Optical and electric properties of poly (vinylidene fluoried-trifluoroethylene) thin film by Langmuir-Blodgett technique

  • Jian Lu Wang*
  • , Xiang Jian Meng
  • , Yan Qing Gao
  • , Zhi Ming Huang
  • , Hong Shen
  • , Jing Lan Sun
  • , Jun Hao Chu
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

Poly (vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE)) thin films were deposited on polyimide substrate using horizontal Langmuir-Blodgett(LB) technology. X-ray diffractions indicate that the films have good crystallinity with (110) preferential orientation for films with different thickness. The optical dispersion of the films were measured by variable-angle spectroscopic ellipsometry. The data ψ and Δ at multiple incident angels (θ=75° and 85°) were fitted using the Cauchy model. The refractive index, extinction coefficient, absorption coefficient and thickness of each film were obtained. The ferroelectric of the films were studied. The remnant polarization is up to 6.3μC/cm2. The coercive field is 100MV/cm. The dielectric measurement for the film shows two distinctive phase transitions, ferroelectric-paraelectric phase transition and β relaxation.

Original languageEnglish
Pages (from-to)406-409+456
JournalHongwai Yu Haomibo Xuebao/Journal of Infrared and Millimeter Waves
Volume29
Issue number6
StatePublished - Dec 2010
Externally publishedYes

Keywords

  • Electric property
  • Langmuir-Blodgett technology
  • P(VDF-TrFE) films
  • Spectroscopic ellipsometry

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