Porous MOFs supported palladium catalysts for phenol hydrogenation: A comparative study on MIL-101 and MIL-53

Damin Zhang; Yejun Guan; Emiel J.M. Hensen; Li Chen; Yimeng Wang

doi:10.1016/j.catcom.2013.06.035

Porous MOFs supported palladium catalysts for phenol hydrogenation: A comparative study on MIL-101 and MIL-53

Damin Zhang
, Yejun Guan^*
, Emiel J.M. Hensen
, Li Chen
, Yimeng Wang

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

72 Scopus citations

Abstract

Two metal organic frameworks (MOFs), chromium benzenedicarboxylates MIL-101 and MIL-53, have been synthesized and used as the support of palladium catalysts. The palladium catalysts were characterized by XRD, TEM, and CO chemisorption. MIL-101 is highly hydrophilic and beneficial as support for fine Pd nanoparticles with an average size of 2.3 nm. Microporous MIL-53 is relatively hydrophobic and larger Pd particles with an average size of 4.3 nm were formed on the external surface. Pd/MIL-101 showed better phenol selective hydrogenation activity to cyclohexanone (> 98%) under mild reaction conditions because of its smaller particle size.

Original language	English
Pages (from-to)	47-51
Number of pages	5
Journal	Catalysis Communications
Volume	41
DOIs	https://doi.org/10.1016/j.catcom.2013.06.035
State	Published - 2013

Keywords

Benzenedicarboxylate
Chromium
Cyclohexanone
Hydrogenation
Palladium
Phenol

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10.1016/j.catcom.2013.06.035

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title = "Porous MOFs supported palladium catalysts for phenol hydrogenation: A comparative study on MIL-101 and MIL-53",

abstract = "Two metal organic frameworks (MOFs), chromium benzenedicarboxylates MIL-101 and MIL-53, have been synthesized and used as the support of palladium catalysts. The palladium catalysts were characterized by XRD, TEM, and CO chemisorption. MIL-101 is highly hydrophilic and beneficial as support for fine Pd nanoparticles with an average size of 2.3 nm. Microporous MIL-53 is relatively hydrophobic and larger Pd particles with an average size of 4.3 nm were formed on the external surface. Pd/MIL-101 showed better phenol selective hydrogenation activity to cyclohexanone (> 98\%) under mild reaction conditions because of its smaller particle size.",

keywords = "Benzenedicarboxylate, Chromium, Cyclohexanone, Hydrogenation, Palladium, Phenol",

author = "Damin Zhang and Yejun Guan and Hensen, \{Emiel J.M.\} and Li Chen and Yimeng Wang",

year = "2013",

doi = "10.1016/j.catcom.2013.06.035",

language = "英语",

volume = "41",

pages = "47--51",

journal = "Catalysis Communications",

issn = "1566-7367",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Porous MOFs supported palladium catalysts for phenol hydrogenation

T2 - A comparative study on MIL-101 and MIL-53

AU - Zhang, Damin

AU - Guan, Yejun

AU - Hensen, Emiel J.M.

AU - Chen, Li

AU - Wang, Yimeng

PY - 2013

Y1 - 2013

N2 - Two metal organic frameworks (MOFs), chromium benzenedicarboxylates MIL-101 and MIL-53, have been synthesized and used as the support of palladium catalysts. The palladium catalysts were characterized by XRD, TEM, and CO chemisorption. MIL-101 is highly hydrophilic and beneficial as support for fine Pd nanoparticles with an average size of 2.3 nm. Microporous MIL-53 is relatively hydrophobic and larger Pd particles with an average size of 4.3 nm were formed on the external surface. Pd/MIL-101 showed better phenol selective hydrogenation activity to cyclohexanone (> 98%) under mild reaction conditions because of its smaller particle size.

AB - Two metal organic frameworks (MOFs), chromium benzenedicarboxylates MIL-101 and MIL-53, have been synthesized and used as the support of palladium catalysts. The palladium catalysts were characterized by XRD, TEM, and CO chemisorption. MIL-101 is highly hydrophilic and beneficial as support for fine Pd nanoparticles with an average size of 2.3 nm. Microporous MIL-53 is relatively hydrophobic and larger Pd particles with an average size of 4.3 nm were formed on the external surface. Pd/MIL-101 showed better phenol selective hydrogenation activity to cyclohexanone (> 98%) under mild reaction conditions because of its smaller particle size.

KW - Benzenedicarboxylate

KW - Chromium

KW - Cyclohexanone

KW - Hydrogenation

KW - Palladium

KW - Phenol

UR - https://www.scopus.com/pages/publications/84880886583

U2 - 10.1016/j.catcom.2013.06.035

DO - 10.1016/j.catcom.2013.06.035

M3 - 文章

AN - SCOPUS:84880886583

SN - 1566-7367

VL - 41

SP - 47

EP - 51

JO - Catalysis Communications

JF - Catalysis Communications

ER -

Porous MOFs supported palladium catalysts for phenol hydrogenation: A comparative study on MIL-101 and MIL-53

Abstract

Keywords

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