One-step synthesis of large pore mesoporous metallo-aluminophosphates under nonaqueous media

L. Wang; B. Tian; J. Fan; C. Yu; B. Tu; D. Zhao

doi:10.1016/s0167-2991(04)80931-5

One-step synthesis of large pore mesoporous metallo-aluminophosphates under nonaqueous media

L. Wang
, B. Tian
, J. Fan
, C. Yu
, B. Tu^*
, D. Zhao

^*Corresponding author for this work

Fudan University

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

The simple and generalized one-step synthesis of large pore mesoporous metallo-aluminophosphates (MeAPOs) by using "acid-base pairs" route and nonionic block copolymer surfactant F127 as a template under non-aqueous media is described. By using this method, a series of transition and rare earth metals (e.g. Fe, Co, Ni, Cu, Zn, Mn, Sn, Sb, B, Cr, Nd, Y, Ce) can be introduced into the framework of aluminophosphates with tunable Me/Al ratio (0 ∼ 0.4) and disperse evenly without the formation of bulky metal oxides crystals. The products (MeAPOs) have large mesopore (up to 7 nm) and show good thermal stability (up to 550°C), suggesting this one-step method is a general and effective way in the synthesis of mesoporous metallo-aluminophosphates.

Original language	English
Pages (from-to)	1111-1117
Number of pages	7
Journal	Studies in Surface Science and Catalysis
Volume	154 A
DOIs	https://doi.org/10.1016/s0167-2991(04)80931-5
State	Published - 2004
Externally published	Yes

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title = "One-step synthesis of large pore mesoporous metallo-aluminophosphates under nonaqueous media",

abstract = "The simple and generalized one-step synthesis of large pore mesoporous metallo-aluminophosphates (MeAPOs) by using {"}acid-base pairs{"} route and nonionic block copolymer surfactant F127 as a template under non-aqueous media is described. By using this method, a series of transition and rare earth metals (e.g. Fe, Co, Ni, Cu, Zn, Mn, Sn, Sb, B, Cr, Nd, Y, Ce) can be introduced into the framework of aluminophosphates with tunable Me/Al ratio (0 ∼ 0.4) and disperse evenly without the formation of bulky metal oxides crystals. The products (MeAPOs) have large mesopore (up to 7 nm) and show good thermal stability (up to 550°C), suggesting this one-step method is a general and effective way in the synthesis of mesoporous metallo-aluminophosphates.",

author = "L. Wang and B. Tian and J. Fan and C. Yu and B. Tu and D. Zhao",

year = "2004",

doi = "10.1016/s0167-2991(04)80931-5",

language = "英语",

volume = "154 A",

pages = "1111--1117",

journal = "Studies in Surface Science and Catalysis",

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TY - JOUR

T1 - One-step synthesis of large pore mesoporous metallo-aluminophosphates under nonaqueous media

AU - Wang, L.

AU - Tian, B.

AU - Fan, J.

AU - Yu, C.

AU - Tu, B.

AU - Zhao, D.

PY - 2004

Y1 - 2004

N2 - The simple and generalized one-step synthesis of large pore mesoporous metallo-aluminophosphates (MeAPOs) by using "acid-base pairs" route and nonionic block copolymer surfactant F127 as a template under non-aqueous media is described. By using this method, a series of transition and rare earth metals (e.g. Fe, Co, Ni, Cu, Zn, Mn, Sn, Sb, B, Cr, Nd, Y, Ce) can be introduced into the framework of aluminophosphates with tunable Me/Al ratio (0 ∼ 0.4) and disperse evenly without the formation of bulky metal oxides crystals. The products (MeAPOs) have large mesopore (up to 7 nm) and show good thermal stability (up to 550°C), suggesting this one-step method is a general and effective way in the synthesis of mesoporous metallo-aluminophosphates.

AB - The simple and generalized one-step synthesis of large pore mesoporous metallo-aluminophosphates (MeAPOs) by using "acid-base pairs" route and nonionic block copolymer surfactant F127 as a template under non-aqueous media is described. By using this method, a series of transition and rare earth metals (e.g. Fe, Co, Ni, Cu, Zn, Mn, Sn, Sb, B, Cr, Nd, Y, Ce) can be introduced into the framework of aluminophosphates with tunable Me/Al ratio (0 ∼ 0.4) and disperse evenly without the formation of bulky metal oxides crystals. The products (MeAPOs) have large mesopore (up to 7 nm) and show good thermal stability (up to 550°C), suggesting this one-step method is a general and effective way in the synthesis of mesoporous metallo-aluminophosphates.

UR - https://www.scopus.com/pages/publications/11844262629

U2 - 10.1016/s0167-2991(04)80931-5

DO - 10.1016/s0167-2991(04)80931-5

M3 - 文章

AN - SCOPUS:11844262629

SN - 0167-2991

VL - 154 A

SP - 1111

EP - 1117

JO - Studies in Surface Science and Catalysis

JF - Studies in Surface Science and Catalysis

ER -

One-step synthesis of large pore mesoporous metallo-aluminophosphates under nonaqueous media

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