Open-framework borophosphate: (NH4)0.5Fe II0.5FeIII0.5•(H 2O)2 BP2O8•0.5 H2O

Heng Zhen Shi; Yong Kui Shan; Li Yi Dai; Yu Yan Liu

Open-framework borophosphate: (NH₄)_0.5Fe ^II_0.5Fe^III_0.5•(H ₂O)₂ BP₂O₈•0.5 H₂O

Heng Zhen Shi^*
, Yong Kui Shan
, Li Yi Dai
, Yu Yan Liu

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

An open-framework ammonium ferricborophosphate compound was synthesized by mild hydrothermal condition at 110°C. The crystal structure has been determined by single-crystal X-ray diffraction analysis: hexagonal, P6 ₅22, a = 9.452(2) Å, c = 15.698(5) Å, α = 90°, γ = 120°, Z = 6, M_r = 310.58, V = 1214.0(5) Å ³, D_c = 2.549 g/cm³, μ = 2.311 mm ^-1, F(000) = 930. The chiral tetrahedral-tetrahedral helical ribbons are linked by the mixed valance Fe^II/Fe^IIIO₆ coordinated octahedra. The ammonium ions are located reside the free loop of helical ribbons close to the inner wall of the helical channels ∞ ¹ {[BP₂O₈]^3-}, effecting on balancing charge and stabilizing helical ribbons.

Original language	English
Pages (from-to)	744-747
Number of pages	4
Journal	Chinese Chemical Letters
Volume	14
Issue number	7
State	Published - 1 Jul 2003

Keywords

Borophosphate
Open-framework
Single crystal
Synthesis

Cite this

@article{430b0f401bc64ee8b41315e96cc79e46,

title = "Open-framework borophosphate: (NH4)0.5Fe II0.5FeIII0.5•(H 2O)2 BP2O8•0.5 H2O",

abstract = "An open-framework ammonium ferricborophosphate compound was synthesized by mild hydrothermal condition at 110°C. The crystal structure has been determined by single-crystal X-ray diffraction analysis: hexagonal, P6 522, a = 9.452(2) {\AA}, c = 15.698(5) {\AA}, α = 90°, γ = 120°, Z = 6, Mr = 310.58, V = 1214.0(5) {\AA} 3, Dc = 2.549 g/cm3, μ = 2.311 mm -1, F(000) = 930. The chiral tetrahedral-tetrahedral helical ribbons are linked by the mixed valance FeII/FeIIIO6 coordinated octahedra. The ammonium ions are located reside the free loop of helical ribbons close to the inner wall of the helical channels ∞ 1 \{[BP2O8]3-\}, effecting on balancing charge and stabilizing helical ribbons.",

keywords = "Borophosphate, Open-framework, Single crystal, Synthesis",

author = "Shi, \{Heng Zhen\} and Shan, \{Yong Kui\} and Dai, \{Li Yi\} and Liu, \{Yu Yan\}",

year = "2003",

month = jul,

day = "1",

language = "英语",

volume = "14",

pages = "744--747",

journal = "Chinese Chemical Letters",

issn = "1001-8417",

publisher = "Elsevier B.V.",

number = "7",

}

TY - JOUR

T1 - Open-framework borophosphate

T2 - (NH4)0.5Fe II0.5FeIII0.5•(H 2O)2 BP2O8•0.5 H2O

AU - Shi, Heng Zhen

AU - Shan, Yong Kui

AU - Dai, Li Yi

AU - Liu, Yu Yan

PY - 2003/7/1

Y1 - 2003/7/1

N2 - An open-framework ammonium ferricborophosphate compound was synthesized by mild hydrothermal condition at 110°C. The crystal structure has been determined by single-crystal X-ray diffraction analysis: hexagonal, P6 522, a = 9.452(2) Å, c = 15.698(5) Å, α = 90°, γ = 120°, Z = 6, Mr = 310.58, V = 1214.0(5) Å 3, Dc = 2.549 g/cm3, μ = 2.311 mm -1, F(000) = 930. The chiral tetrahedral-tetrahedral helical ribbons are linked by the mixed valance FeII/FeIIIO6 coordinated octahedra. The ammonium ions are located reside the free loop of helical ribbons close to the inner wall of the helical channels ∞ 1 {[BP2O8]3-}, effecting on balancing charge and stabilizing helical ribbons.

AB - An open-framework ammonium ferricborophosphate compound was synthesized by mild hydrothermal condition at 110°C. The crystal structure has been determined by single-crystal X-ray diffraction analysis: hexagonal, P6 522, a = 9.452(2) Å, c = 15.698(5) Å, α = 90°, γ = 120°, Z = 6, Mr = 310.58, V = 1214.0(5) Å 3, Dc = 2.549 g/cm3, μ = 2.311 mm -1, F(000) = 930. The chiral tetrahedral-tetrahedral helical ribbons are linked by the mixed valance FeII/FeIIIO6 coordinated octahedra. The ammonium ions are located reside the free loop of helical ribbons close to the inner wall of the helical channels ∞ 1 {[BP2O8]3-}, effecting on balancing charge and stabilizing helical ribbons.

KW - Borophosphate

KW - Open-framework

KW - Single crystal

KW - Synthesis

UR - https://www.scopus.com/pages/publications/0042378513

M3 - 文章

AN - SCOPUS:0042378513

SN - 1001-8417

VL - 14

SP - 744

EP - 747

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 7

ER -

Open-framework borophosphate: (NH₄)_0.5Fe ^II_0.5Fe^III_0.5•(H ₂O)₂ BP₂O₈•0.5 H₂O

Abstract

Keywords

Other files and links

Fingerprint

Cite this