Oxalic acid as the: In situ carbon monoxide generator in palladium-catalyzed hydroxycarbonylation of arylhalides

Changdong Shao; Ailan Lu; Xiaoling Wang; Bo Zhou; Xiaohong Guan; Yanghui Zhang

doi:10.1039/c7ob01052d

Oxalic acid as the: In situ carbon monoxide generator in palladium-catalyzed hydroxycarbonylation of arylhalides

Changdong Shao
, Ailan Lu
, Xiaoling Wang
, Bo Zhou
, Xiaohong Guan
, Yanghui Zhang

Tongji University
Shanghai Key Laboratory of Chemical Assessment and Sustainability

Research output: Contribution to journal › Article › peer-review

41 Scopus citations

Abstract

An efficient palladium-catalyzed hydroxycarbonylation reaction of arylhalides using oxalic acid as a CO source has been developed. The reaction features high safety, low catalyst loading, and a broad substrate scope, and provides a safe and tractable approach to access a variety of aromatic carboxylic acid compounds. Mechanistic studies revealed the decomposition pattern of oxalic acid.

Original language	English
Pages (from-to)	5033-5040
Number of pages	8
Journal	Organic and Biomolecular Chemistry
Volume	15
Issue number	23
DOIs	https://doi.org/10.1039/c7ob01052d
State	Published - 2017
Externally published	Yes

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10.1039/c7ob01052d

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abstract = "An efficient palladium-catalyzed hydroxycarbonylation reaction of arylhalides using oxalic acid as a CO source has been developed. The reaction features high safety, low catalyst loading, and a broad substrate scope, and provides a safe and tractable approach to access a variety of aromatic carboxylic acid compounds. Mechanistic studies revealed the decomposition pattern of oxalic acid.",

author = "Changdong Shao and Ailan Lu and Xiaoling Wang and Bo Zhou and Xiaohong Guan and Yanghui Zhang",

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T2 - In situ carbon monoxide generator in palladium-catalyzed hydroxycarbonylation of arylhalides

AU - Shao, Changdong

AU - Lu, Ailan

AU - Wang, Xiaoling

AU - Zhou, Bo

AU - Guan, Xiaohong

AU - Zhang, Yanghui

N1 - Publisher Copyright: © The Royal Society of Chemistry 2017.

PY - 2017

Y1 - 2017

N2 - An efficient palladium-catalyzed hydroxycarbonylation reaction of arylhalides using oxalic acid as a CO source has been developed. The reaction features high safety, low catalyst loading, and a broad substrate scope, and provides a safe and tractable approach to access a variety of aromatic carboxylic acid compounds. Mechanistic studies revealed the decomposition pattern of oxalic acid.

AB - An efficient palladium-catalyzed hydroxycarbonylation reaction of arylhalides using oxalic acid as a CO source has been developed. The reaction features high safety, low catalyst loading, and a broad substrate scope, and provides a safe and tractable approach to access a variety of aromatic carboxylic acid compounds. Mechanistic studies revealed the decomposition pattern of oxalic acid.

UR - https://www.scopus.com/pages/publications/85021635608

U2 - 10.1039/c7ob01052d

DO - 10.1039/c7ob01052d

M3 - 文章

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AN - SCOPUS:85021635608

SN - 1477-0520

VL - 15

SP - 5033

EP - 5040

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 23

ER -

Oxalic acid as the: In situ carbon monoxide generator in palladium-catalyzed hydroxycarbonylation of arylhalides

Abstract

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