Organically doped palladium: A highly efficient catalyst for electroreduction of CO2 to methanol

Heng Pan Yang; Sen Qin; Huan Wang; Jia Xing Lu

doi:10.1039/c5gc01504a

Organically doped palladium: A highly efficient catalyst for electroreduction of CO₂ to methanol

Heng Pan Yang, Sen Qin, Huan Wang, Jia Xing Lu

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

67 Scopus citations

Abstract

A [PYD]@Pd composite was prepared by the entrapment of a pyridine derivative within metallic palladium. Metallic Pd acts as a heterogeneous support and a pyridine ring served as an active site for electroreduction of CO₂, and no additional catalyst was needed in the electrolyte. 35% Faradaic efficiency of methanol was obtained at only -0.6 V vs. SCE. Moreover, [PYD]@Pd has remarkable stability and reusability.

Original language	English
Pages (from-to)	5144-5148
Number of pages	5
Journal	Green Chemistry
Volume	17
Issue number	12
DOIs	https://doi.org/10.1039/c5gc01504a
State	Published - 31 Jul 2015

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title = "Organically doped palladium: A highly efficient catalyst for electroreduction of CO2 to methanol",

abstract = "A [PYD]@Pd composite was prepared by the entrapment of a pyridine derivative within metallic palladium. Metallic Pd acts as a heterogeneous support and a pyridine ring served as an active site for electroreduction of CO2, and no additional catalyst was needed in the electrolyte. 35\% Faradaic efficiency of methanol was obtained at only -0.6 V vs. SCE. Moreover, [PYD]@Pd has remarkable stability and reusability.",

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T2 - A highly efficient catalyst for electroreduction of CO2 to methanol

AU - Yang, Heng Pan

AU - Qin, Sen

AU - Wang, Huan

AU - Lu, Jia Xing

PY - 2015/7/31

Y1 - 2015/7/31

N2 - A [PYD]@Pd composite was prepared by the entrapment of a pyridine derivative within metallic palladium. Metallic Pd acts as a heterogeneous support and a pyridine ring served as an active site for electroreduction of CO2, and no additional catalyst was needed in the electrolyte. 35% Faradaic efficiency of methanol was obtained at only -0.6 V vs. SCE. Moreover, [PYD]@Pd has remarkable stability and reusability.

AB - A [PYD]@Pd composite was prepared by the entrapment of a pyridine derivative within metallic palladium. Metallic Pd acts as a heterogeneous support and a pyridine ring served as an active site for electroreduction of CO2, and no additional catalyst was needed in the electrolyte. 35% Faradaic efficiency of methanol was obtained at only -0.6 V vs. SCE. Moreover, [PYD]@Pd has remarkable stability and reusability.

UR - https://www.scopus.com/pages/publications/84948467956

U2 - 10.1039/c5gc01504a

DO - 10.1039/c5gc01504a

M3 - 文章

AN - SCOPUS:84948467956

SN - 1463-9262

VL - 17

SP - 5144

EP - 5148

JO - Green Chemistry

JF - Green Chemistry

IS - 12

ER -

Organically doped palladium: A highly efficient catalyst for electroreduction of CO₂ to methanol

Abstract

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