Oxidation of styrene catalyzed by ionic manganese porphyrin immobilized in ionic liquid

Ye Liu; Hong Jiao Zhang; Hai Hong Wu; Xiu Li Liu; Yue Qin Cai; Yong Lu

Oxidation of styrene catalyzed by ionic manganese porphyrin immobilized in ionic liquid

Ye Liu^*
, Hong Jiao Zhang
, Hai Hong Wu
, Xiu Li Liu
, Yue Qin Cai
, Yong Lu

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Without the additional involvement of axial ligand and organic solvent, the ionic manganese porphyrin [Mn^III(BF₄)T(N-Me-4-Py)P] [BF₄]₄(1d) immobilized in [BMIM]BF₄ efficiently catalyzed the oxidation of styrene with a good activity (87% conv.) and epoxide selectivity (90%) under mild reaction conditions. The generality of 1d-[BMIM] BF₄ system to the substrates of styrene derivatives with different electronical effects also lead to the pleasing results. The degradation of metalloporphyrin coming from the π-π stacking of porphyrin itself and the oxidation destruction was greatly suppressed in this built-up 1d-[BMIM] BF₄ system.

Original language	English
Pages (from-to)	1523-1527
Number of pages	5
Journal	Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities
Volume	28
Issue number	8
State	Published - Aug 2007

Keywords

Catalytic oxidation
Ionic liquid
Porphyrin
Styrene

Cite this

@article{578facea27484faca3131995529eac67,

title = "Oxidation of styrene catalyzed by ionic manganese porphyrin immobilized in ionic liquid",

abstract = "Without the additional involvement of axial ligand and organic solvent, the ionic manganese porphyrin [MnIII(BF4)T(N-Me-4-Py)P] [BF4]4(1d) immobilized in [BMIM]BF4 efficiently catalyzed the oxidation of styrene with a good activity (87\% conv.) and epoxide selectivity (90\%) under mild reaction conditions. The generality of 1d-[BMIM] BF4 system to the substrates of styrene derivatives with different electronical effects also lead to the pleasing results. The degradation of metalloporphyrin coming from the π-π stacking of porphyrin itself and the oxidation destruction was greatly suppressed in this built-up 1d-[BMIM] BF4 system.",

keywords = "Catalytic oxidation, Ionic liquid, Porphyrin, Styrene",

author = "Ye Liu and Zhang, \{Hong Jiao\} and Wu, \{Hai Hong\} and Liu, \{Xiu Li\} and Cai, \{Yue Qin\} and Yong Lu",

year = "2007",

month = aug,

language = "英语",

volume = "28",

pages = "1523--1527",

journal = "Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities",

issn = "0251-0790",

publisher = "Higher Education Press Limited Company",

number = "8",

}

TY - JOUR

T1 - Oxidation of styrene catalyzed by ionic manganese porphyrin immobilized in ionic liquid

AU - Liu, Ye

AU - Zhang, Hong Jiao

AU - Wu, Hai Hong

AU - Liu, Xiu Li

AU - Cai, Yue Qin

AU - Lu, Yong

PY - 2007/8

Y1 - 2007/8

N2 - Without the additional involvement of axial ligand and organic solvent, the ionic manganese porphyrin [MnIII(BF4)T(N-Me-4-Py)P] [BF4]4(1d) immobilized in [BMIM]BF4 efficiently catalyzed the oxidation of styrene with a good activity (87% conv.) and epoxide selectivity (90%) under mild reaction conditions. The generality of 1d-[BMIM] BF4 system to the substrates of styrene derivatives with different electronical effects also lead to the pleasing results. The degradation of metalloporphyrin coming from the π-π stacking of porphyrin itself and the oxidation destruction was greatly suppressed in this built-up 1d-[BMIM] BF4 system.

AB - Without the additional involvement of axial ligand and organic solvent, the ionic manganese porphyrin [MnIII(BF4)T(N-Me-4-Py)P] [BF4]4(1d) immobilized in [BMIM]BF4 efficiently catalyzed the oxidation of styrene with a good activity (87% conv.) and epoxide selectivity (90%) under mild reaction conditions. The generality of 1d-[BMIM] BF4 system to the substrates of styrene derivatives with different electronical effects also lead to the pleasing results. The degradation of metalloporphyrin coming from the π-π stacking of porphyrin itself and the oxidation destruction was greatly suppressed in this built-up 1d-[BMIM] BF4 system.

KW - Catalytic oxidation

KW - Ionic liquid

KW - Porphyrin

KW - Styrene

UR - https://www.scopus.com/pages/publications/34648827350

M3 - 文章

AN - SCOPUS:34648827350

SN - 0251-0790

VL - 28

SP - 1523

EP - 1527

JO - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

JF - Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities

IS - 8

ER -

Oxidation of styrene catalyzed by ionic manganese porphyrin immobilized in ionic liquid

Abstract

Keywords

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