One-pot synthesis of benzamide over a robust tandem catalyst based on center radially fibrous silica encapsulated TS-1

Hong Gen Peng; Le Xu; Haihong Wu; Kun Zhang; Peng Wu

doi:10.1039/c3cc38546a

One-pot synthesis of benzamide over a robust tandem catalyst based on center radially fibrous silica encapsulated TS-1

Hong Gen Peng, Le Xu, Haihong Wu, Kun Zhang, Peng Wu

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

66 Scopus citations

Abstract

A center radially fibrous silica encapsulated TS-1 zeolite (TS-1@KCC-1) has been synthesized in a microemulsion system for the first time. Supporting the Rh(OH)₃ species, this novel core–shell structured material serves as a robust bifunctional catalyst for one-pot synthesis of benzamide from benzaldehyde, ammonia and hydrogen peroxide, in which the aldehyde ammoximation and oxime rearrangement occur in a tandem way.

Original language	English
Pages (from-to)	2709-2711
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	26
DOIs	https://doi.org/10.1039/c3cc38546a
State	Published - 5 Mar 2013

Access to Document

10.1039/c3cc38546a

Cite this

@article{c460d0422f904df3b0ab1523765f3f57,

title = "One-pot synthesis of benzamide over a robust tandem catalyst based on center radially fibrous silica encapsulated TS-1",

abstract = "A center radially fibrous silica encapsulated TS-1 zeolite (TS-1@KCC-1) has been synthesized in a microemulsion system for the first time. Supporting the Rh(OH)3 species, this novel core–shell structured material serves as a robust bifunctional catalyst for one-pot synthesis of benzamide from benzaldehyde, ammonia and hydrogen peroxide, in which the aldehyde ammoximation and oxime rearrangement occur in a tandem way.",

author = "Peng, \{Hong Gen\} and Le Xu and Haihong Wu and Kun Zhang and Peng Wu",

year = "2013",

month = mar,

day = "5",

doi = "10.1039/c3cc38546a",

language = "英语",

volume = "49",

pages = "2709--2711",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "26",

}

TY - JOUR

T1 - One-pot synthesis of benzamide over a robust tandem catalyst based on center radially fibrous silica encapsulated TS-1

AU - Peng, Hong Gen

AU - Xu, Le

AU - Wu, Haihong

AU - Zhang, Kun

AU - Wu, Peng

PY - 2013/3/5

Y1 - 2013/3/5

N2 - A center radially fibrous silica encapsulated TS-1 zeolite (TS-1@KCC-1) has been synthesized in a microemulsion system for the first time. Supporting the Rh(OH)3 species, this novel core–shell structured material serves as a robust bifunctional catalyst for one-pot synthesis of benzamide from benzaldehyde, ammonia and hydrogen peroxide, in which the aldehyde ammoximation and oxime rearrangement occur in a tandem way.

AB - A center radially fibrous silica encapsulated TS-1 zeolite (TS-1@KCC-1) has been synthesized in a microemulsion system for the first time. Supporting the Rh(OH)3 species, this novel core–shell structured material serves as a robust bifunctional catalyst for one-pot synthesis of benzamide from benzaldehyde, ammonia and hydrogen peroxide, in which the aldehyde ammoximation and oxime rearrangement occur in a tandem way.

UR - https://www.scopus.com/pages/publications/84874842599

U2 - 10.1039/c3cc38546a

DO - 10.1039/c3cc38546a

M3 - 文章

C2 - 23435621

AN - SCOPUS:84874842599

SN - 1359-7345

VL - 49

SP - 2709

EP - 2711

JO - Chemical Communications

JF - Chemical Communications

IS - 26

ER -

One-pot synthesis of benzamide over a robust tandem catalyst based on center radially fibrous silica encapsulated TS-1

Abstract

Access to Document

Other files and links

Fingerprint

Cite this