One-Step synthesis of acetals from phenol/alcohols mixtures using a Pd/Aluminoborate catalyst

Yejun Guan; Damin Zhang; Yimeng Wang

doi:10.1007/s10562-012-0891-4

One-Step synthesis of acetals from phenol/alcohols mixtures using a Pd/Aluminoborate catalyst

Yejun Guan^*
, Damin Zhang
, Yimeng Wang

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A one-step synthesis of cyclohexanone acetals from phenol/alcohol mixtures has been explored using bifunctional aluminum borates supported Pd catalysts. Three aluminum borates have been prepared via either a high temperature calcination (9Al ₂O ₃·2B ₂O ₃) or a selfpressured thermal synthesis (PKU-1 and ABO-X) using various aluminum precursors and boric acid. Well dispersed Pd nanoparticles loaded on these materials show excellent phenol hydrogenation activity in both water and ethanol. The reactivity follows the trend of Pd/ABOX[ Pd/9Al ₂O ₃·2B ₂O ₃[Pd/PKU-1, which is similar to the sequence of BO ₄/BO ₃ ratio presented in the aluminoborates as shown by NMR spectra. When ethanol is used as a solvent, 13.5 % yield of cyclohexanone diethyl acetal has been obtained under the conditions investigated on Pd/ ABO-X, which is attributed to its high activity in both hydrogenation and acetalization for the one-step synthesis of cyclohexanone acetals.

Original language	English
Pages (from-to)	1225-1233
Number of pages	9
Journal	Catalysis Letters
Volume	142
Issue number	10
DOIs	https://doi.org/10.1007/s10562-012-0891-4
State	Published - Oct 2012

Keywords

Acetalization
Aluminum borate
Cyclohexanone
Palladium
Phenol hydrogenation

Access to Document

10.1007/s10562-012-0891-4

Cite this

@article{54a33b7d4f1e440e886417c8e7ad6684,

title = "One-Step synthesis of acetals from phenol/alcohols mixtures using a Pd/Aluminoborate catalyst",

abstract = "A one-step synthesis of cyclohexanone acetals from phenol/alcohol mixtures has been explored using bifunctional aluminum borates supported Pd catalysts. Three aluminum borates have been prepared via either a high temperature calcination (9Al 2O 3·2B 2O 3) or a selfpressured thermal synthesis (PKU-1 and ABO-X) using various aluminum precursors and boric acid. Well dispersed Pd nanoparticles loaded on these materials show excellent phenol hydrogenation activity in both water and ethanol. The reactivity follows the trend of Pd/ABOX[ Pd/9Al 2O 3·2B 2O 3[Pd/PKU-1, which is similar to the sequence of BO 4/BO 3 ratio presented in the aluminoborates as shown by NMR spectra. When ethanol is used as a solvent, 13.5 \% yield of cyclohexanone diethyl acetal has been obtained under the conditions investigated on Pd/ ABO-X, which is attributed to its high activity in both hydrogenation and acetalization for the one-step synthesis of cyclohexanone acetals.",

keywords = "Acetalization, Aluminum borate, Cyclohexanone, Palladium, Phenol hydrogenation",

author = "Yejun Guan and Damin Zhang and Yimeng Wang",

year = "2012",

month = oct,

doi = "10.1007/s10562-012-0891-4",

language = "英语",

volume = "142",

pages = "1225--1233",

journal = "Catalysis Letters",

issn = "1011-372X",

publisher = "Kluwer Academic Publishers",

number = "10",

}

TY - JOUR

T1 - One-Step synthesis of acetals from phenol/alcohols mixtures using a Pd/Aluminoborate catalyst

AU - Guan, Yejun

AU - Zhang, Damin

AU - Wang, Yimeng

PY - 2012/10

Y1 - 2012/10

N2 - A one-step synthesis of cyclohexanone acetals from phenol/alcohol mixtures has been explored using bifunctional aluminum borates supported Pd catalysts. Three aluminum borates have been prepared via either a high temperature calcination (9Al 2O 3·2B 2O 3) or a selfpressured thermal synthesis (PKU-1 and ABO-X) using various aluminum precursors and boric acid. Well dispersed Pd nanoparticles loaded on these materials show excellent phenol hydrogenation activity in both water and ethanol. The reactivity follows the trend of Pd/ABOX[ Pd/9Al 2O 3·2B 2O 3[Pd/PKU-1, which is similar to the sequence of BO 4/BO 3 ratio presented in the aluminoborates as shown by NMR spectra. When ethanol is used as a solvent, 13.5 % yield of cyclohexanone diethyl acetal has been obtained under the conditions investigated on Pd/ ABO-X, which is attributed to its high activity in both hydrogenation and acetalization for the one-step synthesis of cyclohexanone acetals.

AB - A one-step synthesis of cyclohexanone acetals from phenol/alcohol mixtures has been explored using bifunctional aluminum borates supported Pd catalysts. Three aluminum borates have been prepared via either a high temperature calcination (9Al 2O 3·2B 2O 3) or a selfpressured thermal synthesis (PKU-1 and ABO-X) using various aluminum precursors and boric acid. Well dispersed Pd nanoparticles loaded on these materials show excellent phenol hydrogenation activity in both water and ethanol. The reactivity follows the trend of Pd/ABOX[ Pd/9Al 2O 3·2B 2O 3[Pd/PKU-1, which is similar to the sequence of BO 4/BO 3 ratio presented in the aluminoborates as shown by NMR spectra. When ethanol is used as a solvent, 13.5 % yield of cyclohexanone diethyl acetal has been obtained under the conditions investigated on Pd/ ABO-X, which is attributed to its high activity in both hydrogenation and acetalization for the one-step synthesis of cyclohexanone acetals.

KW - Acetalization

KW - Aluminum borate

KW - Cyclohexanone

KW - Palladium

KW - Phenol hydrogenation

UR - https://www.scopus.com/pages/publications/84868475818

U2 - 10.1007/s10562-012-0891-4

DO - 10.1007/s10562-012-0891-4

M3 - 文章

AN - SCOPUS:84868475818

SN - 1011-372X

VL - 142

SP - 1225

EP - 1233

JO - Catalysis Letters

JF - Catalysis Letters

IS - 10

ER -

One-Step synthesis of acetals from phenol/alcohols mixtures using a Pd/Aluminoborate catalyst

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this