Optical Pd2+ sensing by rhodamine hydrazone ligands: Different stoichiometries in aqueous/nonaqueous environments

Honglin Li; Jianfang Cao; Hao Zhu; Jiangli Fan; Xiaojun Peng

doi:10.1016/j.tetlet.2013.05.094

Optical Pd²⁺ sensing by rhodamine hydrazone ligands: Different stoichiometries in aqueous/nonaqueous environments

Honglin Li
, Jianfang Cao
, Hao Zhu
, Jiangli Fan^*
, Xiaojun Peng

^*Corresponding author for this work

Dalian University of Technology

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

A series of rhodamine spiro-leuco compounds have been developed as fluorescence-enhanced sensors for optical sensing of palladium ion (Pd ²⁺). The initial rhodamine hydrazone derivatives, RPd1-a, RPd1-b, and RPd1-c, display a good coordination to Pd²⁺ inducing the spirolactam-open reaction with a significant fluorescence enhancement and color generation. Different stoichiometry results, 1:2 in EtOH/H₂O and 1:1 in MeOH/DCM were observed for Pd²⁺/RPd1-c complexation.

Original language	English
Pages (from-to)	4357-4361
Number of pages	5
Journal	Tetrahedron Letters
Volume	54
Issue number	33
DOIs	https://doi.org/10.1016/j.tetlet.2013.05.094
State	Published - 14 Aug 2013
Externally published	Yes

Keywords

Optical sensing
Palladium ion
Rhodamine hydrazone
Selectivity
Stoichiometry

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10.1016/j.tetlet.2013.05.094

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title = "Optical Pd2+ sensing by rhodamine hydrazone ligands: Different stoichiometries in aqueous/nonaqueous environments",

abstract = "A series of rhodamine spiro-leuco compounds have been developed as fluorescence-enhanced sensors for optical sensing of palladium ion (Pd 2+). The initial rhodamine hydrazone derivatives, RPd1-a, RPd1-b, and RPd1-c, display a good coordination to Pd2+ inducing the spirolactam-open reaction with a significant fluorescence enhancement and color generation. Different stoichiometry results, 1:2 in EtOH/H2O and 1:1 in MeOH/DCM were observed for Pd2+/RPd1-c complexation.",

keywords = "Optical sensing, Palladium ion, Rhodamine hydrazone, Selectivity, Stoichiometry",

author = "Honglin Li and Jianfang Cao and Hao Zhu and Jiangli Fan and Xiaojun Peng",

year = "2013",

month = aug,

day = "14",

doi = "10.1016/j.tetlet.2013.05.094",

language = "英语",

volume = "54",

pages = "4357--4361",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Ltd",

number = "33",

}

TY - JOUR

T1 - Optical Pd2+ sensing by rhodamine hydrazone ligands

T2 - Different stoichiometries in aqueous/nonaqueous environments

AU - Li, Honglin

AU - Cao, Jianfang

AU - Zhu, Hao

AU - Fan, Jiangli

AU - Peng, Xiaojun

PY - 2013/8/14

Y1 - 2013/8/14

N2 - A series of rhodamine spiro-leuco compounds have been developed as fluorescence-enhanced sensors for optical sensing of palladium ion (Pd 2+). The initial rhodamine hydrazone derivatives, RPd1-a, RPd1-b, and RPd1-c, display a good coordination to Pd2+ inducing the spirolactam-open reaction with a significant fluorescence enhancement and color generation. Different stoichiometry results, 1:2 in EtOH/H2O and 1:1 in MeOH/DCM were observed for Pd2+/RPd1-c complexation.

AB - A series of rhodamine spiro-leuco compounds have been developed as fluorescence-enhanced sensors for optical sensing of palladium ion (Pd 2+). The initial rhodamine hydrazone derivatives, RPd1-a, RPd1-b, and RPd1-c, display a good coordination to Pd2+ inducing the spirolactam-open reaction with a significant fluorescence enhancement and color generation. Different stoichiometry results, 1:2 in EtOH/H2O and 1:1 in MeOH/DCM were observed for Pd2+/RPd1-c complexation.

KW - Optical sensing

KW - Palladium ion

KW - Rhodamine hydrazone

KW - Selectivity

KW - Stoichiometry

UR - https://www.scopus.com/pages/publications/84880042070

U2 - 10.1016/j.tetlet.2013.05.094

DO - 10.1016/j.tetlet.2013.05.094

M3 - 文章

AN - SCOPUS:84880042070

SN - 0040-4039

VL - 54

SP - 4357

EP - 4361

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 33

ER -

Optical Pd²⁺ sensing by rhodamine hydrazone ligands: Different stoichiometries in aqueous/nonaqueous environments

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Keywords

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