"open" Nonporous Nonasil Zeolite Structure for Selective Catalysis

Kun Lu; Yaqi Fan; Ju Huang; Jilong Wang; Hao Xu; Jingang Jiang; Yanhang Ma; Peng Wu

doi:10.1021/jacs.1c08768

"open" Nonporous Nonasil Zeolite Structure for Selective Catalysis

Kun Lu, Yaqi Fan, Ju Huang, Jilong Wang, Hao Xu, Jingang Jiang, Yanhang Ma, Peng Wu

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Nonasil (NON-type framework) zeolite, having inner large cages but only 6-ring (R) apertures, is recognized as a nonporous material without practical application values as catalysts or adsorbents. A novel bottom-up structural construction strategy assisted with well-designed Gemini-type surfactant is proposed to "open"the non cages, constructing two novel NON-related structures with accessible and stable acid sites. The obtained derivant (named as ECNU-27) possessed hierarchical porosity with short-range ordered 8-R micropores and abundant intercrystal mesopores, serving as a promising catalyst for the 1-butene cracking to lower alkenes.

Original language	English
Pages (from-to)	20569-20573
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	143
Issue number	49
DOIs	https://doi.org/10.1021/jacs.1c08768
State	Published - 15 Dec 2021

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10.1021/jacs.1c08768

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abstract = "Nonasil (NON-type framework) zeolite, having inner large cages but only 6-ring (R) apertures, is recognized as a nonporous material without practical application values as catalysts or adsorbents. A novel bottom-up structural construction strategy assisted with well-designed Gemini-type surfactant is proposed to {"}open{"}the non cages, constructing two novel NON-related structures with accessible and stable acid sites. The obtained derivant (named as ECNU-27) possessed hierarchical porosity with short-range ordered 8-R micropores and abundant intercrystal mesopores, serving as a promising catalyst for the 1-butene cracking to lower alkenes.",

author = "Kun Lu and Yaqi Fan and Ju Huang and Jilong Wang and Hao Xu and Jingang Jiang and Yanhang Ma and Peng Wu",

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AU - Lu, Kun

AU - Fan, Yaqi

AU - Huang, Ju

AU - Wang, Jilong

AU - Xu, Hao

AU - Jiang, Jingang

AU - Ma, Yanhang

AU - Wu, Peng

PY - 2021/12/15

Y1 - 2021/12/15

N2 - Nonasil (NON-type framework) zeolite, having inner large cages but only 6-ring (R) apertures, is recognized as a nonporous material without practical application values as catalysts or adsorbents. A novel bottom-up structural construction strategy assisted with well-designed Gemini-type surfactant is proposed to "open"the non cages, constructing two novel NON-related structures with accessible and stable acid sites. The obtained derivant (named as ECNU-27) possessed hierarchical porosity with short-range ordered 8-R micropores and abundant intercrystal mesopores, serving as a promising catalyst for the 1-butene cracking to lower alkenes.

AB - Nonasil (NON-type framework) zeolite, having inner large cages but only 6-ring (R) apertures, is recognized as a nonporous material without practical application values as catalysts or adsorbents. A novel bottom-up structural construction strategy assisted with well-designed Gemini-type surfactant is proposed to "open"the non cages, constructing two novel NON-related structures with accessible and stable acid sites. The obtained derivant (named as ECNU-27) possessed hierarchical porosity with short-range ordered 8-R micropores and abundant intercrystal mesopores, serving as a promising catalyst for the 1-butene cracking to lower alkenes.

UR - https://www.scopus.com/pages/publications/85120322603

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M3 - 文章

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AN - SCOPUS:85120322603

SN - 0002-7863

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EP - 20573

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 49

ER -

"open" Nonporous Nonasil Zeolite Structure for Selective Catalysis

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