New stable multiply charged negative atomic ions in linearly polarized superintense laser fields

Qi Wei, Sabre Kais, Nimrod Moiseyev

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22 Scopus citations

Abstract

Singly charged negative atomic ions exist in the gas phase and are of fundamental importance in atomic and molecular physics. However, theoretical calculations and experimental results clearly exclude the existence of any stable doubly-negatively-charged atomic ion in the gas phase, only one electron can be added to a free atom in the gas phase. In this report, using the high-frequency Floquet theory, we predict that in a linear superintense laser field one can stabilize multiply charged negative atomic ions in the gas phase. We present self-consistent field calculations for the linear superintense laser fields needed to bind extra one and two electrons to form He-, He2-, and Li2-, with detachment energies dependent on the laser intensity and maximal values of 1.2, 0.12, and 0.13 eV, respectively. The fields and frequencies needed for binding extra electrons are within experimental reach. This method of stabilization is general and can be used to predict stability of larger multiply charged negative atomic ions.

Original languageEnglish
Article number201108
JournalJournal of Chemical Physics
Volume124
Issue number20
DOIs
StatePublished - 28 May 2006
Externally publishedYes

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