Palladium-catalyzed allenylation/intramolecular diels-alder reaction of furans with propargyl carboxylates for the synthesis of polycyclic compounds

Yanzhong Li; Chengyu Wang; Lingkai Kong; Yanli Li

doi:10.1002/ejoc.201402059

Palladium-catalyzed allenylation/intramolecular diels-alder reaction of furans with propargyl carboxylates for the synthesis of polycyclic compounds

Yanzhong Li^*
, Chengyu Wang
, Lingkai Kong
, Yanli Li^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

A highly efficient palladium-catalyzed cascade reaction of propargyl carboxylates bearing a furanyl group with organoborons was developed. This methodology offers rapid access to polycyclic Diels-Alder cycloadducts in good to high yields. The thus-formed oxygen-bridged products were further converted into anthracene derivatives in a chemoselective manner under mild conditions.

Original language	English
Pages (from-to)	3556-3560
Number of pages	5
Journal	European Journal of Organic Chemistry
Volume	2014
Issue number	17
DOIs	https://doi.org/10.1002/ejoc.201402059
State	Published - Jun 2014

Keywords

Chemoselectivity
Cycloaddition
Domino reactions
Palladium
Polycycles
Synthetic methods

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10.1002/ejoc.201402059

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abstract = "A highly efficient palladium-catalyzed cascade reaction of propargyl carboxylates bearing a furanyl group with organoborons was developed. This methodology offers rapid access to polycyclic Diels-Alder cycloadducts in good to high yields. The thus-formed oxygen-bridged products were further converted into anthracene derivatives in a chemoselective manner under mild conditions.",

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AU - Li, Yanzhong

AU - Wang, Chengyu

AU - Kong, Lingkai

AU - Li, Yanli

PY - 2014/6

Y1 - 2014/6

N2 - A highly efficient palladium-catalyzed cascade reaction of propargyl carboxylates bearing a furanyl group with organoborons was developed. This methodology offers rapid access to polycyclic Diels-Alder cycloadducts in good to high yields. The thus-formed oxygen-bridged products were further converted into anthracene derivatives in a chemoselective manner under mild conditions.

AB - A highly efficient palladium-catalyzed cascade reaction of propargyl carboxylates bearing a furanyl group with organoborons was developed. This methodology offers rapid access to polycyclic Diels-Alder cycloadducts in good to high yields. The thus-formed oxygen-bridged products were further converted into anthracene derivatives in a chemoselective manner under mild conditions.

KW - Chemoselectivity

KW - Cycloaddition

KW - Domino reactions

KW - Palladium

KW - Polycycles

KW - Synthetic methods

UR - https://www.scopus.com/pages/publications/84901843525

U2 - 10.1002/ejoc.201402059

DO - 10.1002/ejoc.201402059

M3 - 文章

AN - SCOPUS:84901843525

SN - 1434-193X

VL - 2014

SP - 3556

EP - 3560

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 17

ER -

Palladium-catalyzed allenylation/intramolecular diels-alder reaction of furans with propargyl carboxylates for the synthesis of polycyclic compounds

Abstract

Keywords

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