Optical limiting response in a unsymmetrical dithiolene metal complex (Me4N)2[Zn(dmit)(Sph)2]

Zhenrong Sun; Minghong Tong; Heping Zeng; Liangen Ding; Zugeng Wang; Zhizhan Xu; Jie Dai; Guoqing Bian

doi:10.1016/S0009-2614(01)00614-5

Optical limiting response in a unsymmetrical dithiolene metal complex (Me₄N)₂[Zn(dmit)(Sph)₂]

Zhenrong Sun^*
, Minghong Tong
, Heping Zeng
, Liangen Ding
, Zugeng Wang
, Zhizhan Xu
, Jie Dai
, Guoqing Bian

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

We report the measurements of reverse saturable absorption (RSA) and optical limiting responses in a unsymmetric dithiolene metal complex (Me₄N)₂[Zn(dmit)(Sph)₂] with nanosecond and picosecond laser pulses at 532 nm. The experimental results show that the triplet-triplet absorption is responsible for the measured RSA, resulting in optical limiting responses. The measured data can be well simulated by a rate equation model to obtain the absorption cross-section of the excited state.

Original language	English
Pages (from-to)	323-327
Number of pages	5
Journal	Chemical Physics Letters
Volume	342
Issue number	3-4
DOIs	https://doi.org/10.1016/S0009-2614(01)00614-5
State	Published - 13 Jul 2001
Externally published	Yes

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title = "Optical limiting response in a unsymmetrical dithiolene metal complex (Me4N)2[Zn(dmit)(Sph)2]",

abstract = "We report the measurements of reverse saturable absorption (RSA) and optical limiting responses in a unsymmetric dithiolene metal complex (Me4N)2[Zn(dmit)(Sph)2] with nanosecond and picosecond laser pulses at 532 nm. The experimental results show that the triplet-triplet absorption is responsible for the measured RSA, resulting in optical limiting responses. The measured data can be well simulated by a rate equation model to obtain the absorption cross-section of the excited state.",

author = "Zhenrong Sun and Minghong Tong and Heping Zeng and Liangen Ding and Zugeng Wang and Zhizhan Xu and Jie Dai and Guoqing Bian",

year = "2001",

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doi = "10.1016/S0009-2614(01)00614-5",

language = "英语",

volume = "342",

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T1 - Optical limiting response in a unsymmetrical dithiolene metal complex (Me4N)2[Zn(dmit)(Sph)2]

AU - Sun, Zhenrong

AU - Tong, Minghong

AU - Zeng, Heping

AU - Ding, Liangen

AU - Wang, Zugeng

AU - Xu, Zhizhan

AU - Dai, Jie

AU - Bian, Guoqing

PY - 2001/7/13

Y1 - 2001/7/13

N2 - We report the measurements of reverse saturable absorption (RSA) and optical limiting responses in a unsymmetric dithiolene metal complex (Me4N)2[Zn(dmit)(Sph)2] with nanosecond and picosecond laser pulses at 532 nm. The experimental results show that the triplet-triplet absorption is responsible for the measured RSA, resulting in optical limiting responses. The measured data can be well simulated by a rate equation model to obtain the absorption cross-section of the excited state.

AB - We report the measurements of reverse saturable absorption (RSA) and optical limiting responses in a unsymmetric dithiolene metal complex (Me4N)2[Zn(dmit)(Sph)2] with nanosecond and picosecond laser pulses at 532 nm. The experimental results show that the triplet-triplet absorption is responsible for the measured RSA, resulting in optical limiting responses. The measured data can be well simulated by a rate equation model to obtain the absorption cross-section of the excited state.

UR - https://www.scopus.com/pages/publications/0013102120

U2 - 10.1016/S0009-2614(01)00614-5

DO - 10.1016/S0009-2614(01)00614-5

M3 - 文章

AN - SCOPUS:0013102120

SN - 0009-2614

VL - 342

SP - 323

EP - 327

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 3-4

ER -

Optical limiting response in a unsymmetrical dithiolene metal complex (Me₄N)₂[Zn(dmit)(Sph)₂]

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