One-pot synthesis of polymeric nanoparticle by ring-opening metathesis polymerization

Liya Zhang; Chunmei Song; Jiahui Yu; Dan Yang; Meiran Xie

doi:10.1002/pola.24323

One-pot synthesis of polymeric nanoparticle by ring-opening metathesis polymerization

Liya Zhang
, Chunmei Song
, Jiahui Yu^*
, Dan Yang
, Meiran Xie

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

Shell-functionalized polymeric nanoparticle was prepared through the method of polymerization-induced self-assembly of block copolymers [poly(2,3-bis(2-bromoisobutyryloxymethyl)-5-norbornene)-block-poly(7-oxanorborn- 5-ene-exo-exo-2,3-dicarboxylic acid dimethyl ester), PBNBE-b-PONBDM] via one-pot ring-opening metathesis polymerization of 2,3-bis(2-bromoisobutyryloxymethyl)- 5-norbornene (BNBE) and 7-oxanorborn-5-ene-exo-exo-2,3-dicarboxylic acid dimethyl ester (ONBDM) in a selective solvent. The compositions and the molecular weights of the copolymers were estimated by ¹H-NMR and gel permeation chromatography. The micelles were characterized by dynamic light scattering, transmission electron micrograph, and atomic force microscopy. The results indicated that the spherical micelles constructed with bromine-bearing PBNBE shell and PONBDM core were stable and reproducible in toluene.

Original language	English
Pages (from-to)	5231-5238
Number of pages	8
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	48
Issue number	22
DOIs	https://doi.org/10.1002/pola.24323
State	Published - 15 Nov 2010

Keywords

one-pot synthesis
polymeric nanoparticles
polymerization-induced self-assembly
ring-opening metathesis polymerization (ROMP)

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title = "One-pot synthesis of polymeric nanoparticle by ring-opening metathesis polymerization",

abstract = "Shell-functionalized polymeric nanoparticle was prepared through the method of polymerization-induced self-assembly of block copolymers [poly(2,3-bis(2-bromoisobutyryloxymethyl)-5-norbornene)-block-poly(7-oxanorborn- 5-ene-exo-exo-2,3-dicarboxylic acid dimethyl ester), PBNBE-b-PONBDM] via one-pot ring-opening metathesis polymerization of 2,3-bis(2-bromoisobutyryloxymethyl)- 5-norbornene (BNBE) and 7-oxanorborn-5-ene-exo-exo-2,3-dicarboxylic acid dimethyl ester (ONBDM) in a selective solvent. The compositions and the molecular weights of the copolymers were estimated by 1H-NMR and gel permeation chromatography. The micelles were characterized by dynamic light scattering, transmission electron micrograph, and atomic force microscopy. The results indicated that the spherical micelles constructed with bromine-bearing PBNBE shell and PONBDM core were stable and reproducible in toluene.",

keywords = "one-pot synthesis, polymeric nanoparticles, polymerization-induced self-assembly, ring-opening metathesis polymerization (ROMP)",

author = "Liya Zhang and Chunmei Song and Jiahui Yu and Dan Yang and Meiran Xie",

year = "2010",

month = nov,

day = "15",

doi = "10.1002/pola.24323",

language = "英语",

volume = "48",

pages = "5231--5238",

journal = "Journal of Polymer Science, Part A: Polymer Chemistry",

issn = "0887-624X",

publisher = "John Wiley \& Sons Inc.",

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T1 - One-pot synthesis of polymeric nanoparticle by ring-opening metathesis polymerization

AU - Zhang, Liya

AU - Song, Chunmei

AU - Yu, Jiahui

AU - Yang, Dan

AU - Xie, Meiran

PY - 2010/11/15

Y1 - 2010/11/15

N2 - Shell-functionalized polymeric nanoparticle was prepared through the method of polymerization-induced self-assembly of block copolymers [poly(2,3-bis(2-bromoisobutyryloxymethyl)-5-norbornene)-block-poly(7-oxanorborn- 5-ene-exo-exo-2,3-dicarboxylic acid dimethyl ester), PBNBE-b-PONBDM] via one-pot ring-opening metathesis polymerization of 2,3-bis(2-bromoisobutyryloxymethyl)- 5-norbornene (BNBE) and 7-oxanorborn-5-ene-exo-exo-2,3-dicarboxylic acid dimethyl ester (ONBDM) in a selective solvent. The compositions and the molecular weights of the copolymers were estimated by 1H-NMR and gel permeation chromatography. The micelles were characterized by dynamic light scattering, transmission electron micrograph, and atomic force microscopy. The results indicated that the spherical micelles constructed with bromine-bearing PBNBE shell and PONBDM core were stable and reproducible in toluene.

AB - Shell-functionalized polymeric nanoparticle was prepared through the method of polymerization-induced self-assembly of block copolymers [poly(2,3-bis(2-bromoisobutyryloxymethyl)-5-norbornene)-block-poly(7-oxanorborn- 5-ene-exo-exo-2,3-dicarboxylic acid dimethyl ester), PBNBE-b-PONBDM] via one-pot ring-opening metathesis polymerization of 2,3-bis(2-bromoisobutyryloxymethyl)- 5-norbornene (BNBE) and 7-oxanorborn-5-ene-exo-exo-2,3-dicarboxylic acid dimethyl ester (ONBDM) in a selective solvent. The compositions and the molecular weights of the copolymers were estimated by 1H-NMR and gel permeation chromatography. The micelles were characterized by dynamic light scattering, transmission electron micrograph, and atomic force microscopy. The results indicated that the spherical micelles constructed with bromine-bearing PBNBE shell and PONBDM core were stable and reproducible in toluene.

KW - one-pot synthesis

KW - polymeric nanoparticles

KW - polymerization-induced self-assembly

KW - ring-opening metathesis polymerization (ROMP)

UR - https://www.scopus.com/pages/publications/78649604223

U2 - 10.1002/pola.24323

DO - 10.1002/pola.24323

M3 - 文章

AN - SCOPUS:78649604223

SN - 0887-624X

VL - 48

SP - 5231

EP - 5238

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 22

ER -

One-pot synthesis of polymeric nanoparticle by ring-opening metathesis polymerization

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Keywords

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