Polyfluoroalkoxylation and methoxylation of polychloropyridines

Xiaoyong Xu; Xuhong Qian; Zhong Li; Gonghua Song

doi:10.1016/S0022-1139(97)00094-8

Polyfluoroalkoxylation and methoxylation of polychloropyridines

Xiaoyong Xu
, Xuhong Qian^*
, Zhong Li
, Gonghua Song

^*Corresponding author for this work

East China University of Science and Technology

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

With sodium 2,2,2-trifluoroethoxide, sodium 1,1,1,3,3,3-hexafluoro-2-propoxide and sodium methoxide used as nucleophilic reagents, the alcoholysis reactions of 2,3,4,5,6-pentachloropyridine and 2,3,5,6-tetrachloropyridine were studied. Some new polyfluoroalkoxypyridines have been synthesized. The activities, pathways, mechanism of the alcoholysis reactions are discussed.

Original language	English
Pages (from-to)	9-13
Number of pages	5
Journal	Journal of Fluorine Chemistry
Volume	88
Issue number	1
DOIs	https://doi.org/10.1016/S0022-1139(97)00094-8
State	Published - 27 Feb 1998
Externally published	Yes

Keywords

Alcoholysis
Nucleophilic reagents
Polychloropyridine

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10.1016/S0022-1139(97)00094-8

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@article{1deb296cb75a44a996058930135bf75b,

title = "Polyfluoroalkoxylation and methoxylation of polychloropyridines",

abstract = "With sodium 2,2,2-trifluoroethoxide, sodium 1,1,1,3,3,3-hexafluoro-2-propoxide and sodium methoxide used as nucleophilic reagents, the alcoholysis reactions of 2,3,4,5,6-pentachloropyridine and 2,3,5,6-tetrachloropyridine were studied. Some new polyfluoroalkoxypyridines have been synthesized. The activities, pathways, mechanism of the alcoholysis reactions are discussed.",

keywords = "Alcoholysis, Nucleophilic reagents, Polychloropyridine",

author = "Xiaoyong Xu and Xuhong Qian and Zhong Li and Gonghua Song",

year = "1998",

month = feb,

day = "27",

doi = "10.1016/S0022-1139(97)00094-8",

language = "英语",

volume = "88",

pages = "9--13",

journal = "Journal of Fluorine Chemistry",

issn = "0022-1139",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - Polyfluoroalkoxylation and methoxylation of polychloropyridines

AU - Xu, Xiaoyong

AU - Qian, Xuhong

AU - Li, Zhong

AU - Song, Gonghua

PY - 1998/2/27

Y1 - 1998/2/27

N2 - With sodium 2,2,2-trifluoroethoxide, sodium 1,1,1,3,3,3-hexafluoro-2-propoxide and sodium methoxide used as nucleophilic reagents, the alcoholysis reactions of 2,3,4,5,6-pentachloropyridine and 2,3,5,6-tetrachloropyridine were studied. Some new polyfluoroalkoxypyridines have been synthesized. The activities, pathways, mechanism of the alcoholysis reactions are discussed.

AB - With sodium 2,2,2-trifluoroethoxide, sodium 1,1,1,3,3,3-hexafluoro-2-propoxide and sodium methoxide used as nucleophilic reagents, the alcoholysis reactions of 2,3,4,5,6-pentachloropyridine and 2,3,5,6-tetrachloropyridine were studied. Some new polyfluoroalkoxypyridines have been synthesized. The activities, pathways, mechanism of the alcoholysis reactions are discussed.

KW - Alcoholysis

KW - Nucleophilic reagents

KW - Polychloropyridine

UR - https://www.scopus.com/pages/publications/0032570403

U2 - 10.1016/S0022-1139(97)00094-8

DO - 10.1016/S0022-1139(97)00094-8

M3 - 文章

AN - SCOPUS:0032570403

SN - 0022-1139

VL - 88

SP - 9

EP - 13

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 1

ER -

Polyfluoroalkoxylation and methoxylation of polychloropyridines

Abstract

Keywords

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