Poly[[diaqua(μ2-5,5-dioxodibenzo[b,d]thiophene-3, 7-dicarboxylato)(μ2-ethylene glycol)manganese(II)] dimethyl-acetamide solvate]

Xiu Chun Yi, Li Yan, En Qing Gao

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Abstract

In the title complex, {[Mn(C14H6O6S) (C2H6O2)(H2O)2] ·C4H9NO}n , the MnII ion is six-coordinated in a trans-octa-hedral geometry by two carboxyl-ate O atoms from two 5,5-dioxodibenzo[b,d]thiophene-3,7-dicarboxyl-ate (L) ligands in a monodentate mode, two O atoms from two ethylene glycol (EG) molecules and two aqua O atoms. The metal ions are linked by the EG and L ligands, forming two-dimensional coordination networks, which are associated into the three-dimensional structure through O - H⋯O hydrogen bonds.

Original languageEnglish
Pages (from-to)m1554
JournalActa Crystallographica Section E: Structure Reports Online
Volume66
Issue number12
DOIs
StatePublished - Dec 2010

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