magnitude of lead dioxide crystal grain and the preferred crystallizing orientation on the substrate surface, even though it didn't change the basic structure of PbO2. When the modified electrode was applied as an analytical sensor to determine phenolic compounds, the linearity was in the range of 2 × 10-5 - 1 × 10 -3 mol/L and the detection limit was 2.5 × 10-6 mol/L. It was all found that the stability and reproducibility of the oxide-modified electrodes were improved by additional F-.

AB - The effect of F- on the modified films of lead dioxide in morphology and structure was studied. The results obtained by cyclic voltammetry (CV), X-diffractometer (XRD) and scanning electron microscope (SEM) techniques indicated that F- could change the magnitude of lead dioxide crystal grain and the preferred crystallizing orientation on the substrate surface, even though it didn't change the basic structure of PbO2. When the modified electrode was applied as an analytical sensor to determine phenolic compounds, the linearity was in the range of 2 × 10-5 - 1 × 10 -3 mol/L and the detection limit was 2.5 × 10-6 mol/L. It was all found that the stability and reproducibility of the oxide-modified electrodes were improved by additional F-.

KW - Amperometry

KW - Anode

KW - Fluoride

KW - Lead dioxide

KW - Phenol

UR - https://www.scopus.com/pages/publications/0142027325

U2 - 10.1002/elan.200302667

DO - 10.1002/elan.200302667

M3 - 文章

AN - SCOPUS:0142027325

SN - 1040-0397

VL - 15

SP - 1403

EP - 1409

JO - Electroanalysis

JF - Electroanalysis

IS - 17

ER -

Preparation of fluorine-doped lead dioxide modified electrodes for electroanalytical applications

Abstract

Keywords

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