Nickel-catalyzed electrocarboxylation of allylic halides with CO2

La Xia Wu; Fang Jie Deng; Lin Wu; Huan Wang; Tai Jie Chen; Ye Bin Guan; Jia Xing Lu

doi:10.1039/d1nj02006d

Nickel-catalyzed electrocarboxylation of allylic halides with CO₂

La Xia Wu, Fang Jie Deng, Lin Wu, Huan Wang, Tai Jie Chen, Ye Bin Guan, Jia Xing Lu

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Nickel-catalyzed regioselective electrocarboxylation of allylic halides with CO₂at atmospheric pressure has been developed by adjusting reaction parameters, including catalyst, solvent, temperature and additive. β,γ-Unsaturated carboxylic acids were obtained in moderate to good yields and with high chain selectivity. This reaction shows tolerance to functional groups. In addition, cyclic voltammetry was performed to provide the possible mechanism of nickel-catalyzed CO₂allylation.

Original language	English
Pages (from-to)	13137-13141
Number of pages	5
Journal	New Journal of Chemistry
Volume	45
Issue number	29
DOIs	https://doi.org/10.1039/d1nj02006d
State	Published - 7 Aug 2021

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title = "Nickel-catalyzed electrocarboxylation of allylic halides with CO2",

abstract = "Nickel-catalyzed regioselective electrocarboxylation of allylic halides with CO2at atmospheric pressure has been developed by adjusting reaction parameters, including catalyst, solvent, temperature and additive. β,γ-Unsaturated carboxylic acids were obtained in moderate to good yields and with high chain selectivity. This reaction shows tolerance to functional groups. In addition, cyclic voltammetry was performed to provide the possible mechanism of nickel-catalyzed CO2allylation.",

author = "Wu, \{La Xia\} and Deng, \{Fang Jie\} and Lin Wu and Huan Wang and Chen, \{Tai Jie\} and Guan, \{Ye Bin\} and Lu, \{Jia Xing\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2021.",

year = "2021",

month = aug,

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doi = "10.1039/d1nj02006d",

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TY - JOUR

T1 - Nickel-catalyzed electrocarboxylation of allylic halides with CO2

AU - Wu, La Xia

AU - Deng, Fang Jie

AU - Wu, Lin

AU - Wang, Huan

AU - Chen, Tai Jie

AU - Guan, Ye Bin

AU - Lu, Jia Xing

PY - 2021/8/7

Y1 - 2021/8/7

N2 - Nickel-catalyzed regioselective electrocarboxylation of allylic halides with CO2at atmospheric pressure has been developed by adjusting reaction parameters, including catalyst, solvent, temperature and additive. β,γ-Unsaturated carboxylic acids were obtained in moderate to good yields and with high chain selectivity. This reaction shows tolerance to functional groups. In addition, cyclic voltammetry was performed to provide the possible mechanism of nickel-catalyzed CO2allylation.

AB - Nickel-catalyzed regioselective electrocarboxylation of allylic halides with CO2at atmospheric pressure has been developed by adjusting reaction parameters, including catalyst, solvent, temperature and additive. β,γ-Unsaturated carboxylic acids were obtained in moderate to good yields and with high chain selectivity. This reaction shows tolerance to functional groups. In addition, cyclic voltammetry was performed to provide the possible mechanism of nickel-catalyzed CO2allylation.

UR - https://www.scopus.com/pages/publications/85111373997

U2 - 10.1039/d1nj02006d

DO - 10.1039/d1nj02006d

M3 - 文章

AN - SCOPUS:85111373997

SN - 1144-0546

VL - 45

SP - 13137

EP - 13141

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 29

ER -

Nickel-catalyzed electrocarboxylation of allylic halides with CO₂

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