Preparation and characterization of lithium-ion-conductive Li1.3Al0.3Ti1.7(PO4)3 thin films by the solution deposition

Xian Ming Wu; Xin Hai Li; Shao Wei Wang; Zhuo Wang; Yun He Zhang; Ming Fei Xu; Ze Qiang He

doi:10.1016/S0040-6090(02)01094-5

Preparation and characterization of lithium-ion-conductive Li_1.3Al_0.3Ti_1.7(PO₄)₃ thin films by the solution deposition

Xian Ming Wu^*
, Xin Hai Li
, Shao Wei Wang
, Zhuo Wang
, Yun He Zhang
, Ming Fei Xu
, Ze Qiang He

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

Li_1.3Al_0.3Ti_1.7(PO₄)₃ thin films were successfully prepared by the solution deposition using lithium acetate, aluminum nitrate, ammonium dihydrogen phosphate and titanium butoxide as starting materials. The structure, surface morphology, electrochemical window, and ionic conductivity of the films were studied by X-ray diffraction, scanning electron microscopy, cyclic voltammetry and AC impedance. The results showed that Li_1.3Al_0.3Ti_1.7(PO₄)₃ thin films annealed between 750 °C and 900 °C prepared by this method were well crystallized, homogenous and crack-free. The electrochemical window was beyond 2.4 V and the ionic conductivity was approximately 1.57×10^-5 S/cm at room temperature for the film annealed at 800 °C for 30 min.

Original language	English
Pages (from-to)	103-107
Number of pages	5
Journal	Thin Solid Films
Volume	425
Issue number	1-2
DOIs	https://doi.org/10.1016/S0040-6090(02)01094-5
State	Published - 3 Feb 2003
Externally published	Yes

Keywords

Electrochemistry
Lithium titanium phosphate
Scanning electron microscopy
X-ray diffraction

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10.1016/S0040-6090(02)01094-5

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@article{f44f1982ab664cdea477803945a7edc3,

title = "Preparation and characterization of lithium-ion-conductive Li1.3Al0.3Ti1.7(PO4)3 thin films by the solution deposition",

abstract = "Li1.3Al0.3Ti1.7(PO4)3 thin films were successfully prepared by the solution deposition using lithium acetate, aluminum nitrate, ammonium dihydrogen phosphate and titanium butoxide as starting materials. The structure, surface morphology, electrochemical window, and ionic conductivity of the films were studied by X-ray diffraction, scanning electron microscopy, cyclic voltammetry and AC impedance. The results showed that Li1.3Al0.3Ti1.7(PO4)3 thin films annealed between 750 °C and 900 °C prepared by this method were well crystallized, homogenous and crack-free. The electrochemical window was beyond 2.4 V and the ionic conductivity was approximately 1.57×10-5 S/cm at room temperature for the film annealed at 800 °C for 30 min.",

keywords = "Electrochemistry, Lithium titanium phosphate, Scanning electron microscopy, X-ray diffraction",

author = "Wu, \{Xian Ming\} and Li, \{Xin Hai\} and Wang, \{Shao Wei\} and Zhuo Wang and Zhang, \{Yun He\} and Xu, \{Ming Fei\} and He, \{Ze Qiang\}",

year = "2003",

month = feb,

day = "3",

doi = "10.1016/S0040-6090(02)01094-5",

language = "英语",

volume = "425",

pages = "103--107",

journal = "Thin Solid Films",

issn = "0040-6090",

publisher = "Elsevier B.V.",

number = "1-2",

}

TY - JOUR

T1 - Preparation and characterization of lithium-ion-conductive Li1.3Al0.3Ti1.7(PO4)3 thin films by the solution deposition

AU - Wu, Xian Ming

AU - Li, Xin Hai

AU - Wang, Shao Wei

AU - Wang, Zhuo

AU - Zhang, Yun He

AU - Xu, Ming Fei

AU - He, Ze Qiang

PY - 2003/2/3

Y1 - 2003/2/3

N2 - Li1.3Al0.3Ti1.7(PO4)3 thin films were successfully prepared by the solution deposition using lithium acetate, aluminum nitrate, ammonium dihydrogen phosphate and titanium butoxide as starting materials. The structure, surface morphology, electrochemical window, and ionic conductivity of the films were studied by X-ray diffraction, scanning electron microscopy, cyclic voltammetry and AC impedance. The results showed that Li1.3Al0.3Ti1.7(PO4)3 thin films annealed between 750 °C and 900 °C prepared by this method were well crystallized, homogenous and crack-free. The electrochemical window was beyond 2.4 V and the ionic conductivity was approximately 1.57×10-5 S/cm at room temperature for the film annealed at 800 °C for 30 min.

AB - Li1.3Al0.3Ti1.7(PO4)3 thin films were successfully prepared by the solution deposition using lithium acetate, aluminum nitrate, ammonium dihydrogen phosphate and titanium butoxide as starting materials. The structure, surface morphology, electrochemical window, and ionic conductivity of the films were studied by X-ray diffraction, scanning electron microscopy, cyclic voltammetry and AC impedance. The results showed that Li1.3Al0.3Ti1.7(PO4)3 thin films annealed between 750 °C and 900 °C prepared by this method were well crystallized, homogenous and crack-free. The electrochemical window was beyond 2.4 V and the ionic conductivity was approximately 1.57×10-5 S/cm at room temperature for the film annealed at 800 °C for 30 min.

KW - Electrochemistry

KW - Lithium titanium phosphate

KW - Scanning electron microscopy

KW - X-ray diffraction

UR - https://www.scopus.com/pages/publications/0037415864

U2 - 10.1016/S0040-6090(02)01094-5

DO - 10.1016/S0040-6090(02)01094-5

M3 - 文章

AN - SCOPUS:0037415864

SN - 0040-6090

VL - 425

SP - 103

EP - 107

JO - Thin Solid Films

JF - Thin Solid Films

IS - 1-2

ER -

Preparation and characterization of lithium-ion-conductive Li_1.3Al_0.3Ti_1.7(PO₄)₃ thin films by the solution deposition

Abstract

Keywords

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