Preparation and characterization of WO3/ZrO2 solid acid catalyst with hierarchically porous structure

Chongcheng Chen; Hangrong Chen; Jianchang Yu; Zhengqing Ye; Jianlin Shi

doi:10.3724/SP.J.1088.2011.01203

Preparation and characterization of WO₃/ZrO₂ solid acid catalyst with hierarchically porous structure

Chongcheng Chen
, Hangrong Chen^*
, Jianchang Yu
, Zhengqing Ye
, Jianlin Shi

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

WO₃/ZrO₂ solid acid catalyst with hierarchically porous structure was prepared by the one-pot hydrothermal method involving templating from a composite surfactant. The catalyst samples were characterized by X-ray diffraction, N₂ adsorption-desorption, Raman spectroscopy and NH₃ temperature-programmed desorption. The results indicated that WO₃ doping significantly increased the BET surface area and provided more surface acid centers. The esterification of acetic acid and butanol showed that the hierarchically porous WO₃/ZrO₂ solid acid catalyst has excellent catalytic activity and reusability. The 20% WO₃/ZrO₂ sample calcined at 550 °C for 5 h has the highest catalytic activity.

Original language	English
Pages (from-to)	647-651
Number of pages	5
Journal	Chinese Journal of Catalysis
Volume	32
Issue number	4
DOIs	https://doi.org/10.3724/SP.J.1088.2011.01203
State	Published - Apr 2011
Externally published	Yes

Keywords

Acetic acid
Butyl acetate
Esterification
Hierarchical pore
N-butanol
Reusability
Solid superacid
Tungsten oxide
Zirconia

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10.3724/SP.J.1088.2011.01203

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title = "Preparation and characterization of WO3/ZrO2 solid acid catalyst with hierarchically porous structure",

abstract = "WO3/ZrO2 solid acid catalyst with hierarchically porous structure was prepared by the one-pot hydrothermal method involving templating from a composite surfactant. The catalyst samples were characterized by X-ray diffraction, N2 adsorption-desorption, Raman spectroscopy and NH3 temperature-programmed desorption. The results indicated that WO3 doping significantly increased the BET surface area and provided more surface acid centers. The esterification of acetic acid and butanol showed that the hierarchically porous WO3/ZrO2 solid acid catalyst has excellent catalytic activity and reusability. The 20\% WO3/ZrO2 sample calcined at 550 °C for 5 h has the highest catalytic activity.",

keywords = "Acetic acid, Butyl acetate, Esterification, Hierarchical pore, N-butanol, Reusability, Solid superacid, Tungsten oxide, Zirconia",

author = "Chongcheng Chen and Hangrong Chen and Jianchang Yu and Zhengqing Ye and Jianlin Shi",

year = "2011",

month = apr,

doi = "10.3724/SP.J.1088.2011.01203",

language = "英语",

volume = "32",

pages = "647--651",

journal = "Chinese Journal of Catalysis",

issn = "1872-2067",

publisher = "Science Press ",

number = "4",

}

TY - JOUR

T1 - Preparation and characterization of WO3/ZrO2 solid acid catalyst with hierarchically porous structure

AU - Chen, Chongcheng

AU - Chen, Hangrong

AU - Yu, Jianchang

AU - Ye, Zhengqing

AU - Shi, Jianlin

PY - 2011/4

Y1 - 2011/4

N2 - WO3/ZrO2 solid acid catalyst with hierarchically porous structure was prepared by the one-pot hydrothermal method involving templating from a composite surfactant. The catalyst samples were characterized by X-ray diffraction, N2 adsorption-desorption, Raman spectroscopy and NH3 temperature-programmed desorption. The results indicated that WO3 doping significantly increased the BET surface area and provided more surface acid centers. The esterification of acetic acid and butanol showed that the hierarchically porous WO3/ZrO2 solid acid catalyst has excellent catalytic activity and reusability. The 20% WO3/ZrO2 sample calcined at 550 °C for 5 h has the highest catalytic activity.

AB - WO3/ZrO2 solid acid catalyst with hierarchically porous structure was prepared by the one-pot hydrothermal method involving templating from a composite surfactant. The catalyst samples were characterized by X-ray diffraction, N2 adsorption-desorption, Raman spectroscopy and NH3 temperature-programmed desorption. The results indicated that WO3 doping significantly increased the BET surface area and provided more surface acid centers. The esterification of acetic acid and butanol showed that the hierarchically porous WO3/ZrO2 solid acid catalyst has excellent catalytic activity and reusability. The 20% WO3/ZrO2 sample calcined at 550 °C for 5 h has the highest catalytic activity.

KW - Acetic acid

KW - Butyl acetate

KW - Esterification

KW - Hierarchical pore

KW - N-butanol

KW - Reusability

KW - Solid superacid

KW - Tungsten oxide

KW - Zirconia

UR - https://www.scopus.com/pages/publications/79957882253

U2 - 10.3724/SP.J.1088.2011.01203

DO - 10.3724/SP.J.1088.2011.01203

M3 - 文章

AN - SCOPUS:79957882253

SN - 1872-2067

VL - 32

SP - 647

EP - 651

JO - Chinese Journal of Catalysis

JF - Chinese Journal of Catalysis

IS - 4

ER -

Preparation and characterization of WO₃/ZrO₂ solid acid catalyst with hierarchically porous structure

Abstract

Keywords

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