One-pot synthesis of 5-hydroxymethylfurfural from glucose using bifunctional [Sn,Al]-Beta catalysts

Liang Li; Jianghong Ding; Jin Gang Jiang; Zhiguo Zhu; Peng Wu

doi:10.1016/S1872-2067(14)60287-4

One-pot synthesis of 5-hydroxymethylfurfural from glucose using bifunctional [Sn,Al]-Beta catalysts

Liang Li
, Jianghong Ding
, Jin Gang Jiang
, Zhiguo Zhu
, Peng Wu^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

74 Scopus citations

Abstract

The one-pot synthesis of 5-hydroxymethylfurfural (5-HMF) from glucose was investigated, using [Sn,Al]-Beta catalysts prepared by a combination of partial dealumination and isomorphous substitution of Sn into the zeolite framework. The amount of Al in [Sn,Al]-Beta was adjusted by changing the concentration and acid treatment time, and the Sn content was varied by changing the SnCl₄ vapor treatment time. [Sn,Al]-Beta contains framework Al-related Brönsted acid sites and tetrahedral Sn-related Lewis acid sites, and is therefore a bifunctional solid acid catalyst. The reaction parameters for the [Sn,Al]-Beta-catalyzed one-pot conversion of glucose to 5-HMF were optimized. [Sn,Al]-Beta with a suitable Sn/Al molar ratio gave a glucose conversion of 60.0% and 5-HMF selectivity of 62.1%.

Original language	English
Pages (from-to)	820-828
Number of pages	9
Journal	Chinese Journal of Catalysis
Volume	36
Issue number	6
DOIs	https://doi.org/10.1016/S1872-2067(14)60287-4
State	Published - 20 Jun 2015

Keywords

Aldose-Ketose Isomerization
Bifunctional Catalysis
Biomass
Hydroxymethyl furfural
Isomorphous substitution
[Sn,Al]-Beta

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@article{26df052d1aad426bb41bc23e549e308b,

title = "One-pot synthesis of 5-hydroxymethylfurfural from glucose using bifunctional [Sn,Al]-Beta catalysts",

abstract = "The one-pot synthesis of 5-hydroxymethylfurfural (5-HMF) from glucose was investigated, using [Sn,Al]-Beta catalysts prepared by a combination of partial dealumination and isomorphous substitution of Sn into the zeolite framework. The amount of Al in [Sn,Al]-Beta was adjusted by changing the concentration and acid treatment time, and the Sn content was varied by changing the SnCl4 vapor treatment time. [Sn,Al]-Beta contains framework Al-related Br{\"o}nsted acid sites and tetrahedral Sn-related Lewis acid sites, and is therefore a bifunctional solid acid catalyst. The reaction parameters for the [Sn,Al]-Beta-catalyzed one-pot conversion of glucose to 5-HMF were optimized. [Sn,Al]-Beta with a suitable Sn/Al molar ratio gave a glucose conversion of 60.0\% and 5-HMF selectivity of 62.1\%.",

keywords = "Aldose-Ketose Isomerization, Bifunctional Catalysis, Biomass, Hydroxymethyl furfural, Isomorphous substitution, [Sn,Al]-Beta",

author = "Liang Li and Jianghong Ding and Jiang, \{Jin Gang\} and Zhiguo Zhu and Peng Wu",

year = "2015",

month = jun,

day = "20",

doi = "10.1016/S1872-2067(14)60287-4",

language = "英语",

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TY - JOUR

T1 - One-pot synthesis of 5-hydroxymethylfurfural from glucose using bifunctional [Sn,Al]-Beta catalysts

AU - Li, Liang

AU - Ding, Jianghong

AU - Jiang, Jin Gang

AU - Zhu, Zhiguo

AU - Wu, Peng

PY - 2015/6/20

Y1 - 2015/6/20

N2 - The one-pot synthesis of 5-hydroxymethylfurfural (5-HMF) from glucose was investigated, using [Sn,Al]-Beta catalysts prepared by a combination of partial dealumination and isomorphous substitution of Sn into the zeolite framework. The amount of Al in [Sn,Al]-Beta was adjusted by changing the concentration and acid treatment time, and the Sn content was varied by changing the SnCl4 vapor treatment time. [Sn,Al]-Beta contains framework Al-related Brönsted acid sites and tetrahedral Sn-related Lewis acid sites, and is therefore a bifunctional solid acid catalyst. The reaction parameters for the [Sn,Al]-Beta-catalyzed one-pot conversion of glucose to 5-HMF were optimized. [Sn,Al]-Beta with a suitable Sn/Al molar ratio gave a glucose conversion of 60.0% and 5-HMF selectivity of 62.1%.

AB - The one-pot synthesis of 5-hydroxymethylfurfural (5-HMF) from glucose was investigated, using [Sn,Al]-Beta catalysts prepared by a combination of partial dealumination and isomorphous substitution of Sn into the zeolite framework. The amount of Al in [Sn,Al]-Beta was adjusted by changing the concentration and acid treatment time, and the Sn content was varied by changing the SnCl4 vapor treatment time. [Sn,Al]-Beta contains framework Al-related Brönsted acid sites and tetrahedral Sn-related Lewis acid sites, and is therefore a bifunctional solid acid catalyst. The reaction parameters for the [Sn,Al]-Beta-catalyzed one-pot conversion of glucose to 5-HMF were optimized. [Sn,Al]-Beta with a suitable Sn/Al molar ratio gave a glucose conversion of 60.0% and 5-HMF selectivity of 62.1%.

KW - Aldose-Ketose Isomerization

KW - Bifunctional Catalysis

KW - Biomass

KW - Hydroxymethyl furfural

KW - Isomorphous substitution

KW - [Sn,Al]-Beta

UR - https://www.scopus.com/pages/publications/84932139768

U2 - 10.1016/S1872-2067(14)60287-4

DO - 10.1016/S1872-2067(14)60287-4

M3 - 文章

AN - SCOPUS:84932139768

SN - 1872-2067

VL - 36

SP - 820

EP - 828

JO - Chinese Journal of Catalysis

JF - Chinese Journal of Catalysis

IS - 6

ER -

One-pot synthesis of 5-hydroxymethylfurfural from glucose using bifunctional [Sn,Al]-Beta catalysts

Abstract

Keywords

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