Novel alkylimidazolium/vanadium pentoxide intercalation compounds with excellent adsorption performance for methylene blue

Aiguo Kong; Yong Jie Ding; Ping Wang; Heng Qiang Zhang; Fan Yang; Yong Kui Shan

doi:10.1016/j.jssc.2010.12.008

Novel alkylimidazolium/vanadium pentoxide intercalation compounds with excellent adsorption performance for methylene blue

Aiguo Kong, Yong Jie Ding, Ping Wang, Heng Qiang Zhang, Fan Yang, Yong Kui Shan

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

Novel alkylimidazolium-intercalated V₂O₅ compounds were synthesized by a redox reaction between iodide ion and V₂O ₅. The X-ray photoelectron spectroscopy and the diffuse reflectance UVvis spectrometry experiments reveal that the vanadium in the intercalated V₂O₅ products was partially reduced by an iodide ion and the resultant iodine can be removed in the final products. The transmission electron microscope observation and X-ray diffraction analysis testify that the prepared alkylimidazolium/V₂O₅ intercalation compounds have typical lamellar structure with different d₁₀₀ interlayer spacing values and the special straw-like nanofiber morphology with the length of 0.510 μm. Systematic investigation indicates that new intercalation compounds possess the extraordinary adsorption performance for methylene blue in an aqueous solution.

Original language	English
Pages (from-to)	331-336
Number of pages	6
Journal	Journal of Solid State Chemistry
Volume	184
Issue number	2
DOIs	https://doi.org/10.1016/j.jssc.2010.12.008
State	Published - Feb 2011

Keywords

Alkylimidazolium insertion
Ionic liquid
Methylene blue adsorption
VO

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10.1016/j.jssc.2010.12.008

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title = "Novel alkylimidazolium/vanadium pentoxide intercalation compounds with excellent adsorption performance for methylene blue",

abstract = "Novel alkylimidazolium-intercalated V2O5 compounds were synthesized by a redox reaction between iodide ion and V2O 5. The X-ray photoelectron spectroscopy and the diffuse reflectance UVvis spectrometry experiments reveal that the vanadium in the intercalated V2O5 products was partially reduced by an iodide ion and the resultant iodine can be removed in the final products. The transmission electron microscope observation and X-ray diffraction analysis testify that the prepared alkylimidazolium/V2O5 intercalation compounds have typical lamellar structure with different d100 interlayer spacing values and the special straw-like nanofiber morphology with the length of 0.510 μm. Systematic investigation indicates that new intercalation compounds possess the extraordinary adsorption performance for methylene blue in an aqueous solution.",

keywords = "Alkylimidazolium insertion, Ionic liquid, Methylene blue adsorption, VO",

author = "Aiguo Kong and Ding, \{Yong Jie\} and Ping Wang and Zhang, \{Heng Qiang\} and Fan Yang and Shan, \{Yong Kui\}",

year = "2011",

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doi = "10.1016/j.jssc.2010.12.008",

language = "英语",

volume = "184",

pages = "331--336",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

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TY - JOUR

T1 - Novel alkylimidazolium/vanadium pentoxide intercalation compounds with excellent adsorption performance for methylene blue

AU - Kong, Aiguo

AU - Ding, Yong Jie

AU - Wang, Ping

AU - Zhang, Heng Qiang

AU - Yang, Fan

AU - Shan, Yong Kui

PY - 2011/2

Y1 - 2011/2

N2 - Novel alkylimidazolium-intercalated V2O5 compounds were synthesized by a redox reaction between iodide ion and V2O 5. The X-ray photoelectron spectroscopy and the diffuse reflectance UVvis spectrometry experiments reveal that the vanadium in the intercalated V2O5 products was partially reduced by an iodide ion and the resultant iodine can be removed in the final products. The transmission electron microscope observation and X-ray diffraction analysis testify that the prepared alkylimidazolium/V2O5 intercalation compounds have typical lamellar structure with different d100 interlayer spacing values and the special straw-like nanofiber morphology with the length of 0.510 μm. Systematic investigation indicates that new intercalation compounds possess the extraordinary adsorption performance for methylene blue in an aqueous solution.

AB - Novel alkylimidazolium-intercalated V2O5 compounds were synthesized by a redox reaction between iodide ion and V2O 5. The X-ray photoelectron spectroscopy and the diffuse reflectance UVvis spectrometry experiments reveal that the vanadium in the intercalated V2O5 products was partially reduced by an iodide ion and the resultant iodine can be removed in the final products. The transmission electron microscope observation and X-ray diffraction analysis testify that the prepared alkylimidazolium/V2O5 intercalation compounds have typical lamellar structure with different d100 interlayer spacing values and the special straw-like nanofiber morphology with the length of 0.510 μm. Systematic investigation indicates that new intercalation compounds possess the extraordinary adsorption performance for methylene blue in an aqueous solution.

KW - Alkylimidazolium insertion

KW - Ionic liquid

KW - Methylene blue adsorption

KW - VO

UR - https://www.scopus.com/pages/publications/79551688794

U2 - 10.1016/j.jssc.2010.12.008

DO - 10.1016/j.jssc.2010.12.008

M3 - 文章

AN - SCOPUS:79551688794

SN - 0022-4596

VL - 184

SP - 331

EP - 336

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 2

ER -

Novel alkylimidazolium/vanadium pentoxide intercalation compounds with excellent adsorption performance for methylene blue

Abstract

Keywords

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