New alternating ferro- and antiferromagnetic one-dimensional complexes. Synthesis, characterization, crystal structure, and magnetic properties of [M(4,4'-dimethylbipyridine)(N3)2](n) [M = Cu(II), Mn(II), Ni(II), Fe(II)]

Hao Yu Shen; Wei Ming Bu; En Qing Gao; Dai Zheng Liao; Zong Hui Jiang; Shi Ping Yan; Geng Lin Wang

doi:10.1021/ic990338y

New alternating ferro- and antiferromagnetic one-dimensional complexes. Synthesis, characterization, crystal structure, and magnetic properties of [M(4,4'-dimethylbipyridine)(N₃)₂](n) [M = Cu(II), Mn(II), Ni(II), Fe(II)]

Hao Yu Shen
, Wei Ming Bu
, En Qing Gao
, Dai Zheng Liao^*
, Zong Hui Jiang
, Shi Ping Yan
, Geng Lin Wang

^*Corresponding author for this work

Sunhuan Lucky New Materials, INC.
Nankai University
Jilin University
Nanjing University

Research output: Contribution to journal › Article › peer-review

75 Scopus citations

Abstract

The preparation, X-ray crystal structure, and magnetic properties of alternating 1,1- and 1,3-azido-bridged copper(II) complex [Cu(4,4'-dmbpy)(N₃)₂](n) (1, 4,4'-dmbpy = 4,4'-dimethylbipyridine) have been reported. It crystallizes in triclinic system, space group P1, a = 7.9903(1) Å, b = 9.3545(9) Å, c = 10.754(2) Å, α = 113.485(1)°, β = 101.399(1)°, γ = 101.897(1)°, Z = 2. The magnetic properties of 1 have been investigated in the temperature range 1.5-300 K. Alternating antiferromagnetic (-J = 191.0 cm^-1) interaction through a 1,3-N₃^- bridge and ferromagnetic (J = 297.1 cm^-1) interaction through a 1,1-N₃^- bridge are obtained for 1 by analyzing the magnetic susceptibility data with the Hamiltonian H = -JΣ(S(2i)S (2i-1) - αS(2i)S(2i+1)). It's derivatives ({Mn(4,4'-dmbpy)(N₃)₂}(n) (2), {Ni(4,4'-dmbpy)(N₃)₂}(n) (3), and {Fe(4,4'-dmbpy)(N₃)₂}(n) (4) and the heterometallic derivatives {NiMn(4,4'-dmbpy)₂(N₃)₄}(n) (5) and {CuMn(4,4'-dmbpy)₂(N₃)₄}(n) (6) have also been synthesized and characterized by electronic and IR spectra. The X-ray powder diffraction and the magnetic properties of 6 have also been discussed.

Original language	English
Pages (from-to)	396-400
Number of pages	5
Journal	Inorganic Chemistry
Volume	39
Issue number	3
DOIs	https://doi.org/10.1021/ic990338y
State	Published - 7 Feb 2000
Externally published	Yes

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Shen, H. Y., Bu, W. M., Gao, E. Q., Liao, D. Z., Jiang, Z. H., Yan, S. P., & Wang, G. L. (2000). New alternating ferro- and antiferromagnetic one-dimensional complexes. Synthesis, characterization, crystal structure, and magnetic properties of [M(4,4'-dimethylbipyridine)(N₃)₂](n) [M = Cu(II), Mn(II), Ni(II), Fe(II)]. Inorganic Chemistry, 39(3), 396-400. https://doi.org/10.1021/ic990338y

@article{db6c1983cdb440f5ba3461ce647aa228,

title = "New alternating ferro- and antiferromagnetic one-dimensional complexes. Synthesis, characterization, crystal structure, and magnetic properties of [M(4,4'-dimethylbipyridine)(N3)2](n) [M = Cu(II), Mn(II), Ni(II), Fe(II)]",

abstract = "The preparation, X-ray crystal structure, and magnetic properties of alternating 1,1- and 1,3-azido-bridged copper(II) complex [Cu(4,4'-dmbpy)(N3)2](n) (1, 4,4'-dmbpy = 4,4'-dimethylbipyridine) have been reported. It crystallizes in triclinic system, space group P1, a = 7.9903(1) {\AA}, b = 9.3545(9) {\AA}, c = 10.754(2) {\AA}, α = 113.485(1)°, β = 101.399(1)°, γ = 101.897(1)°, Z = 2. The magnetic properties of 1 have been investigated in the temperature range 1.5-300 K. Alternating antiferromagnetic (-J = 191.0 cm-1) interaction through a 1,3-N3- bridge and ferromagnetic (J = 297.1 cm-1) interaction through a 1,1-N3- bridge are obtained for 1 by analyzing the magnetic susceptibility data with the Hamiltonian H = -JΣ(S(2i)S (2i-1) - αS(2i)S(2i+1)). It's derivatives (\{Mn(4,4'-dmbpy)(N3)2\}(n) (2), \{Ni(4,4'-dmbpy)(N3)2\}(n) (3), and \{Fe(4,4'-dmbpy)(N3)2\}(n) (4) and the heterometallic derivatives \{NiMn(4,4'-dmbpy)2(N3)4\}(n) (5) and \{CuMn(4,4'-dmbpy)2(N3)4\}(n) (6) have also been synthesized and characterized by electronic and IR spectra. The X-ray powder diffraction and the magnetic properties of 6 have also been discussed.",

author = "Shen, \{Hao Yu\} and Bu, \{Wei Ming\} and Gao, \{En Qing\} and Liao, \{Dai Zheng\} and Jiang, \{Zong Hui\} and Yan, \{Shi Ping\} and Wang, \{Geng Lin\}",

year = "2000",

month = feb,

day = "7",

doi = "10.1021/ic990338y",

language = "英语",

volume = "39",

pages = "396--400",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "3",

}

Shen, HY, Bu, WM, Gao, EQ, Liao, DZ, Jiang, ZH, Yan, SP & Wang, GL 2000, 'New alternating ferro- and antiferromagnetic one-dimensional complexes. Synthesis, characterization, crystal structure, and magnetic properties of [M(4,4'-dimethylbipyridine)(N₃)₂](n) [M = Cu(II), Mn(II), Ni(II), Fe(II)]', Inorganic Chemistry, vol. 39, no. 3, pp. 396-400. https://doi.org/10.1021/ic990338y

New alternating ferro- and antiferromagnetic one-dimensional complexes. Synthesis, characterization, crystal structure, and magnetic properties of [M(4,4'-dimethylbipyridine)(N₃)₂](n) [M = Cu(II), Mn(II), Ni(II), Fe(II)]. / Shen, Hao Yu; Bu, Wei Ming; Gao, En Qing et al.
In: Inorganic Chemistry, Vol. 39, No. 3, 07.02.2000, p. 396-400.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - New alternating ferro- and antiferromagnetic one-dimensional complexes. Synthesis, characterization, crystal structure, and magnetic properties of [M(4,4'-dimethylbipyridine)(N3)2](n) [M = Cu(II), Mn(II), Ni(II), Fe(II)]

AU - Shen, Hao Yu

AU - Bu, Wei Ming

AU - Gao, En Qing

AU - Liao, Dai Zheng

AU - Jiang, Zong Hui

AU - Yan, Shi Ping

AU - Wang, Geng Lin

PY - 2000/2/7

Y1 - 2000/2/7

N2 - The preparation, X-ray crystal structure, and magnetic properties of alternating 1,1- and 1,3-azido-bridged copper(II) complex [Cu(4,4'-dmbpy)(N3)2](n) (1, 4,4'-dmbpy = 4,4'-dimethylbipyridine) have been reported. It crystallizes in triclinic system, space group P1, a = 7.9903(1) Å, b = 9.3545(9) Å, c = 10.754(2) Å, α = 113.485(1)°, β = 101.399(1)°, γ = 101.897(1)°, Z = 2. The magnetic properties of 1 have been investigated in the temperature range 1.5-300 K. Alternating antiferromagnetic (-J = 191.0 cm-1) interaction through a 1,3-N3- bridge and ferromagnetic (J = 297.1 cm-1) interaction through a 1,1-N3- bridge are obtained for 1 by analyzing the magnetic susceptibility data with the Hamiltonian H = -JΣ(S(2i)S (2i-1) - αS(2i)S(2i+1)). It's derivatives ({Mn(4,4'-dmbpy)(N3)2}(n) (2), {Ni(4,4'-dmbpy)(N3)2}(n) (3), and {Fe(4,4'-dmbpy)(N3)2}(n) (4) and the heterometallic derivatives {NiMn(4,4'-dmbpy)2(N3)4}(n) (5) and {CuMn(4,4'-dmbpy)2(N3)4}(n) (6) have also been synthesized and characterized by electronic and IR spectra. The X-ray powder diffraction and the magnetic properties of 6 have also been discussed.

AB - The preparation, X-ray crystal structure, and magnetic properties of alternating 1,1- and 1,3-azido-bridged copper(II) complex [Cu(4,4'-dmbpy)(N3)2](n) (1, 4,4'-dmbpy = 4,4'-dimethylbipyridine) have been reported. It crystallizes in triclinic system, space group P1, a = 7.9903(1) Å, b = 9.3545(9) Å, c = 10.754(2) Å, α = 113.485(1)°, β = 101.399(1)°, γ = 101.897(1)°, Z = 2. The magnetic properties of 1 have been investigated in the temperature range 1.5-300 K. Alternating antiferromagnetic (-J = 191.0 cm-1) interaction through a 1,3-N3- bridge and ferromagnetic (J = 297.1 cm-1) interaction through a 1,1-N3- bridge are obtained for 1 by analyzing the magnetic susceptibility data with the Hamiltonian H = -JΣ(S(2i)S (2i-1) - αS(2i)S(2i+1)). It's derivatives ({Mn(4,4'-dmbpy)(N3)2}(n) (2), {Ni(4,4'-dmbpy)(N3)2}(n) (3), and {Fe(4,4'-dmbpy)(N3)2}(n) (4) and the heterometallic derivatives {NiMn(4,4'-dmbpy)2(N3)4}(n) (5) and {CuMn(4,4'-dmbpy)2(N3)4}(n) (6) have also been synthesized and characterized by electronic and IR spectra. The X-ray powder diffraction and the magnetic properties of 6 have also been discussed.

UR - https://www.scopus.com/pages/publications/0034614876

U2 - 10.1021/ic990338y

DO - 10.1021/ic990338y

M3 - 文章

AN - SCOPUS:0034614876

SN - 0020-1669

VL - 39

SP - 396

EP - 400

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 3