Molecular-sieve membrane with hydrogen permselectivity: ZIF-22 in LTA topology prepared with 3-aminopropyltriethoxysilane as covalent linker

Aisheng Huang; Helge Bux; Frank Steinbach; Jürgen Caro

doi:10.1002/anie.201001919

Molecular-sieve membrane with hydrogen permselectivity: ZIF-22 in LTA topology prepared with 3-aminopropyltriethoxysilane as covalent linker

Aisheng Huang^*
, Helge Bux
, Frank Steinbach
, Jürgen Caro

^*Corresponding author for this work

Leibniz University Hannover

Research output: Contribution to journal › Article › peer-review

392 Scopus citations

Abstract

(Figure Presented) High hydrogen selectivity and thermal stability are displayed by a membrane of zeolitic imidazolate ZIF-22 grown on porous ceramic supports by using 3aminopropyltriethoxysilane (APTES) as covalent linker (see picture). At 323 K, H₂/ CO₂ selectivity of 7.2 and H ₂ permeance of 1.6×10^-7 mol m^-2 S ^-1 Pa^-1 were achieved.

Original language	English
Pages (from-to)	4958-4961
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	29
DOIs	https://doi.org/10.1002/anie.201001919
State	Published - 5 Jul 2010
Externally published	Yes

Keywords

Gas separation
Hydrothermal synthesis
Membranes
Metal-organic frameworks
Microporous materials

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10.1002/anie.201001919

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title = "Molecular-sieve membrane with hydrogen permselectivity: ZIF-22 in LTA topology prepared with 3-aminopropyltriethoxysilane as covalent linker",

abstract = "(Figure Presented) High hydrogen selectivity and thermal stability are displayed by a membrane of zeolitic imidazolate ZIF-22 grown on porous ceramic supports by using 3aminopropyltriethoxysilane (APTES) as covalent linker (see picture). At 323 K, H2/ CO2 selectivity of 7.2 and H 2 permeance of 1.6×10-7 mol m-2 S -1 Pa-1 were achieved.",

keywords = "Gas separation, Hydrothermal synthesis, Membranes, Metal-organic frameworks, Microporous materials",

author = "Aisheng Huang and Helge Bux and Frank Steinbach and J{\"u}rgen Caro",

year = "2010",

month = jul,

day = "5",

doi = "10.1002/anie.201001919",

language = "英语",

volume = "49",

pages = "4958--4961",

journal = "Angewandte Chemie - International Edition",

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TY - JOUR

T1 - Molecular-sieve membrane with hydrogen permselectivity

T2 - ZIF-22 in LTA topology prepared with 3-aminopropyltriethoxysilane as covalent linker

AU - Huang, Aisheng

AU - Bux, Helge

AU - Steinbach, Frank

AU - Caro, Jürgen

PY - 2010/7/5

Y1 - 2010/7/5

N2 - (Figure Presented) High hydrogen selectivity and thermal stability are displayed by a membrane of zeolitic imidazolate ZIF-22 grown on porous ceramic supports by using 3aminopropyltriethoxysilane (APTES) as covalent linker (see picture). At 323 K, H2/ CO2 selectivity of 7.2 and H 2 permeance of 1.6×10-7 mol m-2 S -1 Pa-1 were achieved.

AB - (Figure Presented) High hydrogen selectivity and thermal stability are displayed by a membrane of zeolitic imidazolate ZIF-22 grown on porous ceramic supports by using 3aminopropyltriethoxysilane (APTES) as covalent linker (see picture). At 323 K, H2/ CO2 selectivity of 7.2 and H 2 permeance of 1.6×10-7 mol m-2 S -1 Pa-1 were achieved.

KW - Gas separation

KW - Hydrothermal synthesis

KW - Membranes

KW - Metal-organic frameworks

KW - Microporous materials

UR - https://www.scopus.com/pages/publications/77954344927

U2 - 10.1002/anie.201001919

DO - 10.1002/anie.201001919

M3 - 文章

AN - SCOPUS:77954344927

SN - 1433-7851

VL - 49

SP - 4958

EP - 4961

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 29

ER -

Molecular-sieve membrane with hydrogen permselectivity: ZIF-22 in LTA topology prepared with 3-aminopropyltriethoxysilane as covalent linker

Abstract

Keywords

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