Pd-catalyzed reactions of unactivated Csp3-I bonds

Hui Liu; Xuefeng Jiang

doi:10.1515/pac-2014-5032

Pd-catalyzed reactions of unactivated C_sp3-I bonds

Hui Liu, Xuefeng Jiang

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

C_sp3-I bonds, especially those with β-hydrogen atoms, are a class of challenging substrates for the Pd-catalyzed transformations. The challenges mainly stem from the reluctant oxidative addition of C _sp3-I bond with Pd(0) species and the facile β-H elimination for alkylpalladium intermediate. Herein, Pd-catalyzed reactions from unactivated C_sp3-I bond were discussed.

Original language	English
Pages (from-to)	307-314
Number of pages	8
Journal	Pure and Applied Chemistry
Volume	86
Issue number	3
DOIs	https://doi.org/10.1515/pac-2014-5032
State	Published - 20 Mar 2014

Keywords

C-C bond formation
C-I bond formation
C-S bond formation
OMCOS-17
palladium-catalyzed

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10.1515/pac-2014-5032

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title = "Pd-catalyzed reactions of unactivated Csp3-I bonds",

abstract = "Csp3-I bonds, especially those with β-hydrogen atoms, are a class of challenging substrates for the Pd-catalyzed transformations. The challenges mainly stem from the reluctant oxidative addition of C sp3-I bond with Pd(0) species and the facile β-H elimination for alkylpalladium intermediate. Herein, Pd-catalyzed reactions from unactivated Csp3-I bond were discussed.",

keywords = "C-C bond formation, C-I bond formation, C-S bond formation, OMCOS-17, palladium-catalyzed",

author = "Hui Liu and Xuefeng Jiang",

year = "2014",

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doi = "10.1515/pac-2014-5032",

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journal = "Pure and Applied Chemistry",

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T1 - Pd-catalyzed reactions of unactivated Csp3-I bonds

AU - Liu, Hui

AU - Jiang, Xuefeng

PY - 2014/3/20

Y1 - 2014/3/20

N2 - Csp3-I bonds, especially those with β-hydrogen atoms, are a class of challenging substrates for the Pd-catalyzed transformations. The challenges mainly stem from the reluctant oxidative addition of C sp3-I bond with Pd(0) species and the facile β-H elimination for alkylpalladium intermediate. Herein, Pd-catalyzed reactions from unactivated Csp3-I bond were discussed.

AB - Csp3-I bonds, especially those with β-hydrogen atoms, are a class of challenging substrates for the Pd-catalyzed transformations. The challenges mainly stem from the reluctant oxidative addition of C sp3-I bond with Pd(0) species and the facile β-H elimination for alkylpalladium intermediate. Herein, Pd-catalyzed reactions from unactivated Csp3-I bond were discussed.

KW - C-C bond formation

KW - C-I bond formation

KW - C-S bond formation

KW - OMCOS-17

KW - palladium-catalyzed

UR - https://www.scopus.com/pages/publications/84896258840

U2 - 10.1515/pac-2014-5032

DO - 10.1515/pac-2014-5032

M3 - 文章

AN - SCOPUS:84896258840

SN - 0033-4545

VL - 86

SP - 307

EP - 314

JO - Pure and Applied Chemistry

JF - Pure and Applied Chemistry

IS - 3

ER -

Pd-catalyzed reactions of unactivated C_sp3-I bonds

Abstract

Keywords

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