TY - JOUR
T1 - Linear neutral platinum–acetylide moiety
T2 - beyond the links
AU - Wang, Wei
AU - Yang, Hai Bo
PY - 2014/4/22
Y1 - 2014/4/22
N2 - In this feature article, brief highlights of research progress on the linear neutral platinum–acetylide moiety, trans-Pt(PR3)2(C≡CR′)2, are presented. Due to its unique characteristics such as the well-defined linear geometry, synthetic accessibility, and intriguing photoproperties, this type of platinum–acetylide moiety has been extensively investigated in many respects from supramolecular chemistry to materials science during the past two decades. However, compared with the extensively studied charged platinum–acetylide complexes, the linear neutral platinum–acetylide moiety has been less reviewed. Based upon our recent progress in platinum chemistry, we provide herein a brief review on the linear neutral platinum–acetylide building block. This feature article will focus on its role as a linkage building block, but beyond the links. Three aspects including complex architectures composed of platinum–acetylide links, platinum–acetylide bridged multichromophoric arrays, and supramolecular self-assembly of platinum–acetylide building blocks are discussed.
AB - In this feature article, brief highlights of research progress on the linear neutral platinum–acetylide moiety, trans-Pt(PR3)2(C≡CR′)2, are presented. Due to its unique characteristics such as the well-defined linear geometry, synthetic accessibility, and intriguing photoproperties, this type of platinum–acetylide moiety has been extensively investigated in many respects from supramolecular chemistry to materials science during the past two decades. However, compared with the extensively studied charged platinum–acetylide complexes, the linear neutral platinum–acetylide moiety has been less reviewed. Based upon our recent progress in platinum chemistry, we provide herein a brief review on the linear neutral platinum–acetylide building block. This feature article will focus on its role as a linkage building block, but beyond the links. Three aspects including complex architectures composed of platinum–acetylide links, platinum–acetylide bridged multichromophoric arrays, and supramolecular self-assembly of platinum–acetylide building blocks are discussed.
UR - https://www.scopus.com/pages/publications/84898059689
U2 - 10.1039/c3cc47485b
DO - 10.1039/c3cc47485b
M3 - 文章
AN - SCOPUS:84898059689
SN - 1359-7345
VL - 50
SP - 5171
EP - 5186
JO - Chemical Communications
JF - Chemical Communications
IS - 40
ER -