Optical nonlinear properties of metal cluster [PPh4] [C*pWS3(CuBr)3(dppm)]

Xiao Rong Zhu; Rui Min Niu; Zhen Rong Sun; He Ping Zeng; Zu Geng Wang; Jian Ping Lang

doi:10.1016/S0009-2614(03)00433-0

Optical nonlinear properties of metal cluster [PPh₄] [C*_pWS₃(CuBr)₃(dppm)]

Xiao Rong Zhu
, Rui Min Niu
, Zhen Rong Sun^*
, He Ping Zeng
, Zu Geng Wang
, Jian Ping Lang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

We report the nonlinear optical properties of one metal cluster [PPh₄][C^*_pWS₃(CuBr) ₃(dppm)] by picosecond and nanosecond laser pulses. The third-order nonlinear susceptibility χ⁽³⁾ is measured by degenerate four-wave mixing, the nonlinear absorption by the Z-scan technique, and optical limiting response by the transmission technique. The experimental data are theoretically fitted, and the mechanism for the third-order optical nonlinearities and the optical limiting properties are discussed, and the absorption cross sections of the ground state and the excited state are evaluated by a rate equation model.

Original language	English
Pages (from-to)	524-528
Number of pages	5
Journal	Chemical Physics Letters
Volume	372
Issue number	3-4
DOIs	https://doi.org/10.1016/S0009-2614(03)00433-0
State	Published - 29 Apr 2003
Externally published	Yes

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10.1016/S0009-2614(03)00433-0

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@article{ab87db1742f04cc69ad1a2ee040ed078,

title = "Optical nonlinear properties of metal cluster [PPh4] [C*pWS3(CuBr)3(dppm)]",

abstract = "We report the nonlinear optical properties of one metal cluster [PPh4][C*pWS3(CuBr) 3(dppm)] by picosecond and nanosecond laser pulses. The third-order nonlinear susceptibility χ(3) is measured by degenerate four-wave mixing, the nonlinear absorption by the Z-scan technique, and optical limiting response by the transmission technique. The experimental data are theoretically fitted, and the mechanism for the third-order optical nonlinearities and the optical limiting properties are discussed, and the absorption cross sections of the ground state and the excited state are evaluated by a rate equation model.",

author = "Zhu, \{Xiao Rong\} and Niu, \{Rui Min\} and Sun, \{Zhen Rong\} and Zeng, \{He Ping\} and Wang, \{Zu Geng\} and Lang, \{Jian Ping\}",

year = "2003",

month = apr,

day = "29",

doi = "10.1016/S0009-2614(03)00433-0",

language = "英语",

volume = "372",

pages = "524--528",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

number = "3-4",

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TY - JOUR

T1 - Optical nonlinear properties of metal cluster [PPh4] [C*pWS3(CuBr)3(dppm)]

AU - Zhu, Xiao Rong

AU - Niu, Rui Min

AU - Sun, Zhen Rong

AU - Zeng, He Ping

AU - Wang, Zu Geng

AU - Lang, Jian Ping

PY - 2003/4/29

Y1 - 2003/4/29

N2 - We report the nonlinear optical properties of one metal cluster [PPh4][C*pWS3(CuBr) 3(dppm)] by picosecond and nanosecond laser pulses. The third-order nonlinear susceptibility χ(3) is measured by degenerate four-wave mixing, the nonlinear absorption by the Z-scan technique, and optical limiting response by the transmission technique. The experimental data are theoretically fitted, and the mechanism for the third-order optical nonlinearities and the optical limiting properties are discussed, and the absorption cross sections of the ground state and the excited state are evaluated by a rate equation model.

AB - We report the nonlinear optical properties of one metal cluster [PPh4][C*pWS3(CuBr) 3(dppm)] by picosecond and nanosecond laser pulses. The third-order nonlinear susceptibility χ(3) is measured by degenerate four-wave mixing, the nonlinear absorption by the Z-scan technique, and optical limiting response by the transmission technique. The experimental data are theoretically fitted, and the mechanism for the third-order optical nonlinearities and the optical limiting properties are discussed, and the absorption cross sections of the ground state and the excited state are evaluated by a rate equation model.

UR - https://www.scopus.com/pages/publications/0037472144

U2 - 10.1016/S0009-2614(03)00433-0

DO - 10.1016/S0009-2614(03)00433-0

M3 - 文章

AN - SCOPUS:0037472144

SN - 0009-2614

VL - 372

SP - 524

EP - 528

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 3-4

ER -

Optical nonlinear properties of metal cluster [PPh₄] [C*_pWS₃(CuBr)₃(dppm)]

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