Long-Chain Cross-Linking for Enhanced Mechanical Damping of Poly(styrene-butadiene-styrene) Elastomer

Qitong He; Wei Qian; Xiaxin Qiu; Lidong Zhang

doi:10.1021/acsapm.5c00918

Long-Chain Cross-Linking for Enhanced Mechanical Damping of Poly(styrene-butadiene-styrene) Elastomer

Qitong He
, Wei Qian
, Xiaxin Qiu
, Lidong Zhang^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

This study presents a chemically modified poly(styrene-butadiene-styrene) (SBS) film with enhanced mechanical robustness and vibration damping capabilities through innovative long-chain cross-linking strategies. The long-chain cross-linkers (carbon chain length >100) chemically interlock linear polymer chains within SBS films. These extended molecular bridges enable dual functionality: reinforcing structural integrity through covalent network formation and facilitating energy dissipation via controlled chain slippage within the flexible cross-linker framework during the dynamic loading. The modified SBS film demonstrates exceptional vibration mitigation performance, outperforming pristine SBS film materials by 1.5 times in signal stability.

Original language	English
Pages (from-to)	6613-6621
Number of pages	9
Journal	ACS Applied Polymer Materials
Volume	7
Issue number	11
DOIs	https://doi.org/10.1021/acsapm.5c00918
State	Published - 13 Jun 2025

Keywords

Poly(styrene-butadiene-styrene) (SBS)
damping
elastomer
long-chain cross-linking
mechanical robustness
vibration mitigation

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10.1021/acsapm.5c00918

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title = "Long-Chain Cross-Linking for Enhanced Mechanical Damping of Poly(styrene-butadiene-styrene) Elastomer",

abstract = "This study presents a chemically modified poly(styrene-butadiene-styrene) (SBS) film with enhanced mechanical robustness and vibration damping capabilities through innovative long-chain cross-linking strategies. The long-chain cross-linkers (carbon chain length >100) chemically interlock linear polymer chains within SBS films. These extended molecular bridges enable dual functionality: reinforcing structural integrity through covalent network formation and facilitating energy dissipation via controlled chain slippage within the flexible cross-linker framework during the dynamic loading. The modified SBS film demonstrates exceptional vibration mitigation performance, outperforming pristine SBS film materials by 1.5 times in signal stability.",

keywords = "Poly(styrene-butadiene-styrene) (SBS), damping, elastomer, long-chain cross-linking, mechanical robustness, vibration mitigation",

author = "Qitong He and Wei Qian and Xiaxin Qiu and Lidong Zhang",

note = "Publisher Copyright: {\textcopyright} 2025 American Chemical Society.",

year = "2025",

month = jun,

day = "13",

doi = "10.1021/acsapm.5c00918",

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T1 - Long-Chain Cross-Linking for Enhanced Mechanical Damping of Poly(styrene-butadiene-styrene) Elastomer

AU - He, Qitong

AU - Qian, Wei

AU - Qiu, Xiaxin

AU - Zhang, Lidong

PY - 2025/6/13

Y1 - 2025/6/13

N2 - This study presents a chemically modified poly(styrene-butadiene-styrene) (SBS) film with enhanced mechanical robustness and vibration damping capabilities through innovative long-chain cross-linking strategies. The long-chain cross-linkers (carbon chain length >100) chemically interlock linear polymer chains within SBS films. These extended molecular bridges enable dual functionality: reinforcing structural integrity through covalent network formation and facilitating energy dissipation via controlled chain slippage within the flexible cross-linker framework during the dynamic loading. The modified SBS film demonstrates exceptional vibration mitigation performance, outperforming pristine SBS film materials by 1.5 times in signal stability.

AB - This study presents a chemically modified poly(styrene-butadiene-styrene) (SBS) film with enhanced mechanical robustness and vibration damping capabilities through innovative long-chain cross-linking strategies. The long-chain cross-linkers (carbon chain length >100) chemically interlock linear polymer chains within SBS films. These extended molecular bridges enable dual functionality: reinforcing structural integrity through covalent network formation and facilitating energy dissipation via controlled chain slippage within the flexible cross-linker framework during the dynamic loading. The modified SBS film demonstrates exceptional vibration mitigation performance, outperforming pristine SBS film materials by 1.5 times in signal stability.

KW - Poly(styrene-butadiene-styrene) (SBS)

KW - damping

KW - elastomer

KW - long-chain cross-linking

KW - mechanical robustness

KW - vibration mitigation

UR - https://www.scopus.com/pages/publications/105007507681

U2 - 10.1021/acsapm.5c00918

DO - 10.1021/acsapm.5c00918

M3 - 文章

AN - SCOPUS:105007507681

SN - 2637-6105

VL - 7

SP - 6613

EP - 6621

JO - ACS Applied Polymer Materials

JF - ACS Applied Polymer Materials

IS - 11

ER -

Long-Chain Cross-Linking for Enhanced Mechanical Damping of Poly(styrene-butadiene-styrene) Elastomer

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Keywords

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