Platinum acetylide complexes containing iptycene as cores: A new family of unexpected efficient organometallic gelators

Jing Zhang; Xing Dong Xu; Li Jun Chen; Qi Luo; Nai Wei Wu; De Xian Wang; Xiao Li Zhao; Hai Bo Yang

doi:10.1021/om2002987

Platinum acetylide complexes containing iptycene as cores: A new family of unexpected efficient organometallic gelators

Jing Zhang
, Xing Dong Xu
, Li Jun Chen
, Qi Luo
, Nai Wei Wu
, De Xian Wang
, Xiao Li Zhao
, Hai Bo Yang^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

A new family of platinum acetylide derivatives containing iptycene building blocks end-capped with 3,4,5-tris(alkoxy)phenyl substituents has been successfully synthesized. The structure of the newly designed complexes was characterized by multinuclear NMR (¹H, ³¹P, and ¹³C) and mass spectroscopy and elemental analysis. Unexpectedly, all compounds presented good gel formation properties in some common organic solvents. The morphology of the xerogels was investigated by scanning electron microscopy (SEM). An investigation using electronic absorption and emission spectra was carried out to study the spectroscopic properties of all organometallic complexes in both solution and gel states.

Original language	English
Pages (from-to)	4032-4038
Number of pages	7
Journal	Organometallics
Volume	30
Issue number	15
DOIs	https://doi.org/10.1021/om2002987
State	Published - 8 Aug 2011

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title = "Platinum acetylide complexes containing iptycene as cores: A new family of unexpected efficient organometallic gelators",

abstract = "A new family of platinum acetylide derivatives containing iptycene building blocks end-capped with 3,4,5-tris(alkoxy)phenyl substituents has been successfully synthesized. The structure of the newly designed complexes was characterized by multinuclear NMR (1H, 31P, and 13C) and mass spectroscopy and elemental analysis. Unexpectedly, all compounds presented good gel formation properties in some common organic solvents. The morphology of the xerogels was investigated by scanning electron microscopy (SEM). An investigation using electronic absorption and emission spectra was carried out to study the spectroscopic properties of all organometallic complexes in both solution and gel states.",

author = "Jing Zhang and Xu, \{Xing Dong\} and Chen, \{Li Jun\} and Qi Luo and Wu, \{Nai Wei\} and Wang, \{De Xian\} and Zhao, \{Xiao Li\} and Yang, \{Hai Bo\}",

year = "2011",

month = aug,

day = "8",

doi = "10.1021/om2002987",

language = "英语",

volume = "30",

pages = "4032--4038",

journal = "Organometallics",

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T1 - Platinum acetylide complexes containing iptycene as cores

T2 - A new family of unexpected efficient organometallic gelators

AU - Zhang, Jing

AU - Xu, Xing Dong

AU - Chen, Li Jun

AU - Luo, Qi

AU - Wu, Nai Wei

AU - Wang, De Xian

AU - Zhao, Xiao Li

AU - Yang, Hai Bo

PY - 2011/8/8

Y1 - 2011/8/8

N2 - A new family of platinum acetylide derivatives containing iptycene building blocks end-capped with 3,4,5-tris(alkoxy)phenyl substituents has been successfully synthesized. The structure of the newly designed complexes was characterized by multinuclear NMR (1H, 31P, and 13C) and mass spectroscopy and elemental analysis. Unexpectedly, all compounds presented good gel formation properties in some common organic solvents. The morphology of the xerogels was investigated by scanning electron microscopy (SEM). An investigation using electronic absorption and emission spectra was carried out to study the spectroscopic properties of all organometallic complexes in both solution and gel states.

AB - A new family of platinum acetylide derivatives containing iptycene building blocks end-capped with 3,4,5-tris(alkoxy)phenyl substituents has been successfully synthesized. The structure of the newly designed complexes was characterized by multinuclear NMR (1H, 31P, and 13C) and mass spectroscopy and elemental analysis. Unexpectedly, all compounds presented good gel formation properties in some common organic solvents. The morphology of the xerogels was investigated by scanning electron microscopy (SEM). An investigation using electronic absorption and emission spectra was carried out to study the spectroscopic properties of all organometallic complexes in both solution and gel states.

UR - https://www.scopus.com/pages/publications/79961049310

U2 - 10.1021/om2002987

DO - 10.1021/om2002987

M3 - 文章

AN - SCOPUS:79961049310

SN - 0276-7333

VL - 30

SP - 4032

EP - 4038

JO - Organometallics

JF - Organometallics

IS - 15

ER -

Platinum acetylide complexes containing iptycene as cores: A new family of unexpected efficient organometallic gelators

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