Nucleophilic substitution of hydrogen in naphthalene by chloride (Cl -) in ionic liquids

Shen Yi Shi; Ai Guo Kong; Xin Hua Zhao; Han Ming Ding; Fan Yang; Yong Kui Shan

doi:10.1016/j.cclet.2010.09.021

Nucleophilic substitution of hydrogen in naphthalene by chloride (Cl ^-) in ionic liquids

Shen Yi Shi
, Ai Guo Kong
, Xin Hua Zhao
, Han Ming Ding
, Fan Yang
, Yong Kui Shan

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Nucleophilic aromatic substitution of hydrogen in non-activated aromatic ring, a very rare phenomenon in organic chemistry, is found in ionic liquids containing Cl^- as anion under mild reaction conditions. The reaction may be carried out by the addition of the halogen-bonding adduct (Br ₂Cl^-) as nucleophile to aromatic ring carbon atom, leading to the formation of the nucleophilic substitution product.

Original language	English
Pages (from-to)	147-150
Number of pages	4
Journal	Chinese Chemical Letters
Volume	22
Issue number	2
DOIs	https://doi.org/10.1016/j.cclet.2010.09.021
State	Published - Feb 2011

Keywords

Aromatic compound
Halogen bonding
Ionic liquid
Naphthalene
Nucleophilic reaction

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10.1016/j.cclet.2010.09.021

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title = "Nucleophilic substitution of hydrogen in naphthalene by chloride (Cl -) in ionic liquids",

abstract = "Nucleophilic aromatic substitution of hydrogen in non-activated aromatic ring, a very rare phenomenon in organic chemistry, is found in ionic liquids containing Cl- as anion under mild reaction conditions. The reaction may be carried out by the addition of the halogen-bonding adduct (Br 2Cl-) as nucleophile to aromatic ring carbon atom, leading to the formation of the nucleophilic substitution product.",

keywords = "Aromatic compound, Halogen bonding, Ionic liquid, Naphthalene, Nucleophilic reaction",

author = "Shi, \{Shen Yi\} and Kong, \{Ai Guo\} and Zhao, \{Xin Hua\} and Ding, \{Han Ming\} and Fan Yang and Shan, \{Yong Kui\}",

year = "2011",

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doi = "10.1016/j.cclet.2010.09.021",

language = "英语",

volume = "22",

pages = "147--150",

journal = "Chinese Chemical Letters",

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T1 - Nucleophilic substitution of hydrogen in naphthalene by chloride (Cl -) in ionic liquids

AU - Shi, Shen Yi

AU - Kong, Ai Guo

AU - Zhao, Xin Hua

AU - Ding, Han Ming

AU - Yang, Fan

AU - Shan, Yong Kui

PY - 2011/2

Y1 - 2011/2

N2 - Nucleophilic aromatic substitution of hydrogen in non-activated aromatic ring, a very rare phenomenon in organic chemistry, is found in ionic liquids containing Cl- as anion under mild reaction conditions. The reaction may be carried out by the addition of the halogen-bonding adduct (Br 2Cl-) as nucleophile to aromatic ring carbon atom, leading to the formation of the nucleophilic substitution product.

AB - Nucleophilic aromatic substitution of hydrogen in non-activated aromatic ring, a very rare phenomenon in organic chemistry, is found in ionic liquids containing Cl- as anion under mild reaction conditions. The reaction may be carried out by the addition of the halogen-bonding adduct (Br 2Cl-) as nucleophile to aromatic ring carbon atom, leading to the formation of the nucleophilic substitution product.

KW - Aromatic compound

KW - Halogen bonding

KW - Ionic liquid

KW - Naphthalene

KW - Nucleophilic reaction

UR - https://www.scopus.com/pages/publications/78651292648

U2 - 10.1016/j.cclet.2010.09.021

DO - 10.1016/j.cclet.2010.09.021

M3 - 文章

AN - SCOPUS:78651292648

SN - 1001-8417

VL - 22

SP - 147

EP - 150

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 2

ER -

Nucleophilic substitution of hydrogen in naphthalene by chloride (Cl ^-) in ionic liquids

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Keywords

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