Microwave-irradiated synthesized platinum nanoparticles/carbon nanotubes for oxidative determination of trace arsenic(III)

He Xu; Liping Zeng; Sujie Xing; Yuezhong Xian; Litong Jin

doi:10.1016/j.elecom.2008.01.028

Microwave-irradiated synthesized platinum nanoparticles/carbon nanotubes for oxidative determination of trace arsenic(III)

He Xu
, Liping Zeng
, Sujie Xing
, Yuezhong Xian
, Litong Jin^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

47 Scopus citations

Abstract

Platinum nanoparticles/carbon nanotubes (Pt_nano/CNTs) were rapidly synthesized by microwave radiation, and applied for the oxidative determination of arsenic(III). The transmission electron microscopy (TEM) revealed the size of synthesized Pt nanoparticles with nominal diameter of 15 ± 3 nm. Pt_nano/CNTs modified glassy carbon electrode (Pt_nano/CNTs/GCE) exhibited better performance for arsenic(III) analysis than that of Pt nanoparticles modified GCE (Pt_nano/GCE) by electrochemical deposition or Pt foil electrode. Excellent reproducibility of the Pt_nano/CNTs/GCE was obtained with the relative standard deviation (RSD) of 3.5% at 20 repeated analysis of 40 μM As(III), while the RSD was 9.8% for Pt_nano/GCE under the same conditions. The limit of determination (LOD) of the Pt_nano/CNTs/GCE was 0.12 ppb, which was 1-2 orders of magnitude lower than that of Pt_nano/GCE or Pt foil electrode.

Original language	English
Pages (from-to)	551-554
Number of pages	4
Journal	Electrochemistry Communications
Volume	10
Issue number	4
DOIs	https://doi.org/10.1016/j.elecom.2008.01.028
State	Published - Apr 2008

Keywords

Arsenic
Carbon nanotubes
Microwave-irradiated synthesis
Platinum nanoparticles
Voltammetry

Access to Document

10.1016/j.elecom.2008.01.028

Cite this

@article{de5661f3dd94431799a0f87d56e67b8d,

title = "Microwave-irradiated synthesized platinum nanoparticles/carbon nanotubes for oxidative determination of trace arsenic(III)",

abstract = "Platinum nanoparticles/carbon nanotubes (Ptnano/CNTs) were rapidly synthesized by microwave radiation, and applied for the oxidative determination of arsenic(III). The transmission electron microscopy (TEM) revealed the size of synthesized Pt nanoparticles with nominal diameter of 15 ± 3 nm. Ptnano/CNTs modified glassy carbon electrode (Ptnano/CNTs/GCE) exhibited better performance for arsenic(III) analysis than that of Pt nanoparticles modified GCE (Ptnano/GCE) by electrochemical deposition or Pt foil electrode. Excellent reproducibility of the Ptnano/CNTs/GCE was obtained with the relative standard deviation (RSD) of 3.5\% at 20 repeated analysis of 40 μM As(III), while the RSD was 9.8\% for Ptnano/GCE under the same conditions. The limit of determination (LOD) of the Ptnano/CNTs/GCE was 0.12 ppb, which was 1-2 orders of magnitude lower than that of Ptnano/GCE or Pt foil electrode.",

keywords = "Arsenic, Carbon nanotubes, Microwave-irradiated synthesis, Platinum nanoparticles, Voltammetry",

author = "He Xu and Liping Zeng and Sujie Xing and Yuezhong Xian and Litong Jin",

year = "2008",

month = apr,

doi = "10.1016/j.elecom.2008.01.028",

language = "英语",

volume = "10",

pages = "551--554",

journal = "Electrochemistry Communications",

issn = "1388-2481",

publisher = "Elsevier Inc.",

number = "4",

}

TY - JOUR

T1 - Microwave-irradiated synthesized platinum nanoparticles/carbon nanotubes for oxidative determination of trace arsenic(III)

AU - Xu, He

AU - Zeng, Liping

AU - Xing, Sujie

AU - Xian, Yuezhong

AU - Jin, Litong

PY - 2008/4

Y1 - 2008/4

N2 - Platinum nanoparticles/carbon nanotubes (Ptnano/CNTs) were rapidly synthesized by microwave radiation, and applied for the oxidative determination of arsenic(III). The transmission electron microscopy (TEM) revealed the size of synthesized Pt nanoparticles with nominal diameter of 15 ± 3 nm. Ptnano/CNTs modified glassy carbon electrode (Ptnano/CNTs/GCE) exhibited better performance for arsenic(III) analysis than that of Pt nanoparticles modified GCE (Ptnano/GCE) by electrochemical deposition or Pt foil electrode. Excellent reproducibility of the Ptnano/CNTs/GCE was obtained with the relative standard deviation (RSD) of 3.5% at 20 repeated analysis of 40 μM As(III), while the RSD was 9.8% for Ptnano/GCE under the same conditions. The limit of determination (LOD) of the Ptnano/CNTs/GCE was 0.12 ppb, which was 1-2 orders of magnitude lower than that of Ptnano/GCE or Pt foil electrode.

AB - Platinum nanoparticles/carbon nanotubes (Ptnano/CNTs) were rapidly synthesized by microwave radiation, and applied for the oxidative determination of arsenic(III). The transmission electron microscopy (TEM) revealed the size of synthesized Pt nanoparticles with nominal diameter of 15 ± 3 nm. Ptnano/CNTs modified glassy carbon electrode (Ptnano/CNTs/GCE) exhibited better performance for arsenic(III) analysis than that of Pt nanoparticles modified GCE (Ptnano/GCE) by electrochemical deposition or Pt foil electrode. Excellent reproducibility of the Ptnano/CNTs/GCE was obtained with the relative standard deviation (RSD) of 3.5% at 20 repeated analysis of 40 μM As(III), while the RSD was 9.8% for Ptnano/GCE under the same conditions. The limit of determination (LOD) of the Ptnano/CNTs/GCE was 0.12 ppb, which was 1-2 orders of magnitude lower than that of Ptnano/GCE or Pt foil electrode.

KW - Arsenic

KW - Carbon nanotubes

KW - Microwave-irradiated synthesis

KW - Platinum nanoparticles

KW - Voltammetry

UR - https://www.scopus.com/pages/publications/40849083401

U2 - 10.1016/j.elecom.2008.01.028

DO - 10.1016/j.elecom.2008.01.028

M3 - 文章

AN - SCOPUS:40849083401

SN - 1388-2481

VL - 10

SP - 551

EP - 554

JO - Electrochemistry Communications

JF - Electrochemistry Communications

IS - 4

ER -

Microwave-irradiated synthesized platinum nanoparticles/carbon nanotubes for oxidative determination of trace arsenic(III)

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this