MGa2B2O7:Bi3+,Al3+(M = Sr, Ba) blue phosphors with a quantum yield of 99% and negative thermal quenching

Shuai Yang; Yuning Wu; Fangyu Yue; Ruijuan Qi; Bin Jiang; Jiahao Wu; Yang Shen; Chungang Duan; Yongkui Shan; Qingbiao Zhao; Yuefei Zhang

doi:10.1039/d1qi00671a

MGa₂B₂O₇:Bi³⁺,Al³⁺(M = Sr, Ba) blue phosphors with a quantum yield of 99% and negative thermal quenching

Shuai Yang
, Yuning Wu
, Fangyu Yue
, Ruijuan Qi
, Bin Jiang
, Jiahao Wu
, Yang Shen
, Chungang Duan
, Yongkui Shan
, Qingbiao Zhao^*
, Yuefei Zhang

^*Corresponding author for this work

School of Physics and Electronic Science

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

By optimizing the Debye temperature, we identified two extremely efficient phosphors based on the S-P transition of Bi3+. The quantum yields of Sr0.99Ga1.50B2O7:0.01Bi3+,0.50Al3+ and Ba0.995Ga1.60B2O7:0.005Bi3+,0.40Al3+ phosphors reach 96% and 99%, respectively. Moreover, Sr0.99Ga1.50B2O7:0.01Bi3+,0.50Al3+ exhibits negative thermal quenching, which shows unique advantages for practical application. The blue phosphors with quantum efficiencies close to unity and superior thermal stability can be competitive candidates for practical applications.

Original language	English
Pages (from-to)	4257-4266
Number of pages	10
Journal	Inorganic Chemistry Frontiers
Volume	8
Issue number	18
DOIs	https://doi.org/10.1039/d1qi00671a
State	Published - 21 Sep 2021

Access to Document

10.1039/d1qi00671a

Cite this

@article{a373f1643bea423198dd5bc0dae979ab,

title = "MGa2B2O7:Bi3+,Al3+(M = Sr, Ba) blue phosphors with a quantum yield of 99\% and negative thermal quenching",

abstract = "By optimizing the Debye temperature, we identified two extremely efficient phosphors based on the S-P transition of Bi3+. The quantum yields of Sr0.99Ga1.50B2O7:0.01Bi3+,0.50Al3+ and Ba0.995Ga1.60B2O7:0.005Bi3+,0.40Al3+ phosphors reach 96\% and 99\%, respectively. Moreover, Sr0.99Ga1.50B2O7:0.01Bi3+,0.50Al3+ exhibits negative thermal quenching, which shows unique advantages for practical application. The blue phosphors with quantum efficiencies close to unity and superior thermal stability can be competitive candidates for practical applications.",

author = "Shuai Yang and Yuning Wu and Fangyu Yue and Ruijuan Qi and Bin Jiang and Jiahao Wu and Yang Shen and Chungang Duan and Yongkui Shan and Qingbiao Zhao and Yuefei Zhang",

note = "Publisher Copyright: {\textcopyright} the Partner Organisations.",

year = "2021",

month = sep,

day = "21",

doi = "10.1039/d1qi00671a",

language = "英语",

volume = "8",

pages = "4257--4266",

journal = "Inorganic Chemistry Frontiers",

issn = "2052-1545",

publisher = "Royal Society of Chemistry",

number = "18",

}

TY - JOUR

T1 - MGa2B2O7:Bi3+,Al3+(M = Sr, Ba) blue phosphors with a quantum yield of 99% and negative thermal quenching

AU - Yang, Shuai

AU - Wu, Yuning

AU - Yue, Fangyu

AU - Qi, Ruijuan

AU - Jiang, Bin

AU - Wu, Jiahao

AU - Shen, Yang

AU - Duan, Chungang

AU - Shan, Yongkui

AU - Zhao, Qingbiao

AU - Zhang, Yuefei

PY - 2021/9/21

Y1 - 2021/9/21

N2 - By optimizing the Debye temperature, we identified two extremely efficient phosphors based on the S-P transition of Bi3+. The quantum yields of Sr0.99Ga1.50B2O7:0.01Bi3+,0.50Al3+ and Ba0.995Ga1.60B2O7:0.005Bi3+,0.40Al3+ phosphors reach 96% and 99%, respectively. Moreover, Sr0.99Ga1.50B2O7:0.01Bi3+,0.50Al3+ exhibits negative thermal quenching, which shows unique advantages for practical application. The blue phosphors with quantum efficiencies close to unity and superior thermal stability can be competitive candidates for practical applications.

AB - By optimizing the Debye temperature, we identified two extremely efficient phosphors based on the S-P transition of Bi3+. The quantum yields of Sr0.99Ga1.50B2O7:0.01Bi3+,0.50Al3+ and Ba0.995Ga1.60B2O7:0.005Bi3+,0.40Al3+ phosphors reach 96% and 99%, respectively. Moreover, Sr0.99Ga1.50B2O7:0.01Bi3+,0.50Al3+ exhibits negative thermal quenching, which shows unique advantages for practical application. The blue phosphors with quantum efficiencies close to unity and superior thermal stability can be competitive candidates for practical applications.

UR - https://www.scopus.com/pages/publications/85115143537

U2 - 10.1039/d1qi00671a

DO - 10.1039/d1qi00671a

M3 - 文章

AN - SCOPUS:85115143537

SN - 2052-1545

VL - 8

SP - 4257

EP - 4266

JO - Inorganic Chemistry Frontiers

JF - Inorganic Chemistry Frontiers

IS - 18

ER -

MGa₂B₂O₇:Bi³⁺,Al³⁺(M = Sr, Ba) blue phosphors with a quantum yield of 99% and negative thermal quenching

Abstract

Access to Document

Other files and links

Fingerprint

Cite this