Permanent electric dipole moment of molybdenum carbide

Hailing Wang; Wilton L. Virgo; Jinhai Chen; Timothy C. Steimle

doi:10.1063/1.2778427

Permanent electric dipole moment of molybdenum carbide

Hailing Wang, Wilton L. Virgo, Jinhai Chen, Timothy C. Steimle

Arizona State University

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

High resolution optical spectroscopy has been used to study a molecular beam of molybdenum monocarbide (MoC). The Stark effect of the Re (0) and Qfe (1) branch features of the [18.6] Π13 -X -3 (0,0) band system of Mo98 C were analyzed to determine the permanent electric dipole moments μe of 2.68(2) and 6.07 (18) D for the [18.6] Π13 (=0) and X -3 (=0) states, respectively. The dipole moments are compared with the experimental value for ruthenium monocarbide [T. C. Steimle, J. Chem. Phys. 118, 2620 (2003)] and with theoretical predictions. A molecular orbital correlation diagram is used to interpret the observed and predicted trends of ground state μe values for the 4d -metal monocarbides series.

Original language	English
Article number	124302
Journal	Journal of Chemical Physics
Volume	127
Issue number	12
DOIs	https://doi.org/10.1063/1.2778427
State	Published - 2007
Externally published	Yes

Access to Document

10.1063/1.2778427

Cite this

@article{e559299c1f4f4c80aad919912d44f7d7,

title = "Permanent electric dipole moment of molybdenum carbide",

abstract = "High resolution optical spectroscopy has been used to study a molecular beam of molybdenum monocarbide (MoC). The Stark effect of the Re (0) and Qfe (1) branch features of the [18.6] Π13 -X -3 (0,0) band system of Mo98 C were analyzed to determine the permanent electric dipole moments μe of 2.68(2) and 6.07 (18) D for the [18.6] Π13 (=0) and X -3 (=0) states, respectively. The dipole moments are compared with the experimental value for ruthenium monocarbide [T. C. Steimle, J. Chem. Phys. 118, 2620 (2003)] and with theoretical predictions. A molecular orbital correlation diagram is used to interpret the observed and predicted trends of ground state μe values for the 4d -metal monocarbides series.",

author = "Hailing Wang and Virgo, \{Wilton L.\} and Jinhai Chen and Steimle, \{Timothy C.\}",

year = "2007",

doi = "10.1063/1.2778427",

language = "英语",

volume = "127",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "12",

}

TY - JOUR

T1 - Permanent electric dipole moment of molybdenum carbide

AU - Wang, Hailing

AU - Virgo, Wilton L.

AU - Chen, Jinhai

AU - Steimle, Timothy C.

PY - 2007

Y1 - 2007

N2 - High resolution optical spectroscopy has been used to study a molecular beam of molybdenum monocarbide (MoC). The Stark effect of the Re (0) and Qfe (1) branch features of the [18.6] Π13 -X -3 (0,0) band system of Mo98 C were analyzed to determine the permanent electric dipole moments μe of 2.68(2) and 6.07 (18) D for the [18.6] Π13 (=0) and X -3 (=0) states, respectively. The dipole moments are compared with the experimental value for ruthenium monocarbide [T. C. Steimle, J. Chem. Phys. 118, 2620 (2003)] and with theoretical predictions. A molecular orbital correlation diagram is used to interpret the observed and predicted trends of ground state μe values for the 4d -metal monocarbides series.

AB - High resolution optical spectroscopy has been used to study a molecular beam of molybdenum monocarbide (MoC). The Stark effect of the Re (0) and Qfe (1) branch features of the [18.6] Π13 -X -3 (0,0) band system of Mo98 C were analyzed to determine the permanent electric dipole moments μe of 2.68(2) and 6.07 (18) D for the [18.6] Π13 (=0) and X -3 (=0) states, respectively. The dipole moments are compared with the experimental value for ruthenium monocarbide [T. C. Steimle, J. Chem. Phys. 118, 2620 (2003)] and with theoretical predictions. A molecular orbital correlation diagram is used to interpret the observed and predicted trends of ground state μe values for the 4d -metal monocarbides series.

UR - https://www.scopus.com/pages/publications/34848925696

U2 - 10.1063/1.2778427

DO - 10.1063/1.2778427

M3 - 文章

AN - SCOPUS:34848925696

SN - 0021-9606

VL - 127

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 12

M1 - 124302

ER -

Permanent electric dipole moment of molybdenum carbide

Abstract

Access to Document

Other files and links

Fingerprint

Cite this