TY - JOUR
T1 - Post-grafting preparation of large-pore mesoporous materials with localized high content titanium doping
AU - Hua, Zile
AU - Bu, Wenbo
AU - Lian, Yuxiang
AU - Chen, Hangrong
AU - Li, Lei
AU - Zhang, Lingxia
AU - Li, Can
AU - Shi, Jianlin
PY - 2005/2/14
Y1 - 2005/2/14
N2 - A new post-grafting process, consisting of two steps of substrate preparation and sol-gel post-grafting, has been developed to prepare titanium-doped mesoporous SBA-15 material with a double-layered structure and locally concentrated titanium content at the inner pore surface. With this novel technique, the single phased and originally ordered mesostructures can be well conserved; in the conventional direct synthesis they can be partially damaged when the frameworks are doped with high content heteroatoms, Titanium species exist in an isolated, tetrahedral structure and are localized at the pore surface; this is beneficial to both reactant access and product release. Characterization with XRD, N2 adsorption/desorption isotherms, HREM/EDS, ICP, UV-Vis, and the newly developed UV-Raman spectroscopy confirm these results. Preliminary catalytic tests with the selective epoxidation of cyclohexene show good catalytic activity. Among them, sample TiSBA-15-10 with a Si: Ti molar ratio of 10 shows a TON value of 75 and a highest product (epoxide) yield of 55%.
AB - A new post-grafting process, consisting of two steps of substrate preparation and sol-gel post-grafting, has been developed to prepare titanium-doped mesoporous SBA-15 material with a double-layered structure and locally concentrated titanium content at the inner pore surface. With this novel technique, the single phased and originally ordered mesostructures can be well conserved; in the conventional direct synthesis they can be partially damaged when the frameworks are doped with high content heteroatoms, Titanium species exist in an isolated, tetrahedral structure and are localized at the pore surface; this is beneficial to both reactant access and product release. Characterization with XRD, N2 adsorption/desorption isotherms, HREM/EDS, ICP, UV-Vis, and the newly developed UV-Raman spectroscopy confirm these results. Preliminary catalytic tests with the selective epoxidation of cyclohexene show good catalytic activity. Among them, sample TiSBA-15-10 with a Si: Ti molar ratio of 10 shows a TON value of 75 and a highest product (epoxide) yield of 55%.
UR - https://www.scopus.com/pages/publications/14544298294
U2 - 10.1039/b413478h
DO - 10.1039/b413478h
M3 - 文章
AN - SCOPUS:14544298294
SN - 0959-9428
VL - 15
SP - 661
EP - 665
JO - Journal of Materials Chemistry
JF - Journal of Materials Chemistry
IS - 6
ER -