TY - JOUR
T1 - Palladium-catalyzed selective generation of CO from formic acid for carbonylation of alkenes
AU - Sang, Rui
AU - Kucmierczyk, Peter
AU - Dong, Kaiwu
AU - Franke, Robert
AU - Neumann, Helfried
AU - Jackstell, Ralf
AU - Beller, Matthias
N1 - Publisher Copyright:
© 2018 American Chemical Society.
PY - 2018/4/18
Y1 - 2018/4/18
N2 - A general and selective palladium-catalyzed alkoxycarbonylation of all kinds of alkenes with formic acid (HCOOH, FA) is described. Terminal, di-, tri-, and tetra-substituted including functionalized olefins are converted into linear esters with high yields and regioselectivity. Key-to-success is the use of specific palladium catalysts containing ligands with built-in base, e.g., L5. Comparison experiments demonstrate that the active catalyst system not only facilitates isomerization and carbonylation of alkenes but also promotes the selective decomposition of HCOOH to CO under mild conditions.
AB - A general and selective palladium-catalyzed alkoxycarbonylation of all kinds of alkenes with formic acid (HCOOH, FA) is described. Terminal, di-, tri-, and tetra-substituted including functionalized olefins are converted into linear esters with high yields and regioselectivity. Key-to-success is the use of specific palladium catalysts containing ligands with built-in base, e.g., L5. Comparison experiments demonstrate that the active catalyst system not only facilitates isomerization and carbonylation of alkenes but also promotes the selective decomposition of HCOOH to CO under mild conditions.
UR - https://www.scopus.com/pages/publications/85045695948
U2 - 10.1021/jacs.8b01123
DO - 10.1021/jacs.8b01123
M3 - 文章
C2 - 29528637
AN - SCOPUS:85045695948
SN - 0002-7863
VL - 140
SP - 5217
EP - 5223
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 15
ER -