Nucleophilic disulfurating reagents for unsymmetrical disulfides construction via copper-catalyzed oxidative cross coupling

Zhihong Dai; Xiao Xiao; Xuefeng Jiang

doi:10.1016/j.tet.2017.05.010

Nucleophilic disulfurating reagents for unsymmetrical disulfides construction via copper-catalyzed oxidative cross coupling

Zhihong Dai, Xiao Xiao, Xuefeng Jiang

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

Novel disulfuration was established via cross coupling between nucleophilic disulfurating reagent and arylsilane introducing two sulfur atoms in one step. This methodology was applied to synthesize various unsymmetrical disulfides under mild conditions via copper-catalyzed oxidative Hiyama-type cross coupling, providing a new pathway for disulfide synthesis. In addition, pH value of system displayed a key role in alcoholysis process.

Original language	English
Pages (from-to)	3702-3706
Number of pages	5
Journal	Tetrahedron
Volume	73
Issue number	26
DOIs	https://doi.org/10.1016/j.tet.2017.05.010
State	Published - 2017

Keywords

Copper
Nucleophilic disulfurating reagents
Synthetic methods
Unsymmetrical disulfides

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10.1016/j.tet.2017.05.010

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title = "Nucleophilic disulfurating reagents for unsymmetrical disulfides construction via copper-catalyzed oxidative cross coupling",

abstract = "Novel disulfuration was established via cross coupling between nucleophilic disulfurating reagent and arylsilane introducing two sulfur atoms in one step. This methodology was applied to synthesize various unsymmetrical disulfides under mild conditions via copper-catalyzed oxidative Hiyama-type cross coupling, providing a new pathway for disulfide synthesis. In addition, pH value of system displayed a key role in alcoholysis process.",

keywords = "Copper, Nucleophilic disulfurating reagents, Synthetic methods, Unsymmetrical disulfides",

author = "Zhihong Dai and Xiao Xiao and Xuefeng Jiang",

note = "Publisher Copyright: {\textcopyright} 2017 Elsevier Ltd",

year = "2017",

doi = "10.1016/j.tet.2017.05.010",

language = "英语",

volume = "73",

pages = "3702--3706",

journal = "Tetrahedron",

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TY - JOUR

T1 - Nucleophilic disulfurating reagents for unsymmetrical disulfides construction via copper-catalyzed oxidative cross coupling

AU - Dai, Zhihong

AU - Xiao, Xiao

AU - Jiang, Xuefeng

PY - 2017

Y1 - 2017

N2 - Novel disulfuration was established via cross coupling between nucleophilic disulfurating reagent and arylsilane introducing two sulfur atoms in one step. This methodology was applied to synthesize various unsymmetrical disulfides under mild conditions via copper-catalyzed oxidative Hiyama-type cross coupling, providing a new pathway for disulfide synthesis. In addition, pH value of system displayed a key role in alcoholysis process.

AB - Novel disulfuration was established via cross coupling between nucleophilic disulfurating reagent and arylsilane introducing two sulfur atoms in one step. This methodology was applied to synthesize various unsymmetrical disulfides under mild conditions via copper-catalyzed oxidative Hiyama-type cross coupling, providing a new pathway for disulfide synthesis. In addition, pH value of system displayed a key role in alcoholysis process.

KW - Copper

KW - Nucleophilic disulfurating reagents

KW - Synthetic methods

KW - Unsymmetrical disulfides

UR - https://www.scopus.com/pages/publications/85018413747

U2 - 10.1016/j.tet.2017.05.010

DO - 10.1016/j.tet.2017.05.010

M3 - 文章

AN - SCOPUS:85018413747

SN - 0040-4020

VL - 73

SP - 3702

EP - 3706

JO - Tetrahedron

JF - Tetrahedron

IS - 26

ER -

Nucleophilic disulfurating reagents for unsymmetrical disulfides construction via copper-catalyzed oxidative cross coupling

Abstract

Keywords

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