Postsynthesis and catalytic properties of metallosilicates structurally analogous to MCM-56

Lingling Wang, Yueming Liu, Wei Xie, Wu Haihong, Yongwen Jiang, Mingyuan He, Peng Wu

Research output: Chapter in Book/Report/Conference proceedingChapterpeer-review

4 Scopus citations

Abstract

A novel postsynthesis method for preparing various metallosilicates structurally analogous to MCM-56 has been developed. Highly crystalline MCM-56 zeolites were postsynthesized readily from corresponding MWW type lamellar precursors by a simple acid treatment at controllable temperatures. The titanosilicate analogue, Ti-MCM-56, thus obtained has been characterized by various techniques and applied to the liquid-phase oxidation of alkenes in comparison to three-dimensional (3D) Ti-MWW and Ti-Beta. Ti-MCM-56 with an open external surface showed a much higher activity for bulky molecules than Ti-MWW.

Original languageEnglish
Title of host publicationFrom Zeolites to Porous MOF Materials - The 40th Anniversary of International Zeolite Conference
PublisherElsevier Inc.
Pages635-640
Number of pages6
EditionA
ISBN (Print)0444530681, 9780444530684
DOIs
StatePublished - 2007

Publication series

NameStudies in Surface Science and Catalysis
NumberA
Volume170
ISSN (Print)0167-2991

Fingerprint

Dive into the research topics of 'Postsynthesis and catalytic properties of metallosilicates structurally analogous to MCM-56'. Together they form a unique fingerprint.

Cite this