Nonionic block copolymer synthesis of large-pore cubic mesoporous single crystals by use of inorganic salts

Chengzhong Yu; Bozhi Tian; Jie Fan; Galen D. Stucky; Dongyuan Zhao

doi:10.1021/ja025548f

Nonionic block copolymer synthesis of large-pore cubic mesoporous single crystals by use of inorganic salts

Chengzhong Yu
, Bozhi Tian
, Jie Fan
, Galen D. Stucky
, Dongyuan Zhao^*

^*Corresponding author for this work

Fudan University
University of California at Santa Barbara

Research output: Contribution to journal › Article › peer-review

325 Scopus citations

Abstract

Large-pore cubic (Im3m) mesoporous silica single crystals have been synthesized by using commercial nonionic block copolymers as templates and inorganic salts as additives. These single crystals possess exclusively uniform rhombdodecahedron shapes (∼1 μm) with ∼100% yield. The mesopore lattice array in each crystal face is solved by TEM, further confirming that these crystals are perfect single crystals.

Original language	English
Pages (from-to)	4556-4557
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	124
Issue number	17
DOIs	https://doi.org/10.1021/ja025548f
State	Published - 1 May 2002
Externally published	Yes

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10.1021/ja025548f

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title = "Nonionic block copolymer synthesis of large-pore cubic mesoporous single crystals by use of inorganic salts",

abstract = "Large-pore cubic (Im3m) mesoporous silica single crystals have been synthesized by using commercial nonionic block copolymers as templates and inorganic salts as additives. These single crystals possess exclusively uniform rhombdodecahedron shapes (∼1 μm) with ∼100\% yield. The mesopore lattice array in each crystal face is solved by TEM, further confirming that these crystals are perfect single crystals.",

author = "Chengzhong Yu and Bozhi Tian and Jie Fan and Stucky, \{Galen D.\} and Dongyuan Zhao",

year = "2002",

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T1 - Nonionic block copolymer synthesis of large-pore cubic mesoporous single crystals by use of inorganic salts

AU - Yu, Chengzhong

AU - Tian, Bozhi

AU - Fan, Jie

AU - Stucky, Galen D.

AU - Zhao, Dongyuan

PY - 2002/5/1

Y1 - 2002/5/1

N2 - Large-pore cubic (Im3m) mesoporous silica single crystals have been synthesized by using commercial nonionic block copolymers as templates and inorganic salts as additives. These single crystals possess exclusively uniform rhombdodecahedron shapes (∼1 μm) with ∼100% yield. The mesopore lattice array in each crystal face is solved by TEM, further confirming that these crystals are perfect single crystals.

AB - Large-pore cubic (Im3m) mesoporous silica single crystals have been synthesized by using commercial nonionic block copolymers as templates and inorganic salts as additives. These single crystals possess exclusively uniform rhombdodecahedron shapes (∼1 μm) with ∼100% yield. The mesopore lattice array in each crystal face is solved by TEM, further confirming that these crystals are perfect single crystals.

UR - https://www.scopus.com/pages/publications/0036569852

U2 - 10.1021/ja025548f

DO - 10.1021/ja025548f

M3 - 文章

C2 - 11971691

AN - SCOPUS:0036569852

SN - 0002-7863

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SP - 4556

EP - 4557

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 17

ER -

Nonionic block copolymer synthesis of large-pore cubic mesoporous single crystals by use of inorganic salts

Abstract

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