Palladium-catalyzed synthesis of fluoreones from bis(2-bromophenyl)methanols

Qian Gao; Senmiao Xu

doi:10.1039/c7ob02895d

Palladium-catalyzed synthesis of fluoreones from bis(2-bromophenyl)methanols

Qian Gao
, Senmiao Xu^*

^*Corresponding author for this work

CAS - Lanzhou Institute of Chemical Physics

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A palladium-catalyzed synthesis method of fluorenones has been developed. A variety of bis(2-bromophenyl)methanols could undergo the reaction smoothly in the presence of Pd(OAc)₂, affording a series of fluorenones in moderate to good yields (two steps). Mechanistic studies reveal that the reaction might be triggered by oxidation of alcohol followed by intramolecular reductive coupling.

Original language	English
Pages (from-to)	208-212
Number of pages	5
Journal	Organic and Biomolecular Chemistry
Volume	16
Issue number	2
DOIs	https://doi.org/10.1039/c7ob02895d
State	Published - 2018
Externally published	Yes

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title = "Palladium-catalyzed synthesis of fluoreones from bis(2-bromophenyl)methanols",

abstract = "A palladium-catalyzed synthesis method of fluorenones has been developed. A variety of bis(2-bromophenyl)methanols could undergo the reaction smoothly in the presence of Pd(OAc)2, affording a series of fluorenones in moderate to good yields (two steps). Mechanistic studies reveal that the reaction might be triggered by oxidation of alcohol followed by intramolecular reductive coupling.",

author = "Qian Gao and Senmiao Xu",

note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

year = "2018",

doi = "10.1039/c7ob02895d",

language = "英语",

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journal = "Organic and Biomolecular Chemistry",

issn = "1477-0520",

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T1 - Palladium-catalyzed synthesis of fluoreones from bis(2-bromophenyl)methanols

AU - Gao, Qian

AU - Xu, Senmiao

PY - 2018

Y1 - 2018

N2 - A palladium-catalyzed synthesis method of fluorenones has been developed. A variety of bis(2-bromophenyl)methanols could undergo the reaction smoothly in the presence of Pd(OAc)2, affording a series of fluorenones in moderate to good yields (two steps). Mechanistic studies reveal that the reaction might be triggered by oxidation of alcohol followed by intramolecular reductive coupling.

AB - A palladium-catalyzed synthesis method of fluorenones has been developed. A variety of bis(2-bromophenyl)methanols could undergo the reaction smoothly in the presence of Pd(OAc)2, affording a series of fluorenones in moderate to good yields (two steps). Mechanistic studies reveal that the reaction might be triggered by oxidation of alcohol followed by intramolecular reductive coupling.

UR - https://www.scopus.com/pages/publications/85040165901

U2 - 10.1039/c7ob02895d

DO - 10.1039/c7ob02895d

M3 - 文章

C2 - 29256561

AN - SCOPUS:85040165901

SN - 1477-0520

VL - 16

SP - 208

EP - 212

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 2

ER -

Palladium-catalyzed synthesis of fluoreones from bis(2-bromophenyl)methanols

Abstract

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