MOF-derived bimetallic core-shell catalyst HZSM-5@ZrO2-In2O3: high CO2 conversion in reverse water gas shift reaction

Huimin Fang; Guofeng Zhao; Denghui Cheng; Jichang Liu; Dengpeng Lan; Qi Jiang; Xuqiang Liu; Jianping Ge; Zhenliang Xu; Haitao Xu

doi:10.1039/d2qm00307d

MOF-derived bimetallic core-shell catalyst HZSM-5@ZrO₂-In₂O₃: high CO₂ conversion in reverse water gas shift reaction

Huimin Fang
, Guofeng Zhao^*
, Denghui Cheng
, Jichang Liu^*
, Dengpeng Lan
, Qi Jiang
, Xuqiang Liu
, Jianping Ge
, Zhenliang Xu
, Haitao Xu^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The bicomponent core-shell catalyst HZSM-5@ZrO₂-In₂O₃ was synthesized via the decomposition of In(NO₃)₃/HZSM-5@UIO-66, which was obtained by impregnating HZSM-5@UIO-66 with In(NO₃)₃ solution. The bimetallic oxide particles of ZrO₂-In₂O₃ were formed through the simultaneous decomposition of UIO-66 and In(NO₃)₃, and were anchored to the surface of the HZSM-5 core. The HZSM-5@ZrO₂-In₂O₃ catalyst exhibited 31.1% CO₂ conversion with 96.3% CO selectivity at 400 °C for the reverse water gas shift reaction.

Original language	English
Pages (from-to)	2826-2834
Number of pages	9
Journal	Materials Chemistry Frontiers
Volume	6
Issue number	19
DOIs	https://doi.org/10.1039/d2qm00307d
State	Published - 6 Aug 2022

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@article{201d05fa3f524a91aceca3446173b10f,

title = "MOF-derived bimetallic core-shell catalyst HZSM-5@ZrO2-In2O3: high CO2 conversion in reverse water gas shift reaction",

abstract = "The bicomponent core-shell catalyst HZSM-5@ZrO2-In2O3 was synthesized via the decomposition of In(NO3)3/HZSM-5@UIO-66, which was obtained by impregnating HZSM-5@UIO-66 with In(NO3)3 solution. The bimetallic oxide particles of ZrO2-In2O3 were formed through the simultaneous decomposition of UIO-66 and In(NO3)3, and were anchored to the surface of the HZSM-5 core. The HZSM-5@ZrO2-In2O3 catalyst exhibited 31.1\% CO2 conversion with 96.3\% CO selectivity at 400 °C for the reverse water gas shift reaction.",

author = "Huimin Fang and Guofeng Zhao and Denghui Cheng and Jichang Liu and Dengpeng Lan and Qi Jiang and Xuqiang Liu and Jianping Ge and Zhenliang Xu and Haitao Xu",

note = "Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry.",

year = "2022",

month = aug,

day = "6",

doi = "10.1039/d2qm00307d",

language = "英语",

volume = "6",

pages = "2826--2834",

journal = "Materials Chemistry Frontiers",

issn = "2052-1537",

publisher = "Royal Society of Chemistry",

number = "19",

}

TY - JOUR

T1 - MOF-derived bimetallic core-shell catalyst HZSM-5@ZrO2-In2O3

T2 - high CO2 conversion in reverse water gas shift reaction

AU - Fang, Huimin

AU - Zhao, Guofeng

AU - Cheng, Denghui

AU - Liu, Jichang

AU - Lan, Dengpeng

AU - Jiang, Qi

AU - Liu, Xuqiang

AU - Ge, Jianping

AU - Xu, Zhenliang

AU - Xu, Haitao

PY - 2022/8/6

Y1 - 2022/8/6

N2 - The bicomponent core-shell catalyst HZSM-5@ZrO2-In2O3 was synthesized via the decomposition of In(NO3)3/HZSM-5@UIO-66, which was obtained by impregnating HZSM-5@UIO-66 with In(NO3)3 solution. The bimetallic oxide particles of ZrO2-In2O3 were formed through the simultaneous decomposition of UIO-66 and In(NO3)3, and were anchored to the surface of the HZSM-5 core. The HZSM-5@ZrO2-In2O3 catalyst exhibited 31.1% CO2 conversion with 96.3% CO selectivity at 400 °C for the reverse water gas shift reaction.

AB - The bicomponent core-shell catalyst HZSM-5@ZrO2-In2O3 was synthesized via the decomposition of In(NO3)3/HZSM-5@UIO-66, which was obtained by impregnating HZSM-5@UIO-66 with In(NO3)3 solution. The bimetallic oxide particles of ZrO2-In2O3 were formed through the simultaneous decomposition of UIO-66 and In(NO3)3, and were anchored to the surface of the HZSM-5 core. The HZSM-5@ZrO2-In2O3 catalyst exhibited 31.1% CO2 conversion with 96.3% CO selectivity at 400 °C for the reverse water gas shift reaction.

UR - https://www.scopus.com/pages/publications/85138022655

U2 - 10.1039/d2qm00307d

DO - 10.1039/d2qm00307d

M3 - 文章

AN - SCOPUS:85138022655

SN - 2052-1537

VL - 6

SP - 2826

EP - 2834

JO - Materials Chemistry Frontiers

JF - Materials Chemistry Frontiers

IS - 19

ER -

MOF-derived bimetallic core-shell catalyst HZSM-5@ZrO₂-In₂O₃: high CO₂ conversion in reverse water gas shift reaction

Abstract

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