New Fluorescent Conjugates of Uridine Nucleoside and Substituted 1,8-Naphthalimide: Synthesis, Weak Interactions and Solvent Effects on Spectra

Wen Zhang; Yanli Wang; Yufang Xu; Xuhong Qian

doi:10.1007/s00706-002-0525-4

New Fluorescent Conjugates of Uridine Nucleoside and Substituted 1,8-Naphthalimide: Synthesis, Weak Interactions and Solvent Effects on Spectra

Wen Zhang
, Yanli Wang
, Yufang Xu
, Xuhong Qian^*

^*Corresponding author for this work

East China University of Science and Technology
Dalian University of Technology

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Novel fluorescent conjugates of uridine nucleoside and 4-dimethylamino-1,8- naphthalimide via linkage with different length, and their precursors were synthesized. Their spectroscopic properties were examined in ten different solvents. It was found that the spectroscopic properties for these conjugates are strongly dependent on polarity and hydrogen bonding ability of solvents. Their fluorescence spectra are also strongly influenced by intramolecular aromatic stacking and hydrogen bonding between the base or sugar moiety of the uridine nucleoside and naphthalimide moiety, which is controlled by the length of the linker.

Original language	English
Pages (from-to)	393-402
Number of pages	10
Journal	Monatshefte fur Chemie
Volume	134
Issue number	3
DOIs	https://doi.org/10.1007/s00706-002-0525-4
State	Published - Mar 2003
Externally published	Yes

Keywords

Absorption and emission spectra
Fluorescent conjugates
Solvent effects
Uridine nucleoside

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10.1007/s00706-002-0525-4

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title = "New Fluorescent Conjugates of Uridine Nucleoside and Substituted 1,8-Naphthalimide: Synthesis, Weak Interactions and Solvent Effects on Spectra",

abstract = "Novel fluorescent conjugates of uridine nucleoside and 4-dimethylamino-1,8- naphthalimide via linkage with different length, and their precursors were synthesized. Their spectroscopic properties were examined in ten different solvents. It was found that the spectroscopic properties for these conjugates are strongly dependent on polarity and hydrogen bonding ability of solvents. Their fluorescence spectra are also strongly influenced by intramolecular aromatic stacking and hydrogen bonding between the base or sugar moiety of the uridine nucleoside and naphthalimide moiety, which is controlled by the length of the linker.",

keywords = "Absorption and emission spectra, Fluorescent conjugates, Solvent effects, Uridine nucleoside",

author = "Wen Zhang and Yanli Wang and Yufang Xu and Xuhong Qian",

year = "2003",

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doi = "10.1007/s00706-002-0525-4",

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T1 - New Fluorescent Conjugates of Uridine Nucleoside and Substituted 1,8-Naphthalimide

T2 - Synthesis, Weak Interactions and Solvent Effects on Spectra

AU - Zhang, Wen

AU - Wang, Yanli

AU - Xu, Yufang

AU - Qian, Xuhong

PY - 2003/3

Y1 - 2003/3

N2 - Novel fluorescent conjugates of uridine nucleoside and 4-dimethylamino-1,8- naphthalimide via linkage with different length, and their precursors were synthesized. Their spectroscopic properties were examined in ten different solvents. It was found that the spectroscopic properties for these conjugates are strongly dependent on polarity and hydrogen bonding ability of solvents. Their fluorescence spectra are also strongly influenced by intramolecular aromatic stacking and hydrogen bonding between the base or sugar moiety of the uridine nucleoside and naphthalimide moiety, which is controlled by the length of the linker.

AB - Novel fluorescent conjugates of uridine nucleoside and 4-dimethylamino-1,8- naphthalimide via linkage with different length, and their precursors were synthesized. Their spectroscopic properties were examined in ten different solvents. It was found that the spectroscopic properties for these conjugates are strongly dependent on polarity and hydrogen bonding ability of solvents. Their fluorescence spectra are also strongly influenced by intramolecular aromatic stacking and hydrogen bonding between the base or sugar moiety of the uridine nucleoside and naphthalimide moiety, which is controlled by the length of the linker.

KW - Absorption and emission spectra

KW - Fluorescent conjugates

KW - Solvent effects

KW - Uridine nucleoside

UR - https://www.scopus.com/pages/publications/0348140926

U2 - 10.1007/s00706-002-0525-4

DO - 10.1007/s00706-002-0525-4

M3 - 文章

AN - SCOPUS:0348140926

SN - 0026-9247

VL - 134

SP - 393

EP - 402

JO - Monatshefte fur Chemie

JF - Monatshefte fur Chemie

IS - 3

ER -

New Fluorescent Conjugates of Uridine Nucleoside and Substituted 1,8-Naphthalimide: Synthesis, Weak Interactions and Solvent Effects on Spectra

Abstract

Keywords

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