MOF confined in macroporous-mesoporous-TiO2 for light-boosting electrocatalytical oxygen production

Zhenxing Li; Xiaofei Xing; Junmei Chu; Kai Li Wang; Chengcheng Yu; Zhiting Wei; Yangyang Wen; Hui Sun; Zhao Kui Wang

doi:10.1016/j.mtener.2019.05.008

MOF confined in macroporous-mesoporous-TiO₂ for light-boosting electrocatalytical oxygen production

Zhenxing Li, Xiaofei Xing, Junmei Chu, Kai Li Wang, Chengcheng Yu, Zhiting Wei, Yangyang Wen, Hui Sun, Zhao Kui Wang

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

A novel multiscale pore structure material is firstly synthesized by means of the MOF confined in ordered macroporous-mesoporous-TiO₂ (FeCoNi-MOF@TiO₂). We have successfully achieved that three-scale ordered porous structures are integrated into one material, and the porous sizes are 400 nm, 5.1 nm and 3.4 nm, respectively. A photo-based electrocatalytic OER catalytic system was designed, and the FeCoNi-MOF@TiO₂ as a catalyst exhibits high catalytical activity for OER under the irradiation of UV light. The electrons of macroporous-mesoporous-TiO₂ are excited and transferred to the loaded FeCoNi-MOF, when the macroporous-mesoporous-TiO₂ absorbs the UV light, which can improve the conductivity of the FeCoNi-MOF. The photo-induced electron of macroporous-mesoporous-TiO₂ significantly boosts the electrocatalytic active of FeCoNi-MOF. These results provide a promising route on enhancing the catalytic activity of MOFs in electrocatalytic reaction.

Original language	English
Pages (from-to)	125-133
Number of pages	9
Journal	Materials Today Energy
Volume	13
DOIs	https://doi.org/10.1016/j.mtener.2019.05.008
State	Published - Sep 2019
Externally published	Yes

Keywords

Conductivity
MOF
Oxygen evolution reaction
TiO
Ultraviolet light

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/j.mtener.2019.05.008

Cite this

@article{ed97f0a111c445b18881d4332c630e91,

title = "MOF confined in macroporous-mesoporous-TiO2 for light-boosting electrocatalytical oxygen production",

abstract = "A novel multiscale pore structure material is firstly synthesized by means of the MOF confined in ordered macroporous-mesoporous-TiO2 (FeCoNi-MOF@TiO2). We have successfully achieved that three-scale ordered porous structures are integrated into one material, and the porous sizes are 400 nm, 5.1 nm and 3.4 nm, respectively. A photo-based electrocatalytic OER catalytic system was designed, and the FeCoNi-MOF@TiO2 as a catalyst exhibits high catalytical activity for OER under the irradiation of UV light. The electrons of macroporous-mesoporous-TiO2 are excited and transferred to the loaded FeCoNi-MOF, when the macroporous-mesoporous-TiO2 absorbs the UV light, which can improve the conductivity of the FeCoNi-MOF. The photo-induced electron of macroporous-mesoporous-TiO2 significantly boosts the electrocatalytic active of FeCoNi-MOF. These results provide a promising route on enhancing the catalytic activity of MOFs in electrocatalytic reaction.",

keywords = "Conductivity, MOF, Oxygen evolution reaction, TiO, Ultraviolet light",

author = "Zhenxing Li and Xiaofei Xing and Junmei Chu and Wang, \{Kai Li\} and Chengcheng Yu and Zhiting Wei and Yangyang Wen and Hui Sun and Wang, \{Zhao Kui\}",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd",

year = "2019",

month = sep,

doi = "10.1016/j.mtener.2019.05.008",

language = "英语",

volume = "13",

pages = "125--133",

journal = "Materials Today Energy",

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TY - JOUR

T1 - MOF confined in macroporous-mesoporous-TiO2 for light-boosting electrocatalytical oxygen production

AU - Li, Zhenxing

AU - Xing, Xiaofei

AU - Chu, Junmei

AU - Wang, Kai Li

AU - Yu, Chengcheng

AU - Wei, Zhiting

AU - Wen, Yangyang

AU - Sun, Hui

AU - Wang, Zhao Kui

PY - 2019/9

Y1 - 2019/9

N2 - A novel multiscale pore structure material is firstly synthesized by means of the MOF confined in ordered macroporous-mesoporous-TiO2 (FeCoNi-MOF@TiO2). We have successfully achieved that three-scale ordered porous structures are integrated into one material, and the porous sizes are 400 nm, 5.1 nm and 3.4 nm, respectively. A photo-based electrocatalytic OER catalytic system was designed, and the FeCoNi-MOF@TiO2 as a catalyst exhibits high catalytical activity for OER under the irradiation of UV light. The electrons of macroporous-mesoporous-TiO2 are excited and transferred to the loaded FeCoNi-MOF, when the macroporous-mesoporous-TiO2 absorbs the UV light, which can improve the conductivity of the FeCoNi-MOF. The photo-induced electron of macroporous-mesoporous-TiO2 significantly boosts the electrocatalytic active of FeCoNi-MOF. These results provide a promising route on enhancing the catalytic activity of MOFs in electrocatalytic reaction.

AB - A novel multiscale pore structure material is firstly synthesized by means of the MOF confined in ordered macroporous-mesoporous-TiO2 (FeCoNi-MOF@TiO2). We have successfully achieved that three-scale ordered porous structures are integrated into one material, and the porous sizes are 400 nm, 5.1 nm and 3.4 nm, respectively. A photo-based electrocatalytic OER catalytic system was designed, and the FeCoNi-MOF@TiO2 as a catalyst exhibits high catalytical activity for OER under the irradiation of UV light. The electrons of macroporous-mesoporous-TiO2 are excited and transferred to the loaded FeCoNi-MOF, when the macroporous-mesoporous-TiO2 absorbs the UV light, which can improve the conductivity of the FeCoNi-MOF. The photo-induced electron of macroporous-mesoporous-TiO2 significantly boosts the electrocatalytic active of FeCoNi-MOF. These results provide a promising route on enhancing the catalytic activity of MOFs in electrocatalytic reaction.

KW - Conductivity

KW - MOF

KW - Oxygen evolution reaction

KW - TiO

KW - Ultraviolet light

UR - https://www.scopus.com/pages/publications/85066264603

U2 - 10.1016/j.mtener.2019.05.008

DO - 10.1016/j.mtener.2019.05.008

M3 - 文章

AN - SCOPUS:85066264603

SN - 2468-6069

VL - 13

SP - 125

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JO - Materials Today Energy

JF - Materials Today Energy

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