Luminescent CH3NH3PbBr3/β-Cyclodextrin Core/Shell Nanodots with Controlled Size and Ultrastability through Host-Guest Interactions

Sihui Huang; Ting Zhang; Chunli Jiang; Ruijuan Qi; Chunhua Luo; Ye Chen; Hechun Lin; Jadranka Travas-sejdic; Hui Peng

doi:10.1002/cnma.201900381

Luminescent CH₃NH₃PbBr₃/β-Cyclodextrin Core/Shell Nanodots with Controlled Size and Ultrastability through Host-Guest Interactions

Sihui Huang
, Ting Zhang
, Chunli Jiang^*
, Ruijuan Qi
, Chunhua Luo
, Ye Chen
, Hechun Lin
, Jadranka Travas-sejdic
, Hui Peng

^*Corresponding author for this work

School of Physics and Electronic Science

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Luminescent lead halide perovskite nanocrystals (LHP NCs) have attracted great attention. This work reports the synthesis of well-defined core/shell structured CH₃NH₃PbBr₃/β-cyclodextrin (MAPbBr₃/β-CD) nanodots via host-guest interaction between β-cyclodextrin and hexylamine. The MAPbBr₃/β-CD nanodots show high luminescence with photoluminescence quantum yields (PLQYs) of 89.7% in solution and 38.0% in solid state. The MAPbBr₃/β-CD nanodots have superior stability in water, under heat and UV light exposure due to the formation of a β-CD shell, which gives them great potential for optoelectrical and biological applications.

Original language	English
Pages (from-to)	1311-1316
Number of pages	6
Journal	ChemNanoMat
Volume	5
Issue number	10
DOIs	https://doi.org/10.1002/cnma.201900381
State	Published - 1 Oct 2019

Keywords

CHNHPbBr
core/shell structure
luminescence
perovskite nanocrystals
β-cyclodextrin

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1002/cnma.201900381

Cite this

@article{3a65567b447a409ea8e9bc516b341eb7,

title = "Luminescent CH3NH3PbBr3/β-Cyclodextrin Core/Shell Nanodots with Controlled Size and Ultrastability through Host-Guest Interactions",

abstract = "Luminescent lead halide perovskite nanocrystals (LHP NCs) have attracted great attention. This work reports the synthesis of well-defined core/shell structured CH3NH3PbBr3/β-cyclodextrin (MAPbBr3/β-CD) nanodots via host-guest interaction between β-cyclodextrin and hexylamine. The MAPbBr3/β-CD nanodots show high luminescence with photoluminescence quantum yields (PLQYs) of 89.7\% in solution and 38.0\% in solid state. The MAPbBr3/β-CD nanodots have superior stability in water, under heat and UV light exposure due to the formation of a β-CD shell, which gives them great potential for optoelectrical and biological applications.",

keywords = "CHNHPbBr, core/shell structure, luminescence, perovskite nanocrystals, β-cyclodextrin",

author = "Sihui Huang and Ting Zhang and Chunli Jiang and Ruijuan Qi and Chunhua Luo and Ye Chen and Hechun Lin and Jadranka Travas-sejdic and Hui Peng",

note = "Publisher Copyright: {\textcopyright} 2019 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2019",

month = oct,

day = "1",

doi = "10.1002/cnma.201900381",

language = "英语",

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journal = "ChemNanoMat",

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TY - JOUR

T1 - Luminescent CH3NH3PbBr3/β-Cyclodextrin Core/Shell Nanodots with Controlled Size and Ultrastability through Host-Guest Interactions

AU - Huang, Sihui

AU - Zhang, Ting

AU - Jiang, Chunli

AU - Qi, Ruijuan

AU - Luo, Chunhua

AU - Chen, Ye

AU - Lin, Hechun

AU - Travas-sejdic, Jadranka

AU - Peng, Hui

PY - 2019/10/1

Y1 - 2019/10/1

N2 - Luminescent lead halide perovskite nanocrystals (LHP NCs) have attracted great attention. This work reports the synthesis of well-defined core/shell structured CH3NH3PbBr3/β-cyclodextrin (MAPbBr3/β-CD) nanodots via host-guest interaction between β-cyclodextrin and hexylamine. The MAPbBr3/β-CD nanodots show high luminescence with photoluminescence quantum yields (PLQYs) of 89.7% in solution and 38.0% in solid state. The MAPbBr3/β-CD nanodots have superior stability in water, under heat and UV light exposure due to the formation of a β-CD shell, which gives them great potential for optoelectrical and biological applications.

AB - Luminescent lead halide perovskite nanocrystals (LHP NCs) have attracted great attention. This work reports the synthesis of well-defined core/shell structured CH3NH3PbBr3/β-cyclodextrin (MAPbBr3/β-CD) nanodots via host-guest interaction between β-cyclodextrin and hexylamine. The MAPbBr3/β-CD nanodots show high luminescence with photoluminescence quantum yields (PLQYs) of 89.7% in solution and 38.0% in solid state. The MAPbBr3/β-CD nanodots have superior stability in water, under heat and UV light exposure due to the formation of a β-CD shell, which gives them great potential for optoelectrical and biological applications.

KW - CHNHPbBr

KW - core/shell structure

KW - luminescence

KW - perovskite nanocrystals

KW - β-cyclodextrin

UR - https://www.scopus.com/pages/publications/85070677632

U2 - 10.1002/cnma.201900381

DO - 10.1002/cnma.201900381

M3 - 文章

AN - SCOPUS:85070677632

SN - 2199-692X

VL - 5

SP - 1311

EP - 1316

JO - ChemNanoMat

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IS - 10

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