New conducting polymers functionalized with redox-active tetrazines

Hui Li; Qing Zhou; Pierre Audebert; Fabien Miomandre; Clémence Allain; Fan Yang; Jie Tang

doi:10.1016/j.jelechem.2011.12.001

New conducting polymers functionalized with redox-active tetrazines

Hui Li
, Qing Zhou
, Pierre Audebert^*
, Fabien Miomandre
, Clémence Allain
, Fan Yang
, Jie Tang

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

We describe the synthesis of two new polymerizable monomers, based on respectively one thiophene-pyrrole-thiophene (SNS) moiety and one carbazole moiety, both functionalized by 3-chloro-6-alkoxy-s-tetrazine pendant groups. The electrochemical response of the monomers and the subsequent polymers has been studied both by cyclic voltametry and UV-visible spectroscopy. In both case conducting polymers are obtained, featuring both the redox activity of the main chain in oxidation and of the tetrazine functional group upon reduction, but only the one stemming from the SNS moiety is stable to cycling. The spectroscopic and electrochemical characteristics of both the monomer and the polymer are detailed herein, and especially a stable film has been obtained on an ITO plate.

Original language	English
Pages (from-to)	26-29
Number of pages	4
Journal	Journal of Electroanalytical Chemistry
Volume	668
DOIs	https://doi.org/10.1016/j.jelechem.2011.12.001
State	Published - 1 Mar 2012

Keywords

Conducting polymer
Electrochemistry
Polypyrrole
Tetrazine

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10.1016/j.jelechem.2011.12.001

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title = "New conducting polymers functionalized with redox-active tetrazines",

abstract = "We describe the synthesis of two new polymerizable monomers, based on respectively one thiophene-pyrrole-thiophene (SNS) moiety and one carbazole moiety, both functionalized by 3-chloro-6-alkoxy-s-tetrazine pendant groups. The electrochemical response of the monomers and the subsequent polymers has been studied both by cyclic voltametry and UV-visible spectroscopy. In both case conducting polymers are obtained, featuring both the redox activity of the main chain in oxidation and of the tetrazine functional group upon reduction, but only the one stemming from the SNS moiety is stable to cycling. The spectroscopic and electrochemical characteristics of both the monomer and the polymer are detailed herein, and especially a stable film has been obtained on an ITO plate.",

keywords = "Conducting polymer, Electrochemistry, Polypyrrole, Tetrazine",

author = "Hui Li and Qing Zhou and Pierre Audebert and Fabien Miomandre and Cl{\'e}mence Allain and Fan Yang and Jie Tang",

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doi = "10.1016/j.jelechem.2011.12.001",

language = "英语",

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TY - JOUR

T1 - New conducting polymers functionalized with redox-active tetrazines

AU - Li, Hui

AU - Zhou, Qing

AU - Audebert, Pierre

AU - Miomandre, Fabien

AU - Allain, Clémence

AU - Yang, Fan

AU - Tang, Jie

PY - 2012/3/1

Y1 - 2012/3/1

N2 - We describe the synthesis of two new polymerizable monomers, based on respectively one thiophene-pyrrole-thiophene (SNS) moiety and one carbazole moiety, both functionalized by 3-chloro-6-alkoxy-s-tetrazine pendant groups. The electrochemical response of the monomers and the subsequent polymers has been studied both by cyclic voltametry and UV-visible spectroscopy. In both case conducting polymers are obtained, featuring both the redox activity of the main chain in oxidation and of the tetrazine functional group upon reduction, but only the one stemming from the SNS moiety is stable to cycling. The spectroscopic and electrochemical characteristics of both the monomer and the polymer are detailed herein, and especially a stable film has been obtained on an ITO plate.

AB - We describe the synthesis of two new polymerizable monomers, based on respectively one thiophene-pyrrole-thiophene (SNS) moiety and one carbazole moiety, both functionalized by 3-chloro-6-alkoxy-s-tetrazine pendant groups. The electrochemical response of the monomers and the subsequent polymers has been studied both by cyclic voltametry and UV-visible spectroscopy. In both case conducting polymers are obtained, featuring both the redox activity of the main chain in oxidation and of the tetrazine functional group upon reduction, but only the one stemming from the SNS moiety is stable to cycling. The spectroscopic and electrochemical characteristics of both the monomer and the polymer are detailed herein, and especially a stable film has been obtained on an ITO plate.

KW - Conducting polymer

KW - Electrochemistry

KW - Polypyrrole

KW - Tetrazine

UR - https://www.scopus.com/pages/publications/84862795687

U2 - 10.1016/j.jelechem.2011.12.001

DO - 10.1016/j.jelechem.2011.12.001

M3 - 文章

AN - SCOPUS:84862795687

SN - 1572-6657

VL - 668

SP - 26

EP - 29

JO - Journal of Electroanalytical Chemistry

JF - Journal of Electroanalytical Chemistry

ER -

New conducting polymers functionalized with redox-active tetrazines

Abstract

Keywords

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