Photodegradation of per- and polyfluoroalkyl substances in water: A review of fundamentals and applications

Per- and polyfluoroalkyl substances (PFAS) are persistent, mobile, and toxic chemicals that are hazardous to human health and the environment. Several countries, including the United States, plan to set an enforceable maximum contamination level for certain PFAS compounds in drinking water sources. Among the available treatment options, photocatalytic treatment is promising for PFAS degradation and mineralization in the aqueous solution. In this review, recent advances in the abatement of PFAS from water using photo-oxidation and photo-reduction are systematically reviewed. Degradation mechanisms of PFAS by photo-oxidation involving the holes (h_vb⁺) and oxidative radicals and photo-reduction using the electrons (e_cb^-) and hydrated electrons (e_aq^-) are integrated. The recent development of innovative heterogeneous photocatalysts and photolysis systems for enhanced degradation of PFAS is highlighted. Photodegradation mechanisms of alternative compounds, such as hexafluoropropylene oxide dimer acid (GenX) and chlorinated polyfluorinated ether sulfonate (F-53B), are also critically evaluated. This paper concludes by identifying major knowledge gaps and some of the challenges that lie ahead in the scalability and adaptability issues of photocatalysis for natural water treatment. Development made in photocatalysts design and system optimization forges a path toward sustainable treatment of PFAS-contaminated water through photodegradation technologies.