Palladium-catalyzed heck reaction in the multi-functionalized ionic liquid compositions

Qing Xia Wan; Ye Liu; Yong Lu; Min Li; Hai Hong Wu

doi:10.1007/s10562-007-9343-y

Palladium-catalyzed heck reaction in the multi-functionalized ionic liquid compositions

Qing Xia Wan
, Ye Liu^*
, Yong Lu
, Min Li
, Hai Hong Wu

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

39 Scopus citations

Abstract

In the multi-functionalized ionic liquid compositions (MFILC), composed of 1-n-butyl-2-diphenylphosphino-3-methylimidazolium hexafluorophosphate, [BDPPMIM]PF6), 1-(2-piperid-1-yl-ethyl)-3-methylimidazolium hexafluorophosphate, [PEMIM]PF6), and 1-n-butyl-3-methylimidazolium hexafluorophosphate ([BMIM]PF6), PdCl2 served as an efficient catalyst for Heck reactions of aryl iodides and bromides. The built-up PdCl2-MFILC, including stoichiometrically consumed base of [PEMIM]PF6, could be reused at least for seven cycles without activity loss.

Original language	English
Pages (from-to)	331-336
Number of pages	6
Journal	Catalysis Letters
Volume	121
Issue number	3-4
DOIs	https://doi.org/10.1007/s10562-007-9343-y
State	Published - Mar 2008

Keywords

Functionalization
Heck reaction
Ionic liquids
Palladium catalyst

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10.1007/s10562-007-9343-y

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title = "Palladium-catalyzed heck reaction in the multi-functionalized ionic liquid compositions",

abstract = "In the multi-functionalized ionic liquid compositions (MFILC), composed of 1-n-butyl-2-diphenylphosphino-3-methylimidazolium hexafluorophosphate, [BDPPMIM]PF6), 1-(2-piperid-1-yl-ethyl)-3-methylimidazolium hexafluorophosphate, [PEMIM]PF6), and 1-n-butyl-3-methylimidazolium hexafluorophosphate ([BMIM]PF6), PdCl2 served as an efficient catalyst for Heck reactions of aryl iodides and bromides. The built-up PdCl2-MFILC, including stoichiometrically consumed base of [PEMIM]PF6, could be reused at least for seven cycles without activity loss.",

keywords = "Functionalization, Heck reaction, Ionic liquids, Palladium catalyst",

author = "Wan, \{Qing Xia\} and Ye Liu and Yong Lu and Min Li and Wu, \{Hai Hong\}",

year = "2008",

month = mar,

doi = "10.1007/s10562-007-9343-y",

language = "英语",

volume = "121",

pages = "331--336",

journal = "Catalysis Letters",

issn = "1011-372X",

publisher = "Kluwer Academic Publishers",

number = "3-4",

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TY - JOUR

T1 - Palladium-catalyzed heck reaction in the multi-functionalized ionic liquid compositions

AU - Wan, Qing Xia

AU - Liu, Ye

AU - Lu, Yong

AU - Li, Min

AU - Wu, Hai Hong

PY - 2008/3

Y1 - 2008/3

N2 - In the multi-functionalized ionic liquid compositions (MFILC), composed of 1-n-butyl-2-diphenylphosphino-3-methylimidazolium hexafluorophosphate, [BDPPMIM]PF6), 1-(2-piperid-1-yl-ethyl)-3-methylimidazolium hexafluorophosphate, [PEMIM]PF6), and 1-n-butyl-3-methylimidazolium hexafluorophosphate ([BMIM]PF6), PdCl2 served as an efficient catalyst for Heck reactions of aryl iodides and bromides. The built-up PdCl2-MFILC, including stoichiometrically consumed base of [PEMIM]PF6, could be reused at least for seven cycles without activity loss.

AB - In the multi-functionalized ionic liquid compositions (MFILC), composed of 1-n-butyl-2-diphenylphosphino-3-methylimidazolium hexafluorophosphate, [BDPPMIM]PF6), 1-(2-piperid-1-yl-ethyl)-3-methylimidazolium hexafluorophosphate, [PEMIM]PF6), and 1-n-butyl-3-methylimidazolium hexafluorophosphate ([BMIM]PF6), PdCl2 served as an efficient catalyst for Heck reactions of aryl iodides and bromides. The built-up PdCl2-MFILC, including stoichiometrically consumed base of [PEMIM]PF6, could be reused at least for seven cycles without activity loss.

KW - Functionalization

KW - Heck reaction

KW - Ionic liquids

KW - Palladium catalyst

UR - https://www.scopus.com/pages/publications/39149129072

U2 - 10.1007/s10562-007-9343-y

DO - 10.1007/s10562-007-9343-y

M3 - 文章

AN - SCOPUS:39149129072

SN - 1011-372X

VL - 121

SP - 331

EP - 336

JO - Catalysis Letters

JF - Catalysis Letters

IS - 3-4

ER -

Palladium-catalyzed heck reaction in the multi-functionalized ionic liquid compositions

Abstract

Keywords

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