MOFs derived Co/Cu bimetallic nanoparticles embedded in graphitized carbon nanocubes as efficient Fenton catalysts

In this work, Cu-Co bimetallic nanoparticles embedded carbon nanocubes (Cu_xCo_10-x/CNC) are synthesized by direct carbonization of Cu-Co bimetal ZIF. The ratio of Cu and Co nanoparticles in Cu_xCo_10-x/CNC as well as morphology, pore structure and graphitization degree of carbon substrates can be tuned by adjusting the molar ratio of Cu/Co (0:10, 1:9, 2:8, 3:7, 4:6 and 5:5) in ZIF precursors. The Fenton catalytic performances of Cu_xCo_10-x/CNC are further studied by degrading a typical azo dye, Acid Orange II (AOII). The results show the Cu_xCo_10-x/CNC with a Cu/Co ratio of 4/6 display the highest catalytic activity with faster dye degradation rate than other catalysts, which may be ascribed to the synergetic effects of optimized ratio of Cu/Co bimetals, high surface area and graphitized carbon framework. The stability and reusability of the catalyst has been investigated, showing a good performance after five consecutive runs. The catalysts prepared in this study can be used as an attractive alternative in heterogeneous Fenton chemistry and wastewater treatment.