Metal-organic framework based on [Zn4O(COO)6] clusters: Rare 3D kagomé topology and luminescence

Qi Yue; Qian Sun; Ai Ling Cheng; En Qing Gao

doi:10.1021/cg901312t

Metal-organic framework based on [Zn₄O(COO)₆] clusters: Rare 3D kagomé topology and luminescence

Qi Yue
, Qian Sun
, Ai Ling Cheng
, En Qing Gao^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

East China Normal University

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

A 2-fold interpenetrated metal-organic framework displaying intense yellow fluorescence is constructed from [Zn₄O(COO)₆] clusters and a new dicarboxylate ligand bearing the fluorene chromophore fluorene-2.7-dicarboxylic acid. The [Zn₄O(COO)₆] secondary building unit exhibits unusual coordination features and leads to the rare 3D pillared kagomé net topology (3²4⁸6⁵). 2009 American Chemical Society.

Original language	English
Pages (from-to)	44-47
Number of pages	4
Journal	Crystal Growth and Design
Volume	10
Issue number	1
DOIs	https://doi.org/10.1021/cg901312t
State	Published - 6 Jan 2010

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abstract = "A 2-fold interpenetrated metal-organic framework displaying intense yellow fluorescence is constructed from [Zn4O(COO)6] clusters and a new dicarboxylate ligand bearing the fluorene chromophore fluorene-2.7-dicarboxylic acid. The [Zn4O(COO)6] secondary building unit exhibits unusual coordination features and leads to the rare 3D pillared kagom{\'e} net topology (324865). 2009 American Chemical Society.",

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T2 - Rare 3D kagomé topology and luminescence

AU - Yue, Qi

AU - Sun, Qian

AU - Cheng, Ai Ling

AU - Gao, En Qing

PY - 2010/1/6

Y1 - 2010/1/6

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AB - A 2-fold interpenetrated metal-organic framework displaying intense yellow fluorescence is constructed from [Zn4O(COO)6] clusters and a new dicarboxylate ligand bearing the fluorene chromophore fluorene-2.7-dicarboxylic acid. The [Zn4O(COO)6] secondary building unit exhibits unusual coordination features and leads to the rare 3D pillared kagomé net topology (324865). 2009 American Chemical Society.

UR - https://www.scopus.com/pages/publications/74049135716

U2 - 10.1021/cg901312t

DO - 10.1021/cg901312t

M3 - 文章

AN - SCOPUS:74049135716

SN - 1528-7483

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JF - Crystal Growth and Design

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Metal-organic framework based on [Zn₄O(COO)₆] clusters: Rare 3D kagomé topology and luminescence

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